Zircon U–Pb age, trace element and Hf isotope composition of Kongling terrane in the Yangtze Craton: refining the timing of Palaeoproterozoic high-grade metamorphism

U–Pb age, trace element and Hf isotope compositions of zircon were analysed for a metasedimentary rock and two amphibolites from the Kongling terrane in the northern part of the Yangtze Craton. The zircon shows distinct morphological and chemical characteristics. Most zircon in an amphibolite shows oscillatory zoning, high Th/U and ¹⁷⁶Lu/¹⁷⁷Hf ratios, high formation temperature, high trace element contents, clear negative Eu anomaly, as well as HREE-enriched patterns, suggesting that it is igneous. The zircon yields a weighted mean ²⁰⁷Pb/²⁰⁶Pb age of 2857 ± 8 Ma, representing the age of the magmatic protolith. The zircon in the other two samples is metamorphic. It has low Th/U ratios, low trace element concentrations, variable HREE contents (33.8 ≥ Lu_N≥2213; 14.7 ≤ Lu_N/Sm_N ≤ 354) and ¹⁷⁶Lu/¹⁷⁷Hf ratios (0.000030–0.001168). The data indicate that the zircon formed in the presence of garnet and under upper amphibolite facies conditions. The metamorphic zircon yields a weighted mean ²⁰⁷Pb/²⁰⁶Pb age of 2010 ± 13 Ma. These results combined with previously obtained Palaeoproterozoic metamorphic ages suggest a c. 2.0 Ga Palaeoproterozoic collisional event in the Yangtze Craton, which may result from the assembly of the supercontinent Columbia. The zircon in two samples yields weighted mean two-stage Hf model ( T _DM2) ages of 3217 ± 110 and 2943 ± 50 Ma, respectively, indicating that their protoliths were mainly derived from Archean crust.     

Age and early metamorphic history of the Sanbagawa belt: Lu–Hf and P–T constraints from the Western Iratsu eclogite

Two distinct age estimates for eclogite-facies metamorphism in the Sanbagawa belt have been proposed: (i) c.  120–110 Ma based on a zircon SHRIMP age for the Western Iratsu unit and (ii) c.  88–89 Ma based on a garnet–omphacite Lu–Hf isochron age from the Seba and Kotsu eclogite units. Despite the contrasting estimates of formation ages, petrological studies suggest the formation conditions of the Western Iratsu unit are indistinguishable from those of the other two units—all ∼20 kbar and 600–650 °C. Studies of the associated geological structures suggest the Seba and Western Iratsu units are parts of a larger semi-continuous eclogite unit. A combination of geochronological and petrological studies for the Western Iratsu eclogite offers a resolution to this discrepancy in age estimates. New Lu–Hf dating for the Western Iratsu eclogite yields an age of 115.9 ± 0.5 Ma that is compatible with the zircon SHRIMP age. However, petrological studies show that there was significant garnet growth in the Western Iratsu eclogite before eclogite facies metamorphism, and the early core growth is associated with a strong concentration of Lu. Pre-eclogite facies garnet (Grt1) includes epidote–amphibolite facies parageneses equilibrated at 550–650 °C and ∼10 kbar, and this is overgrown by prograde eclogite facies garnet (Grt2). The Lu–Hf age of c.  116 Ma is strongly skewed to the isotopic composition of Grt1 and is interpreted to reflect the age of the pre-eclogite phase. The considerable time gap ( c.  27 Myr) between the two Lu–Hf ages suggests they may be related to separate tectonic events or distinct phases in the evolution of the Sanbagawa subduction zone.     

