Electron paramagnetic resonance,optical absorption,and magnetic circular dichroism studies of the CO 3 − molecular-ion in irradiated natural beryl

Room temperature X-irradiation of some natural beryls produced several new absorption lines in the electron paramagnetic resonance (EPR) spectrum, a known series of optical absorption lines in the 500–700 nm range, and a shift of the absorption edge to lower energies. Several of the new EPR lines and part of the irradiation-induced shift of the absorption edge disappeared after a few days at room temperature, and were not examined in detail. However, three of the paramagnetic centres responsible for the new EPR lines were stable at room temperature and two of these have previously been identified as atomic hydrogen and the methyl radical, CH₃. These species were stable to ～150 and ～450°C respectively. The third stable species, hitherto unreported, showed a single-line EPR spectrum of axial symmetry, with g∥=2.0051 and g⊥=2.0152. This spectrum was found to be intensity-correlated with the series of optical bands in the 500–700 nm range, after thermal bleaching at 175°C. The EPR and optical spectra are therefore assigned to the same species. It is argued that this species is the CO ₃ ^? molecular ion, located in the widest part of the structural channel and aligned with the plane of the molecule perpendicular to the c axis. The EPR spectrum is consistent with a ² A′₂ ground state of a CO ₃ ^? molecule with trigonal symmetry, and this requires that the optical transition has a ² A′₂ → ² E′ character. Most of the features in the optical spectrum can be assigned to coupling of a totally symmetric mode of frequency ～1020 cm^?1 onto a zero-phonon line at 14,490 cm^?1 and a second weaker line at 16,020 cm^?1. However, both of these two fundamental lines are structured, and the two components show strong temperature-dependent derivative-shaped magnetic circular dichroism (MCD). Furthermore, the overall sign of the MCD for the line at 16,020 cm^?1 is opposite to that at 14,490 cm^?1. The separation (～120 cm^?1) of the two components of the 14,490 cm^?1 line is much larger than that expected from spin-orbit interaction, and the origin of this splitting is not yet understood.     

Seismicity re-evaluation of the northern Red Sea

The Aqaba subnetwork of five vertical short-period stations of the seismological observatory of King Saud University was installed in late 1986 along the eastern side of the Gulf of Aqaba, northern Red Sea. During the first six years (1986 August to 1992 July) of the subnetwork operation, 400 microearthquakes were detected. Of these, 93 events were recorded by most of the subnet stations and were located. Their epicentres lie in the northern part of the Red Sea between latitudes 25.5 N and 27.5 N and longitudes 33.5 E and 36 E along the axial depression of the Red Sea where the large intrusions (deeps) are located. Magnitudes of the locatable events ranged from 2.1 to 4.8. Two intensive swarms of about 200 microearthquakes occurred in February and June of 1992. The February swarm is the first intensive sequence observed in the surveying area since the establishment of the KSU network. Frequency-magnitude analysis of the recorded events for the period 1986-1992 yielded 3.543 for a and 0.658 for b . These relatively higher b values (0.658) are a good indication of the crustal heterogeneity under the spreading zone of the northern Red Sea. USGS and KSU data together show 3.41 for a and 0.49 for b . This study, together with historical data, confirms that the area is very seismically active and that the activity is mainly of swarm type, and may be attributed to the subsurface magmatic activity and spreading centres that are usually associated with strike-slip and normal faulting, respectively.     

Stratigraphie und Fazies des Erzgebirgischen Kristallins im Rahmen des Mitteleuropäischen Varistikums

Zusammenfassung Es läßt sich zeigen, daß im erzgebirgischen Raum die jungalgonkische Serie des varistischen Sockels von der Petrofazies diskordant geschnitten wird. Im Bereich des erzgebirgischen Kristallins steigt die Amphibolitfazies beulenförmig bis an die Basis des varistischen Sedimenttroges auf. Mit diesem Aufstieg wird eine Granitbildung regionalen und lokalen Charakters als möglich in Verbindung gebracht.

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It can be demonstrated that the Upper Algonkian rocks of the Hercynian basement are disconformably cut by the petrofacies of the Erzgebirge. In the environment of crystallin rocks amphibolitic facies ascend to the bottom of the hercynian sedimentary trough. With this rise a granitisation of regional and locally restricted character might seem to be possible.

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Résumé On peut montrer que dans la région de l'Erzgebirge les couches de l'Algonkien supérieur du socle hercynien sont recoupées en discordance par le petrofacies. Dans le domaine du cristallin de l'Erzgebirge, le facies amphibolite a la forme d'un dûme atteignant la base de la fosse sédimentaire varisque. On croit pouvoir établir une relation entre la formation de granite à l'échelle régionale et locale et cette montée métamorphique.

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Herrn Prof. Dr. Dr. h. c.Erich Bederke zum 70. Geburtstag gewidmet.     

