First data on the noble metal geochemistry of the rocks from the gabbro-anorthosite massifs of the Kalar group

This paper addresses the geochemical features of the noble metal disseminated sulfide and Timagnetite mineralization in the rocks of the Kalar group of autonomous gabbro-anorthosite massifs. The investigations suggest that this mineralization was formed in two stages. The first stage is related to the gabbroanorthosites proper and may be promising for low-sulfide PGE mineralization as well as PGE-bearing Ti-magnetite mineralization, while the second stage is linked to the ultrabasic intrusions associated with copper-nickel or chromite mineralization accompanying by PGE. The horizons of low-sulfide mineralization in the gabbro-anorthosites and copper-nickel mineralization in the dunite-pyroxenites are characterized by the Pd predominance over Pt, while the Cr-bearing and Ti-magnetite ores show the Pt predominance over Pd.     

The First Results of U–Pb Isotope Dating of Detrital Zircons from the Upper Mesoproterozoic Gulliksenfellet Quartzite (Southern Part of Wedel Jarlsberg Land,Southwest Spitsbergen)

The first results of U–Pb isotopic dating (LA–ICP–MS) of detrital zircons from metasedimentary rocks of the pre-Devonian basement of the SW part of western Spitsbergen (from Upper Mezoproterozoic Gulliksenfellet quartzite) showed ages ranging from 1700 ± 25 to 2948 ± 27 Ma.     

Measuring proton energies and fluxes using EIT (SOHO) CCD areas outside the solar disk images

An indirect proton flux measuring tool based on discrimination of the energy deposited by protons in 128 × 128 pixel EIT CCD areas outside the solar disk images is presented. Single pixel intensity events are converted into proton incident energy flux using modeled energy deposition curves for angles of incidence ±60° in four EIT spatial areas with different proton stopping power. The extracted proton flux is corrected for both the loss of one‐pixel events in the range of angles of incidence as well as for the contribution to the single pixel events resulting from scattered middle‐energy protons (low‐energy or high‐energy particles are stopped by the EIT components or pass through them, accordingly). A simple geometrical approach was found and applied to correct for a non‐unique relation between the proton‐associated CCD output signal and the incident proton energy. With this geometrical approximation four unique proton incident energy ranges were determined as 45–49, 145–154, 297–335, and 390–440 MeV. The indirect proton flux measuring tool has been tested by comparing Solar Energetic Particles (SEP) flux temporal profiles extracted from the EIT CCD frames and downloaded from the GOES database for the Bastille Day (BD) of 2000 July 14 and the more recent 2005 January 20 events. The SEP flux temporal profiles and proton spectra extracted from the EIT in the relatively narrow energy ranges between 45 and 440 MeV reported here are consistent with the related GOES profiles. The four additional EIT extracted ranges provide higher energy resolution of the SEP data. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Search for spatial variation in the jovian N/N ratio from Cassini/CIRS observations

We have used the spectra obtained by the Composite Infrared Spectrometer (CIRS) onboard the Cassini spacecraft to search for latitudinal variation in the ¹⁵N/¹⁴N ratio on Jupiter. We found no variations statistically significant given the observational and model uncertainties. The absence of latitudinal variations demonstrates that ¹⁵NH₃ is not fractionated in Jupiter's atmosphere, and that the measured ¹⁵N/¹⁴N represents Jupiter's global value. Our mean value for the global jovian ¹⁵N/¹⁴N ratio of (2.22±0.52)×10⁻³ agrees with previous measurements made by Fouchet et al. (2000, Icarus 143, 223-243) and Owen et al. (2001, Astrophys. J. 553, L77-L79). We argue that the jovian isotopic ¹⁵N/¹⁴N ratio must represent the solar nitrogen isotopic composition. The solar ¹⁵N/¹⁴N ratio hence significantly differs from the terrestrial value: (¹⁵N/¹⁴N)_⊕=3.68×10⁻³. This supports the proposition that terrestrial nitrogen originates from a nitrogen reservoir isolated from the main nitrogen reservoir in the proto-solar nebula. The origin and carrier of this isolated reservoir are still unknown.     

