内陆水体溶解无机碳同位素研究进展及展望

碳是陆地生态系统中最重要的生命元素,能够在各个圈层之间相互转换和运移。碳循环作为地球各圈层相互连接的纽带,被认为是地表系统最重要的元素地球化学循环。碳在水体中主要以溶解性有机碳（dissolved organic carbon,简称DOC）和溶解性无机碳（dissolved inorganic carbon,简称DIC）形式存在。内陆水体（包括河水、地下水、湖水和水库等）尽管只占陆地表面1%,但它们在碳循环过程中发挥了重要作用。其DIC浓度(CDIC)和DIC同位素组成(δ13CDIC)可以为碳循环研究提供线索,因此成为近年来国际研究的热点之一。本文系统总结了全球内陆水体DIC同位素的研究进展。DIC同位素具有广泛的地质应用,不同碳源具有独特的同位素特征。因此,DIC同位素被用于定性和定量地示踪碳源,指示碳循环过程以及确定河水补给端元。     

柴达木盆地西部地下卤水水化学特征及成因分析

柴达木盆地西部有着丰富的地下卤水资源。通过野外实地考察取样,参考已有数据资料,选择了资源丰富,区域代表性强的柴达木盆地西部茫崖拗陷,特别是中部油墩子—南翼山背斜构造单元的地下油田卤水为主要研究对象;分析了其基本水化学特征,在此基础上初步探讨了卤水的成因、演化和物源信息,为进一步开发利用卤水资源,特别是评价其资源开发潜力有一定指导意义。     

广东硇洲岛地下水化学演化及成因机理

地下水一直是广东硇洲岛唯一的水资源,但近年来许多地区地下水咸化趋势加剧,严峻威胁着岛上居民的用水安全,研究地下水化学演化及成因机理,对预防和减缓水质变咸意义重大。本文结合区域水文地质条件、地形地貌条件及水化学资料分析了整个岛屿地下水水质状况,在此基础上采用Piper三线图研究了水化学特征,并利用PHREEQC软件对水文地球化学演化规律进行模拟研究,结果表明:(1)海水入侵是造成地下水咸化的主要原因,咸化对水质的影响主要表现为Cl-的增加,Ca2+在区分该地区不同水体时反应灵敏,是良好的识别指标之一;(2)海水入侵的过程中,过渡带前缘不存在经受长期古海水演化而成的卤水与地下淡水的混合作用,地下水中Mg2+、Ca2+与Na+之间存在着强烈的离子交换,石膏、白云石及方解石处于不饱和状态;(3)浅层地下水与深层地下水之间无明显的水力联系,属于相对独立的地下水流系统。在全球变暖,海平面上升的总趋势下,海岛地下水开发必须合理规划、严格管理,以防引发大规模海水入侵灾害的发生。     

Geochemistry of Brines from Salt Ore Deposits in Western Tarim Basin

In the geological evolution of the Tarim Basin, many transgressions and relictions happened. So there have been plentiful sources of salt. Moreover, because of uttermost drought, a lot of salt has been deposited. It is possible to find potash salt in this area. In our fieldwork, we have found salt and brine in western Tarim Basin. Based on a geological survey and the characteristics of sedimentary facies and paleogeography, this paper deals with the geochemical parameters and discusses the possibility of formation of potash salt in terms of the chemical analyses of samples collected from western Tarim Basin. Results of brine analysis lead to some conclusions: most of these salt brines have eluviated from very thick halite beds, mainly chloridetype salt and this kind of halite does not reach the stage of potash deposition in all aspects; WKSL (Wukeshalu) occupies a noticeable place, and we should attach importance to this district because there have been some indicators of the occurrence of potash deposits as viewed from the contents of Br and K. Finally, low Br contents are recognized in the Tarim Basin as a result of salt aggradation, and this point of view has been proved by the results of this experiment and the data available. It cannot depend upon the index of Br to judge the evolution stage of halite. We must look for other facies of potash except marine facies.     

The Paleo－Environmental Significance of Sr and Ca Contained in Acid－Soluble Fraction of Plateau Loess Deposits in Xining Basin

The Xining Basin,located on northeastern Qinghai-Xizang Plateau,is adjacent to the Qaidam Bsim and Gobi-desert.Therefore,thick,integrated deposits of loess or paleo-sol sequence were well developed.As is well known,there is much paleo-environmental information recorded in loess and plaeo-sol.So if we deal with paleo-environmental index from different an gles ,especially from loess geochemistry,some important and detailed paleo-environmental evolutional information will be acquired.Based on this,the authors determined the contents of Sr and Ca contained in acid-soluble fraction from the bottom to the top of the Panzishan section.This section was obtained through making a well about 17 m in depth,including S1 paleo-sol that was developed during the last interglacial period.According to the results,it is found that variations in contents of Sr and Ca are well correlated with conversion of loess and paleo-sol.In loess deposits,the contents of Sr and Ca are higher than those in paleo-sol deposits.It is known that loess was deposited under cold-dry climate conditions and paleo-sol was developed during warm-humid climate episodes.It is concluded that due to their mobile behaviors,under cold-dry climate conditions,Sr and Ca are stagnant during weak weathering,but under warm-humid climate conditions,Sr and Ca are easily leached and transported in aqueous solution.Therefore,they can be utilized as indicatiors of climate changes.Moreover,variations in contents of Sr and Ca are more sensitive than susceptibility.The mobile behaviors of Sr and Ca contained in acid-soluble fraction can serve as a new quantitative index to evaluate paleo-environmental changes on the plateau.     