Metamorphic phase relations in orthopyroxene-bearing granitoids: implication for high-pressure metamorphism and prograde melting in the continental crust

In this work, the factors controlling the formation and preservation of high-pressure mineral assemblages in the metamorphosed orthopyroxene-bearing metagranitoids of the Sandmata Complex, Aravalli-Delhi Mobile Belt (ADMB), northwestern India have been modelled. The rocks range in composition from farsundite through quartz mangerite to opdalite, and with varying K₂O, Ca/(Ca + Na)_rock and FeO_tot + MgO contents. A two stage metamorphic evolution has been recorded in these rocks.
An early hydration event stabilized biotite with or without epidote at the expense of magmatic orthopyroxene and plagioclase. Subsequent high-pressure granulite facies metamorphism (∼15 kbar, ∼800 °C) of these hydrated rocks produced two rock types with contrasting mineralogy and textures. In the non-migmatitic metagranitoids, spectacular garnet ± K-feldspar ± quartz corona was formed around reacting biotite, plagioclase, quartz and/or pyroxene. In contrast, biotite ± epidote melting produced migmatites, containing porphyroblastic garnet incongruent solids and leucosomes.
Applying NCKFMASHTO T–M (H₂O) and P–T pseudosection modelling techniques, it is demonstrated that the differential response of these magmatic rocks to high-pressure metamorphism is primarily controlled by the scale of initial hydration. Rocks, which were pervasively hydrated, produced garnetiferous migmatites, while for limited hydration, the same metamorphism formed sub-solidus garnet-bearing coronae. Based on the sequence of mineral assemblage evolution and the mineral compositional zoning features in the two metagranitoids, a clockwise metamorphic P–T path is constrained for the high-pressure metamorphic event. The finding has major implications in formulating geodynamic model of crustal amalgamation in the ADMB.     

Comet nuclei: Morphology and implied processes of surface modification

Surface morphology and related issues for nuclei of three comets: Halley, Borrelly and Wild 2, are considered in the paper. Joint consideration of publications and results of our analysis of the comets’ images led to conclusions, partly new, partly repeating conclusions published by other researchers. It was found that typical for all three nuclei is the presence of rather flat areas: floors of craters and other depressions, mesas and terraces. This implies that flattening surfaces or planation is a process typical for the comet nuclei. Planation seems to work through the sublimation-driven slope collapse and retreat. This requires effective sublimation so this process should work only when a comet is close to the Sun and if on the nucleus there are starting slopes, steep and high enough to support the “long-distance” avalanching of the collapsing material. If the surface had no starting slopes, then instead of planation, the formation of pitted-and-hilly surfaces should occur. An example of this could be the mottled terrain of the Borelly nucleus. Both ways of the sublimational evolution on the nucleus surface should lead to accumulation of cometary regolith. The thickness of the degassed regolith is not known, but it is obvious that in surface depressions, including the flat-floor ones, it should be larger compared with nondepression areas. This may have implications for the in situ study of comets by the Deep Impact and Rosetta missions.Our morphological analysis puts constraints on the applicability of the popular “rubble-pile comet nucleus” hypothesis (Weissman, 1986. Are cometery nuclei primordial rubble piles? Nature 320, 242-244.). We believe that the rubble pile hypothesis can be applicable to the blocky Halley nucleus. The Borelly and Wild 2 nuclei also could be rubble piles. But in these cases the “rubbles” have to be either smaller than 30-50 m (a requirement to keep lineament geometry close to ideal), or larger than 1-2 km (a requirement to form the rather extended smooth, flat surfaces of mesa tops and crater floors). Another option is that the Borelly and Wild 2 nuclei are not rubble piles.In relation to surface morphology we suggest that three end-member types of the comet nuclei may exist: (1) impact cratered “pristine” bodies, (2) non-cratered fragments of catastrophic disruption, and (3) highly Sun-ablated bodies. In this threefold classification, the Wild 2 nucleus is partially ablated primarily cratered body. Borrelly is significantly ablated and could be either primarily cratered or not-cratered fragment. Halley is certainly partially ablated but with the available images it is difficult to say if remnants of impact craters do exist on it.Recently published observations and early results of analysis of the Tempel 1 nucleus images taken by Deep Impact mission are in agreement with our conclusions on the processes responsible for the Halley, Borrelly and Wild 2 nuclei morphologies. In particular, we have now more grounds to suggest that decrease in crater numbers and increase of the role of smooth flat surfaces in the sequence Wild 2?Tempel 1?Borelli reflects a progress in the sublimational degradation of the nucleus surface during comet passages close to the Sun.     