On the existence of a second scale of convection in the upper mantle

Summary. This paper is concerned with an examination of the possibility that there might exist a small scale of convective circulation beneath the oceanic lithosphere. Recent suggestions that this might be the case have been made in an effort to understand why the bathymetry of the sea-floor deviates from the prediction of boundary layer theory for ages in excess of about 100 Ma. The energy source which sustains the secondary motion is supposed to be found in the steep temperature gradient near the planetary surface which is itself presumably maintained by the large-scale convective circulation associated with plate creation and destruction. Here we investigate the extent to which the temperature dependence of viscosity may act so as to stabilize the upper boundary layer against disruption by such secondary instability. If the viscosity profile is monotonie and the asymptotic upper mantle viscosity is about 10²²poise, as suggested by post-glacial rebound data, then the existence of the second scale is extremely unlikely. On the other hand, if a sufficiently pronounced low viscosity zone does exist under old sea-floor then the development of such a second scale cannot be ruled out completely. Some recently obtained geophysical evidence is reviewed which suggests that this is unlikely to be the case.     

Uniaxial creep tests on a morainic material from switzerland

To determine deformation and strength behaviour of a frozen morainic material uniaxial creep tests with constant load on remoulded samples have been carried out.

From the test results an analytical method describing the mechanical behaviour could be found.

In the following the results of this investigation are presented and an analytical solution is derived. In addition, other experimentally determined curves are compared with the calculated ones. For the material tested the proposed method leads to quite satisfactory results and is expected to do so also for other materials.     

INTERSTATE HIGHWAY EXIT MORPHOLOGY: NON-METROPOLITAN EXIT COMMERCE ON 1-75*

The commercial non-metropolitan exit clusters of America's interstate highway system exhibit regularities of basic form, scale, mix of services provided, and the ordinal placement of establishments relative to the exit proper. An examination of 354 exits serving 1-75 indicates the typical morphology of interstate exit clusters.     

Potential implications of differential preservation of testate amoeba shells for paleoenvironmental reconstruction in peatlands

Testate amoebae are now commonly used in paleoenvironmental studies but little is known of their taphonomy. There is some experimental evidence for differential preservation of some testate amoeba shell types over others, but it is unclear what, if any impact this has on palaeoenvironmental reconstruction. To investigate this issue we looked at palaeoecological evidence for the preservation of different shell types. We then investigated the possible impact of selective preservation on quantitative palaeoenvironmental inference. We first used existing palaeoecological data sets to assess the vertical patterns of relative abundance in four testate amoeba shell types: (1) shells made of secreted biosilica plates (idiosomes, e.g. Euglypha), (2) idiosomes with thick organic coating (Assulina), (3) proteinaceous shells (e.g. Hyalosphenia), (4) shells built from recycled organic or mineral particles (xenosomes) (e.g. Difflugia, Centropyxis). In three diagrams a clear pattern of decay was only observed for the idiosome type. In order to assess the implications of differential preservation of testate amoeba taxa for paleoenvironmental reconstruction we then carried out simulations using three existing transfer functions and a wide range of scenarios, downweighting different test categories to represent the impact of selective test decomposition. Simulation results showed that downweighting generally reduced overall model performance. However downweighting a shell type only produced a consistent directional bias in inferred water table depth where that shell type is both dominant and shows a clear preference along the ecological gradient. Applying a scenario derived from previous experimental work did not lead to significant difference in inferred water table. Our results show that differential shell preservation has little impact on paleohydrological reconstruction from Sphagnum-dominated peatlands. By contrast, for the minerotrophic peatlands data-set loss of idiosome tests leads to consistent underestimation of water table depth. However there are few studies from fens and it is possible that idiosome tests are not always dominant, and/or that differential decomposition is less marked than in Sphagnum peatlands. Further work is clearly needed to assess the potential of testate amoebae for paleoecological studies of minerotrophic peatlands.     

Sliding element simulating the response of slip surfaces and its application for the prediction of earthquake-induced landslide movement using one-dimensional dynamic analyses

Landslides - Earthquake-induced landslides involve excessive movement of slopes, usually along slip surfaces. This seismic movement of slopes may depend crucially on (a) the soil response along the...     

高分辨率全球尺度水文模型发展综述

主要从高分辨率全球尺度水文模型（HRGHM）的发展历程、模型的一般结构与特点、模型数据集的发展和模型所面临的主要问题等几个方面对全球尺度水文模型的发展情况进行了综述。HRGHM能够使水文学家从全球的角度深入了解水资源的产生及循环过程,并且对相关环境问题的解决、气候的模拟与预报以及水资源的管理具有重要的意义。经过几十年的发展和努力,在全球尺度数据集的研究和发展方面已经取得了丰硕的成果,并且在HRGHM的实践中得以应用,但空间数据的缺乏仍然是其发展的最大羁绊。HRGHM所面临的问题除了数据的匮乏还在于非线性问题、尺度问题和确定性问题等水文机理和技术层面的问题。