塔里木盆地西部古岩盐地质地球化学特征与成钾条件分析

塔里木盆地是我国重要的成盐盆地,为我国最有远景的找古钾矿地区之一。本文通过多年野外实地调查和大量岩盐样品的化学分析,特别是岩盐中可以指示沉积阶段的Br×103/Cl系数等区域分布特征,联系前人研究资料,分别从构造环境、地层和岩相古地理、地球化学特征等方面进行了成钾条件分析。结果表明,莎车盆地西部喀什坳陷和库车盆地中部拜城坳陷宏观地质特征均有利于钾盐沉积;岩盐地球化学组成相对于正常海相沉积表现出明显的贫Br特征,属海陆交互相或海源陆相沉积。相比之下,莎车盆地的喀什次级坳陷是目前最有前景的找钾远景区。     

西藏麻米错富硼锂盐湖成矿物质平衡计算与物质来源

麻米错盐湖是西藏境内发育的特大型锂矿床之一,目前对该盐湖的Li、B来源仍存在一定争议。文章系统采集麻米错盐湖水及周边补给水体样品,分析其主量元素特征,并使用多种水化学手段进行讨论,同时对盐湖水、河水及地热水进行蒸发模拟。结果表明,研究区河水及泉水中的主要离子受控于流域内岩石风化作用,其中碳酸盐岩矿物与蒸发岩矿物贡献最大,其次是硅酸盐矿物。文章对补给水体输入盐湖的Li、B资源进行定量计算,得出单纯通过河水和泉水的输入无法形成盐湖目前的探明储量。选择西藏地区最为富Li的地热水同补给水体按照一定比例混合后进行蒸发模拟,发现其析盐序列与盐湖水的析盐序列存在很大程度上的重叠,以上均证明麻米错盐湖中的Li、B资源除受到周边河水及泉水的补给外,还受到地热水的补给。     

西藏尼木地区遥感数据地温反演与地热异常预测

为探明西藏尼木地区地热资源的空间分布及指导该区地热资源的勘探与开发,选取2010年1月21日与2月22日的Landsat 5TM数据,基于单波段的单窗算法进行地表温度反演,并利用ArcGIS软件分析了地表温度、已有地热异常点、构造及人类活动之间的关系,对该区潜在的地热异常进行预测。结果表明,地表温度分别为： -21.75～40.65 ℃,-18.95～46.45 ℃,二者进行对比分析表明反演结果符合实际且结果可靠。依据遥感数据地温反演结果,发现区内温度异常区比背景区高10 K以上,研究区存在未被发现的隐伏断层及地热活动异常信息,由此划分出21个潜在地热异常区。结论认为位于亚东—谷露与雅鲁藏布江缝合带交汇区的尼木地区地热异常特征明显,勘探开发前景广阔;在高寒缺资料区基于遥感单窗算法进行温度反演,可以有效提取地热异常信息,帮助预测具有开发前景的地热异常区,并进一步识别圈定具有勘探意义的靶区。     

老挝东泰钾盐矿床地球化学及其沉积后变化初步研究

呵叻高原是世界上最大的钾盐沉积矿床分布区之一,研究区位于呵叻高原北部的沙空那空盆地东部边缘,钻探资料揭示该地区钾盐资源相当可观。该含盐建造包含上、中、下3个盐段,每个盐段都由一套蒸发岩_碎屑沉积旋回组成,钾盐层主要赋存于下盐段上部。剖面和地层学分析表明,研究区盐构造类型为低结构低成熟度的盐背斜构造,盐体几何形态为一低结构低成熟度的盐背斜,盐背斜轴部矿层厚度较两翼矿层厚得多。岩盐中微量元素Br、K含量及Br×1 000/Cl系数的变化指示成盐卤水经过了阶段性的浓缩和淡化过程,并且成盐作用越来越弱。ZK04孔较低的Br含量〔w(Br)=18×10〈sup>-6〈/sup>〕表明下膏盐层在成盐过程中受到了非海相流体的影响。中膏盐层基底石盐中高K低Br特征表明,下膏盐层残余高浓度卤水影响了其成盐过程,并且该基底石盐很可能又经历了溶解和重结晶过程。     

青海湖南岸黑马河黄土剖面碳酸盐含量与记录的古气候变化

在青海湖南岸黑马河2.2 m厚的黄土剖面中,以5 cm的间隔采样,进行了碳酸盐、碳酸盐中Sr含量以及磁化率的测定,通过对比分析研究了12.7 ka以来青海湖湖区古气候的变化,结果表明碳酸盐、碳酸盐中Sr含量、磁化率等基本较真实的记录了该区自12.7 kaBP以来经历的多次暖湿—干冷古气候变化过程。