Hydrodynamical simulations of Galactic fountains – I. Evolution of single fountains

The ejection of the gas out of the disc in late-type galaxies is related to star formation and is due mainly to Type II supernovae. In this paper, we studied in detail the development of the Galactic fountains in order to understand their dynamical evolution and their influence on the redistribution of the freshly delivered metals over the disc. To this aim, we performed a number of 3D hydrodynamical radiative cooling simulations of the gas in the Milky Way where the whole Galaxy structure, the Galactic differential rotation and the supernova explosions generated by a single OB association are considered. A typical fountain powered by 100 Type II supernovae may eject material up to ∼2 kpc which than collapses back mostly in the form of dense, cold clouds and filaments. The majority of the gas lifted up by the fountains falls back on the disc remaining within a radial distance  Δ R = 0.5 kpc  from the place where the fountain originated. This localized circulation of disc gas does not influence the radial chemical gradients on large scale, as required by the chemical models of the Milky Way which reproduce the metallicity distribution without invoking large fluxes of metals. Simulations of multiple fountains fuelled by Type II supernovae of different OB associations will be presented in a companion paper.     

Output-only identification of the modal and physical properties of structures using free vibration response

The viability of a complete structural characterization of civil structures is explored and discussed. In particular, the identification of modal (i.e. natural frequencies, damping ratios and modal shapes) and physical properties (i.e. mass and stiffness) using only the structure’s free decay response is studied. To accomplish this, modal analysis from free vibration response only (MAFVRO) and mass modification (MM) methodologies are engaged along with Wavelet based techniques for optimal signal processing and modal reconstruction. The methodologies are evaluated using simulated and experimental data. The simulated data are extracted from a simple elastic model of a 5 story shear building and from a more realistic nonlinear model of a RC frame structure. The experimental data are gathered from shake table test of a 2-story scaled shear building. Guidelines for the reconstruction procedure from the data are proposed as the quality of the identified properties is shown to be governed by adequate selection of the frequency bands and optimal modal shape reconstruction. Moreover, in cases where the structure has undergone damage, the proposed identification scheme can also be applied for preliminary assessment of structural health.     

The influence of minerals on the pyrolysis of kerogens

The effect of mineral matter on the laboratory pyrolysis of sediments, kerogens and coals, and of coal macerals mixed with either alumina, bentonite, kaolinite, or calcium carbonate has been investigated. Some minerals are more active than others in effecting changes in the composition of the pyrolysate. The relative content of low molecular weight pyrolysis products is higher for kerogens pyrolyzed in a mineral matrix than for isolated kerogens. Our limited data suggests that this is due to both condensation and gasification of higher molecular weight constituents in the ‘primary’ pyrolysate. Differences in the content of aromatic versus aliphatic compounds have been noted when pyrograms from coal macerals are compared with pyrograms from coal maceral-mineral mixtures. We conclude that mineralogy is important in controlling the composition of kerogen pyrolysis products.     

Biostratigraphy and depositional facies of the Cretaceous-Tertiary boundary strata in Amakusa-Shimojima,Kyushu, Western Japan

The Upper Himenoura Subgroup exposed in the island of Amakusa-Shimojima, Kyushu, Japan shows an example of the terminal Cretaceous stratigraphic record in the circum Pacific region. This sequence is a part of the Upper Cretaceous intra-arc basins of southwest Japan. Four cycles of upward coarse-graded facies are recognized. Each cycle consists of a basinal mud facies in the lower part and a tide-dominated shallow marine to brackish coarse clastic facies in the upper part. Biostratigraphic correlation chiefly based on ammonites, inocerami and trigoniids indicates that this sequence is Campanian to Maastrichtian in age. The occurrence of the above three fossils decreases upward and is terminated at the top of the sequence, being replaced by a molluscan assemblage similar to the Danian. This suggests that the sedimentation may have continued to the very end of the Cretaceous period and possibly to the beginning of the Tertiary.     

EVIDENCE FOR THE PRESENCE OF LOW MOLECULAR WEIGHT ALCOHOLS AND CARBONYL COMPOUNDS IN THE MURCHISON METEORITE†

Alcohols, aldehydes and ketones identified in the Murchison C2 chondrite include: methanol, ethanol, 2-propanol, butyl alcohols, formaldehyde, acetaldehyde, propionaldehyde, acetone, 2-butanone, 3-pentanone and 2-pentanone.