Decompression and H<Subscript>2</Subscript>O exsolution driven crystallization and fractionation: development of a new model for low-pressure fractional crystallization in calc-alkaline magmatic systems

Magma ascent, decompression-induced H₂O exsolution and crystallization is now recognized as an important process in hydrous subduction zone magmas. During the course of such a process calculations suggest that the ascent rate of a degassing and crystallizing mafic magma will be greater than crystal settling velocities. Thus, any crystals formed as a consequence of volatile exsolution will remain suspended in the magma. If the magma erupts before the percentage of suspended crystals reaches the critical crystallinity value for mafic magma (~55 vol.%) it will produce the commonly observed crystal rich island arc basalt lava. If the magma reaches its critical crystallinity before it erupts then it will stall within the crust. Extension of compaction experiments on a 55 vol.% sand-Karo syrup suspension at different temperatures (and liquid viscosities) to the likely viscosities of interstitial andesitic to dacitic liquid within such a stalled magma suggest that small amounts (up to ~10%) can be expelled on a time scale of 1–10 years. The expelled liquid can create a new intermediate to silicic body of magma that is related to the original mafic magma via fractional crystallization. The short time scale for liquid expulsion indicate that decompression-induced H₂O exsolution and crystallization can be an important mechanism for fractional crystallization. Based on this assumption a general model of decompression-induced crystallization and fractionation is proposed that explains many of the compositional, mineralogical and textural features of Aleutian (and other andesites).     

Clustering of groundwater chemistry data with implications for reservoir appraisal in West Siberia

Division of sedimentary strata according to groundwater chemistry is discussed with implications for petroleum reservoir potential. It is suggested to process multiparametric water chemistry data from West Siberia using formalized clustering techniques. The efficiency of this approach has been tested for Neocomian clinoform reservoirs with reference to regional-scale appraisal and subregional petroleum division.     

Chemical evolution and petrogenetic implications of loparite in the layered,agpaitic Lovozero complex,Kola Peninsula,Russia

Summary Lovozero, the largest of the world’s layered peralkaline intrusions, includes gigantic deposits of Nb + REE-loparite ore. Loparite, (Na,Ce,Ca)₂(Ti,Nb)₂O₆, became a cumulus phase after crystallisation of about 35% of the ‘Differentiated Complex’, and its compositional evolution has been investigated through a 2.35 km section of the intrusion. The composition of the cumulus loparite changes systematically upwards through the intrusion with an increase in Na, Sr, Nb and Th and decrease in REE and Ti. This main trend of loparite evolution records differentiation of the peralkaline magma through crystallisation of 1600 m of the intrusion. The formation of the loparite ores was the result of several factors including the chemical evolution of the highly alkaline magma and mechanical accumulation of loparite at the base of a convecting unit. At later stages of evolution, when concentrations of alkalis and volatiles reached very high levels, loparite reacted with the residual melt to form a variety of minerals including barytolamprophyllite, lomonosovite, steenstrupine-(Ce), vuonnemite, nordite, nenadkevichite, REE, Sr-rich apatite, vitusite-(Ce), mosandrite, monazite-(Ce), cerite and Ba, Si-rich belovite. The absence of loparite ore in the “Eudialyte complex” is likely to be a result of the wide crystallisation field of lamprophyllite, which here became a cumulus phase. Received November 6, 2000; revised version accepted January 18, 2001     

Constraints on the thermal evolution of continental lithosphere from U-Pb accessory mineral thermochronometry of lower crustal xenoliths,southern Africa