Reef exploration in the East Sengkang Basin,Sulawesi, Indonesia

Reconnaissance seismic shot in 1971/72 showed a number of well defined seismic anomalies within the East Sengkang Basin which were interpreted as buried reefs. Subsequent fieldwork revealed that Upper Miocene reefs outcropped along the southern margin of the basin. A drilling programme in 1975 and 1976 proved the presence of shallow, gas-bearing, Upper Miocene reefs in the northern part of the basin. Seismic acquisition and drilling during 1981 confirmed the economic significance of these discoveries, with four separate accumulations containing about 750 × 10⁹ cubic feet of dry gas in place at an average depth of 700 m. Kampung Baru is the largest field and contains over half the total, both reservoir quality and gas deliverability are excellent. Deposition in the East Sengkang Basin probably started during the Early Miocene. A sequence of Lower Miocene mudstones and limestones unconformably overlies acoustic basement which consists of Eocene volcanics. During the tectonically active Middle Miocene, deposition was interrupted by two periods of deformation and erosion. Carbonate deposition became established in the Late Miocene with widespread development of platform limestones throughout the East Sengkang Basin. Thick pinnacle reef complexes developed in the areas where reef growth could keep pace with the relative rise in sea level. Most reef growth ceased at the end of the Miocene and subsequent renewed clastic sedimentation covered the irregular limestone surface. Late Pliocene regression culminated in the Holocene with erosion. The Walanae fault zone, part of a major regional sinistral strike-slip system, separates the East and West Sengkang Basins. Both normal and reverse faulting are inferred from seismic data and post Late Pliocene reverse faulting is seen in outcrop.     

Microstructures of co-axially folded vein segments and crenulation cleavage： Evidence for dissolution phenomena in the Chamba Thrust Sheet, western Himalayas

The metasediments in the Chamba region experienced three phases of deformation: DF1, DF2 and DF3.Folded quartz veins are co-folded with the F2 crenulation folds. Their geometric and tectonic significance is studied by microstructures and shortening adjacent to the discrete crenulation cleavage, S2. Microstructures of folded vein segments, their geometric changes and truncation to cleavage (S2) are mainly due to pressure-solution phenomena and the estimated volume loss from reconstructed vein segments range from 16 to 25.5%,which is closely related to volume decrease (26%) calculated from the polydeformed slates of North Wales areas.     

Ultraviolet reflectance properties of asteroids

An analysis of the UV spectra of 28 asteroids obtained with the Internal Ultraviolet Explorer (IUE) satellite is presented. The spectra lie within the range 2100–3200 Å. Our results are examined in terms of both asteroid classification and of current ideas concerning the surface mineralogy of asteroids. For all the asteroids examined, UV reflectivity declines approximately linearly toward shorter wavelengths. In general, the same taxonomic groups are seen in the UV as in the visible and IR, although there is some evidence for asteroids with anomalous UV properties and for UV subclasses within the S class. No mineral absorption features are reported of strength similar to the strongest features in the visible and IR regions, but a number of shallow absorptions do occur and may provide valuable information on the surface composition of many asteroids.     

