Equatorial ionospheric response to isolated auroral substorms over a solar cycle (1980-85): evidence of longitudinal anomaly

The equatorial ionospheric response to 228 isolated, rapid-onset auroral substorms (as defined from the auroral electrojet index AE) was found from enhancements of the virtual (minimum) height of the F-region (h′F) in the declining phase of a solar cycle (1980-85). The responses, found for three longitudinal sectors at the equator: Africa (Ouagadougou and Dakar), Asia (Manila) and America (Huancayo), were compared with the response close to the auroral source region at Yakutsk (northern Siberia). The auroral substorm onsets were centered at 17 and 15 UT at sunspot maximum (1980-82) and minimum (1983-85), preceding by 3–5 h the period of post-sunset height rise in the African sector whereas other sectors were in the early afternoon (Huancayo) and morning (Manila). The African response, particularly at Ouagadougou, was distinctly different from other sectors. In the sunspot maximum years (1980-81) the auroral surges were followed after about 3 h by a sharp depression (h′F<0) in the post-sunset height rise, with a period of little or no response (h′F=0) in 1982. A response polarity reversal (h′F>0) was noted in this sector for sunspot minimum (1983-85) when large h′F enhancements were observed at the sunset region. The responses in the Asian and American sector were positive except for a case in Huancayo when response was negative, following an auroral surge before the sunset at this station. It appears that the aurorally generated large-scale travelling ionospheric disturbances (LSTIDs), which first cause positive height enhancements in a sub-auroral location (Yakutsk), subsequently affect the unstable post-sunset ionosphere in the equatorial Africa.     

草簇状石墨烯片限域Pd纳米粒子及其催化应用(英文)

通过氨基离子液体改性石墨烯,并将其固载于堇青石表面,作为负载型Pd催化剂的载体.所制备的Pd催化剂经加氢老化后,表面石墨烯呈草簇状结构,将Pd纳米粒子限域于片层内,有效防止了Pd的流失和团聚.在重要的工业反应对羧基苯甲醛(4-CBA)加氢中,此结构催化剂与传统的钯碳催化剂相比,表现出很好的稳定性     

The construction of self-consistent models for outflowing stellar envelopes

The article presents self-consistent computations of the spherically symmetric envelope of a massive (M=20M _⊙) star whose envelope is flowing outward under the action of continuum radiation pressure. A system of equations describing the out flow for arbitrary optical depth, degree of ionization, and opacity κ are obtained. A numerical solution is obtained for the case of constant κ and degree of ionization via approaching integrations from the singularities and smooth joining in the intermediate region. Asymptotic solutions are found in the vicinity of the sonic point and the singularity at infinity.     

Measurements of solar occulation: the error in a naive retrieval if the constituent's concentration changes

The stratospheric concentrations of many minor constituents change rapidly at sunrise or sunset. If this happens, there is an inherent error when retrieving the vertical profiles of the constituents from measurements of their absorption of sunlight. For retrievals of NO at sunset the error can be estimated from in-situ measurements alone, without appeal to a model of stratospheric photochemistry. Below 20 km this error can approach 100% so that the retrieved NO is zero. But at 40 km, and at 25 km when the absorption is strong and Lorentzian, it can be less than 20%. Precise calculations of the error, even if small, require model calculations of the sunset and sunrise changes. With a model, we have calculated the error for NO, NO₂, OH and ClO.