沉积岩包裹体烃源条件时间温度指数判别法的探讨--以鄂尔多斯下古生界为例

包裹体在油气地质邻域的应用,是近年来包裹体研究的热点和难点。本文探索性地运用沉积岩中包裹体测试数据计算烃源岩主要生烃时期的时间温度指数(TTI),对沉积盆地的烃源条件进行判别。首先利用鄂尔多斯下古生界包裹体显微测温数据求取捕获温度、计算古地温梯度,得出动态古地温曲线;然后计算出下古生界烃源岩的门限。奥陶系烃源岩生烃门限时间为280～131Ma,相当于二叠纪至侏罗纪,其对应的生烃门限温度为70～115℃,门限深度2100～3400m,生烃高峰期为181.4～149.6Ma,相当于侏罗纪中晚期。在生烃高峰期该层位的温度为110～115℃,埋深3300～3400m。和实际主要产气层分布相一致,说明了应用沉积岩包裹体计算时间温度指数,对烃源条件进行判别这种方法的有效性。     

郯庐断裂带南段双山韧—脆性剪切带物质迁移与CO2释放研究

根据动力变质作用的特点，在野外和室内正确鉴别区分郯庐断裂安徽肥东双山一带不同变质等级的动力变质带的矿物组合特点，应用体积亏损-元素得失方程，计算了在应力作用条件下，不同变质带内，不同等级的碳酸盐岩地层的各元素（组分）的得失状况，特别仔细地深入地模拟计算了不同岩性的动力变质岩的构造应力作用下的CO2的释放量和释放机制，从而为探讨和研究动力变质作用下，碳酸盐岩地区岩石生成CO2的过程提供理论和实践上的依据。     

洋中脊俯冲与中国东部中生代地质事件

洋底扩张与俯冲带的交叉是令人感兴趣的主题[1],最早始于对美国西部造山作用的研究[2],然后洋中脊-海沟相互作用就成了一个热门话题.其中一个关键问题是俯冲过程中洋盆的消耗通常把洋底扩张中的洋中脊带向深海沟,即洋中脊俯冲.     

Geochemical studies on REE and trace elements from several Cu-Au deposits along the lower Yangtze metallogenic valley, central-southern Anhui Province

The Yangtze Valley was one of the most important metallogenic regions during the Jurassic-Cretaceous period in East China, where more than 200 polymetallic Cu-Fe-Au, Mo, Zn, Pb, Ag deposits have been found. Trace elements were chemically analyzed and the relevant data were collected from literature for the Yanshanian (Mesozoic) igneous rocks which have close relationship with Cu-Au mineralization. Copper mineralization in the lower Yangtze Valley can be divided into three major types: skarn type, porphyry type and volcanic type. The porphyry type is of rare occurrence, such as the Shaxi porphyry copper deposit in the northern part of the lower Yangtze metallogenic valley. This paper focuses on the REE and trace element geochemistry of several Cu-Au deposits along the lower part of Yangtze metallogenic valley in Anhui. The results showed that there are differences in REE distribution for these four types of Cu-Au mineralization, which confine the sources of REE and trace elements as well as other mantle and transitional compatible elements. The results of both REE and trace element geochemical studies showed that these elements with different characteristics have different origins, probably representing different sources of Cu-Au deposits in the deep crust and upper mantle environments. The 40Ar/39Ar dating of one biotite sample gave an age of 131 Ma with a high level of confidence, which represents the age of formation of the Shaxi porphyrite intrusive with porphrytic Cu-Au mineralization, which is consistent with that of the majority of the adjacent acid intrusives with mass Cu-Au mineralization along the Yangtze metallogenic belt in the Yanshanian period (Mesozoic). This is the first attempt to use the high precision method to date the Shaxi porphyrite intrusive.     