Comparison of marine gas hydrates in sediments of an active and passive continental margin

Two sites of the Deep Sea Drilling Project in contrasting geologic settings provide a basis for comparison of the geochemical conditions associated with marine gas hydrates in continental margin sediments. Site 533 is located at 3191 m water depth on a spit-like extension of the continental rise on a passive margin in the Atlantic Ocean. Site 568, at 2031 m water depth, is in upper slope sediment of an active accretionary margin in the Pacific Ocean. Both sites are characterized by high rates of sedimentation, and the organic carbon contents of these sediments generally exceed 0.5%. Anomalous seismic reflections that transgress sedimentary structures and parallel the seafloor, suggested the presence of gas hydrates at both sites, and, during coring, small samples of gas hydrate were recovered at subbottom depths of 238m (Site 533) and 404 m (Site 568). The principal gaseous components of the gas hydrates wer methane, ethane, and CO₂. Residual methane in sediments at both sites usually exceeded 10 mll^?1 of wet sediment. Carbon isotopic compositions of methane, CO₂, and ΣCO₂ followed parallel trends with depth, suggesting that methane formed mainly as a result of biological reduction of oxidized carbon. Salinity of pore waters decreased with depth, a likely result of gas hydrate formation. These geochemical characteristics define some of the conditions associated with the occurrence of gas hydrates formed by in situ processes in continental margin sediments.     

Eastern Aphrodite Terra on Venus: Characteristics,structure, and mode of origin

Eastern Aphrodite Terra and Western Aphrodite form an altimetrically prominent 14,000 km long part of the equatorial highlands on Venus. Several parallel linear discontinuities striking northwest across the general east-west regional strike of the highlands are mapped in the altimetric and radar image data of Eastern Aphrodite and identified on the basis of abrupt termination of rift-like central chasma, offset and segmentation of the center of the highlands, and radar image discontinuities in the lowlands to the north. These characteristics are similar to those of linear discontinuities previously mapped in Western Aphrodite in terms of length, orientation, and influence on the central highlands and adjacent lowlands.Altimetric profiles in directions parallel to the discontinuities are regionally symmetric, more ridge-like in Eastern Aphrodite compared to the plateau-dominated form of topography in Western Aphrodite, and are characterized by alternating paired ridge-and-trough forms near their crests and on their flanks. By mapping the center of symmetry in multiple profiles, the prominent segmentation of the highland is shown to be imparted by an offset of the regional symmetry along the mapped discontinuities. These characteristics are morphologically similar to several of the large-scale characteristics of divergent plate boundaries of Earth, including mid-ocean rise crests and rifts, offset at fracture zones and transform faults, and symmetric thermal boundary layer topography.The altitude of the surface in profiles parallel to the discontinuities decreases as the square root of distance from the symmetry axes and with a slope similar to that predicted for thermal boundary layer topography associated with rates of divergence on Venus of ~ 1 ± 0.5 cm/yr. In order to test the hypothesis that the linear discontinuities are analogous to fracture zones, the predicted altitude of the surface at great distance from the centers of symmetry of the central highland and in directions across the discontinuities was calculated on the basis of a thermal boundary layer topography model with offset of altimetric symmetry at each discontinuity. Similarity of observed Arecibo high-resolution altimetric profiles across the discontinuities with that calculated for thermal boundary layer topography offset by transform faults reveals that in terms of the sense and magnitude of regional steps in altimetry across discontinuities and the altitude of the surface, Eastern Aphrodite is similar to the known characteristics of crustal spreading at divergent boundaries. The plateau-like form of Western Aphrodite and the ridge-like form of Eastern Aphrodite are analogous respectively to the difference between areas of anomalous (Iceland) and normal crustal production along rise crests on Earth. Estimates of volumetric differences in crustal production in the environment of Venus and as it would be influenced by differences in mantle temperature beneath Western and Eastern Aphrodite imply that Eastern Aphrodite represents normal crustal production. On this basis, Western Aphrodite may be characterized by a mantle temperature that is warmer than the mantle beneath Eastern Aphrodite Terra, perhaps in association with deep convective mantle upwelling.'Geology and Tectonics of Venus', special issue edited by Alexander T. Basilevsky (USSR Acad. of Sci., Moscow), James W. Head (Brown University, Providence), Gordon H. Pettengill (MIT. Cambridge, Massachusetts) and R. S. Saunders (J.P.L., Pasadena).