U-Pb isotopic thermochronometry of rutile, apatite and titanite from kimberlite-borne lower crustal granulite xenoliths has been used to constrain the thermal evolution of Archean cratonic and Proterozoic off-craton continental lithosphere beneath southern Africa. The relatively low closure temperature of the U-Pb rutile thermochronometer (~400-450 °C) allows its use as a particularly sensitive recorder of the establishment of "cratonic" lithospheric geotherms, as well as subsequent thermal perturbations to the lithosphere. Contrasting lower crustal thermal histories are revealed between intracratonic and craton margin regions. Discordant Proterozoic (1.8 to 1.0 Ga) rutile ages in Archean (2.9 to 2.7 Ga) granulites from within the craton are indicative of isotopic resetting by marginal orogenic thermal perturbations influencing the deep crust of the cratonic nucleus. In Proterozoic (1.1 to 1.0 Ga) granulite xenoliths from the craton-bounding orogenic belts, rutiles define discordia arrays with Neoproterozoic (0.8 to 0.6 Ga) upper intercepts and lower intercepts equivalent to Mesozoic exhumation upon kimberlite entrainment. In combination with coexisting titanite and apatite dates, these results are interpreted as a record of postorogenic cooling at an integrated rate of approximately 1 °C/Ma, and subsequent variable Pb loss in the apatite and rutile systems during a Mesozoic thermal perturbation to the deep lithosphere. Closure of the rutile thermochronometer signals temperatures of 𙠂 °C in the lower crust during attainment of cratonic lithospheric conductive geotherms, and such closure in the examined portions of the "off-craton" Proterozoic domains of southern Africa indicates that their lithospheric thermal profiles were essentially cratonic from the Neoproterozoic through to the Late Jurassic. These results suggest similar lithospheric thickness and potential for diamond stability beneath both Proterozoic and Archean domains of southern Africa. Subsequent partial resetting of U-Pb rutile and apatite systematics in the cratonic margin lower crust records a transient Mesozoic thermal modification of the lithosphere, and modeling of the diffusive Pb loss from lower crustal rutile constrains the temperature and duration of Mesozoic heating to 𙡦 °C for ₞ ka. This result indicates that the thermal perturbation is not simply a kimberlite-related magmatic phenomenon, but is rather a more protracted manifestation of lithospheric heating, likely related to mantle upwelling and rifting of Gondwana during the Late Jurassic to Cretaceous. The manifestation of this thermal pulse in the lower crust is spatially and temporally correlated with anomalously elevated and/or kinked Cretaceous mantle paleogeotherms, and evidence for metasomatic modification in cratonic mantle peridotite suites. It is argued that most of the geographic differences in lithospheric thermal structure inferred from mantle xenolith thermobarometry are likewise due to the heterogeneous propagation of this broad upper mantle thermal anomaly. The differential manifestation of heating between cratonic margin and cratonic interior indicates the importance of advective heat transport along pre-existing lithosphere-scale discontinuities. Within this model, kimberlite magmatism was a similarly complex, space- and time-dependent response to Late Mesozoic lithospheric thermal perturbation.     

Structural and magnetic fabric studies of recess structures in the western Himalaya: Implications for 1905 Kangra earthquake

Kinematic information from deformation structures and magnetic fabrics are used to infer recent tectonics around Kangra and Dehradun recesses, western Himalaya. Three types of magnetic fabrics (Type I & II, III, and IV) are identified based on the angle between K3 axis and bedding pole. It was observed that Kangra recess shows more mature fabric type IV as compared to Dehradun recess, where orientation of K3 axes and tectonic fabric reveals dominance of superposed deformation. In the vicinity of Dehradun recess, normal faults occur in un-indurated Quaternary fan deposits confirming their recent formation. The observations are in conformity with earlier studies that during the 1905 Kangra earthquake, the Main Boundary Thrust (MBT) (or one of its subsidiary thrusts) near Kangra showed thrusting whereas the MBT near Dehradun underwent either normal faulting or post seismic adjustments characteristic of normal faulting. The thrusting could be a result of subsurface processes whereas the normal faulting was a result of prevailing surface strains.     

Eutrophication,health risk assessment and spatial analysis of water quality in Gucheng Lake,China

The water characteristics of the Gucheng Lake, such as eutrophication, health and spatial distribution, were investigated. On the basis of the trophic state index (TSI) and entropy weight, a synthesized trophic state index (STSI) model was established to assess lake eutrophication condition through calculating STSI, choosing TP, TN, COD, BOD and NH₃-N as trophic variables. The STSI ranged from 50.58 to 62.44, which showed that the water has been between eutrophic and supereutrophic. A histogram was applied to health risk assessment which was analyzed from carcinogenic substances (Cr⁺⁶, As and Cd) and non-carcinogenic substances (hydroxybenzene, Pb, Hg, CN⁻ and NH₃), and the results showed that the former was much greater than the latter for effect. The total risk for each resident caused by all pollutants ranged from 5.18E-05 to 8.34E-05, which is far higher than the standard, recommended by Sweden Bureau of Environment Protection and Holland Ministry of Building and Environment Protection (1.0E-05). Cluster analysis was used to detect similarities and dissimilarities among the seven sampling sites and explain the observed clustering in terms of affected conditions. Twenty-one variables were used to divide seven sampling sites into three groups, namely, north lake, south lake and lake center.     

Variolitic lavas in the axial rift of the Mid-Atlantic Ridge and their origin (Sierra Leone area, 6°18′N)

Altered variolites described for the first time in the axial zone of the Mid-Atlantic Ridge are represented by rounded globules of andesite (icelandite) composition with light trachyandesite rim embedded in a picrobasaltic matrix. The globules were transferred with picrobasaltic melt and then floated to the surface of lava flow, while formation of leucocratic rims was presumably related to thermodiffusion (Soret effect) in a cooling heterogeneous melt. This heterogeneous melt was formed by penetration of ascending column of picrobasaltic magma in already existing small intracructsal magmatic chamber filled with residual icelanditetype andesite melt and involvement of the latter into a general upward movement. The rapid ascent of the melts in the oceanic spreading zones by means of turbulent flowing caused dispersion of the extragenous melt into small drops in a jet of picrobasaltic magma, without their interaction. Variolites were formed during cooling of such heterogeneous lava flow. No signs of liquid immiscibility were found in the studied variolites.