REE/trace element characteristics of sandstone-type uranium deposits in the Ordos Basin

Erratum:Chin. J. of Geochem. DOI: 10.1007/s11631-006-0354-y Table 3 on page 360 is incorrect and should be replaced by the table below.Table 3. The results of analysis of trace elements for the sandstone-type uranium deposit samples from the Ordos Basin (…     

华北克拉通南缘张士英岩体大陆动力学背景:来自地球化学、锆石U-Pb年龄和Hf同位素的证据

张士英岩体位于华北克拉通南缘,岩体主要由石英正长岩组成。石英正长岩的LA-ICP-MS锆石U-Pb年龄为122.8±1.5Ma。其Si O2含量为66.04%~67.80%,Na2O+K2O=9.03%~10.97%,K2O=4.40%~6.37%,K2O/Na2O1属于钾质长英质岩石。A/CNK=1.26~1.58,A/NK=1.63~1.79属于过铝质岩石系列。石英正长岩的Mg#变化范围在12.9~39.4。富集LREE亏损HREE,轻重稀土分异明显,(La/Yb)N=15.48~21.12,Eu呈弱的负异常(δEu=0.54~0.99)。富集Rb、K、Th、U等大离子亲石元素,亏损Nb、Ta、P、Ti等高场强元素。张士英石英正长岩岩浆锆石εHf(t)集中在-17.6~-13.9,Hf两阶段模式年龄tDM2集中在1.7~1.9Ga。石英正长岩的岩浆Zr饱和温度高(936~998℃)。地球化学及同位素显示张士英石英正长岩源区主要为古老的壳源物质,并有少量年轻组分加入,这种年轻组分是幔源物质。岩体形成于拉张性构造环境下,拉张性的环境导致了幔源物质的上涌,底侵下地壳使其发生部分熔融。形成时代正好位于华北克拉通破坏峰期,张士英石英正长岩正是这一地质事件的响应。     

钼的地球化学性质与成矿

钼在硅酸盐地球中的丰度很低,作为中度不相容元素,简单的岩浆形成、演化过程很难使之从地壳丰度直接富集到工业品位。我们研究结果显示钼的成矿主要通过两阶段富集过程来实现:一是与风化、沉积有关的表生过程;二是与板块俯冲或深埋熔融有关的岩浆过程。钼是变价元素,在寒武纪大气氧再次升高以后,钼在地表化学风化过程中容易被氧化为水溶性的Mo O42-,进入地表径流和海洋湖泊中,并且在还原条件下进入富含有机质的黑色页岩等沉积物(岩)中。富钼沉积物(岩)在随板块俯冲到地幔或深埋等条件下可以因升温变质,进而发生部分熔融,形成富钼的原始岩浆,在俯冲条件下往往形成斑岩铜(金)钼矿床,氧逸度低于斑岩铜矿,而斑岩钼矿的氧逸度更低。具有高化学风化速率、大的流域面积的封闭、半封闭型水域和河口地区是表生过程中钼富集的最佳区域,是大型钼矿形成的基础。     

长江中下游成矿带抛刀岭大型斑岩型金矿特征及找矿前景

抛刀岭金矿位于长江中下游成矿带安庆—池州矿集区,累计金金属量大于22t,为池州地区首例大型金矿床。该矿床金矿体主要产在英安玢岩中,基本不伴生其他有益金属元素,为独立金矿床。通过详细的矿床地质特征描述,结合已有斑岩型金矿的成矿模式,同时利用以往对该含矿岩体U-Pb锆石定年及相关地球化学研究,综合分析认为该矿为产在早白垩纪岛弧背景下的贫铜斑岩型金矿床,同时局部矿段在成矿过程中还经历了热液叠加作用。矿体产出严格受NE向构造-岩浆岩带控制,含矿岩体出露面积小于1.0km2,属于典型的小岩体成大矿。运用"相似类比"、"矿床谱系"、"趋势外推"、"综合信息评价"等原则,指出该矿具有特大型金矿的潜质;同时,受同一NE向构造控制的乌石、白虎山及自来山等同期岩浆岩发育地区,具有与抛刀岭金矿类似的成矿条件,是未来工作的重点靶区;发育于上述同期岩浆岩之间的志留纪地层中的破碎带蚀变岩、与斑岩型矿床配套产出的低温热液多金属硫化物型矿床等,都将是外围工作的重点研究地区。     

庐江沙溪斑岩型铜金矿床构造-岩浆-矿化特征

1区域地质及构造演化安徽庐江沙溪板岩型铜金矿矿区位于扬子陆块北缘下扬子地块沿江褶断带北部巢湖构造带内,沿江褶断带在震旦世隆起已很明显,隆起区沉积厚度不足400m,而两侧坳陷区则可达上千米,这种状态持续到寒武纪末,奥陶纪至志留