Store Mosse (the ‘Great Bog’ in Swedish) is one of the most extensive bog complexes in southern Sweden (~77 km2), where pioneering palaeoenvironmental research has been carried out since the early 20th century. This includes, for example, vegetation changes, carbon and nitrogen dynamics, peat decomposition, atmospheric metal pollution, mineral dust deposition, dendrochronology, and tephrochronology. Even though organic matter (OM) represents the bulk of the peat mass and its compositional change has the potential to provide crucial ecological information on bog responses to environmental factors, peat OM molecular composition has not been addressed in detail. Here, a 568-cm-deep peat sequence was studied at high resolution, by attenuated reflectance Fourier-transform infrared spectroscopy (FTIR-ATR) in the mid-infrared region (4000–400 cm–1). Principal components analysis was performed on selected absorbances and change-point modelling was applied to the records to determine the timing of changes. Four components accounted for peat composition: (i) depletion/accumulation of labile (i.e. carbohydrates) and recalcitrant (i.e. lignin and other aromatics, aliphatics, organic acids and some N compounds) compounds, due to peat decomposition; (ii) variations in N compounds and carbohydrates; (iii) residual variation of lignin and organic acids; and (iv) residual variation of aliphatic structures. Peat decomposition showed two main patterns: a long-term trend highly correlated to peat age (r = 0.87), and a short-term trend, which showed five main phases of increased decomposition (at ~8.4–8.1, ~7.0–5.6, ~3.5–3.1, ~2.7–2.1 and ~1.6–1.3 ka) – mostly corresponding to drier climate and its effect on bog hydrology. The high peat accumulation event (~5.6–3.9 ka), described in earlier studies, is characterized by the lowest degree of peat decomposition of the whole record. Given that FTIR-ATR is a quick, non-destructive, cost-effective technique, our results indicate that it can be applied in a systematic way (including multicore studies) to peat research and provide relevant information on the evolution of peatlands. 相似文献
This study investigates the stratigraphical sequence of Cocina Cave (Spain) employing and testing for the first time the capability of rare earth elements as markers of human activities in caves. Located in Dos Aguas (Valencian Community, Spain), Cocina Cave is characterized by the presence of several Holocene archaeological deposits from the final Mesolithic to the present day and is a pivotal site for understanding the socio-ecological dynamics of the last hunter-gatherer inhabitants of the Iberian Peninsula and the transition to pastoral and agricultural economies in the Western Mediterranean. However, the identification of strata from particular time-periods in the cave is often difficult due to the homogeneity of layers, the poor archaeological record in some strata and the presence of severe disturbance phenomena. The methodological approach of this study consisted of cross-referencing rare earth elements and other chemical markers with the archaeological stratigraphical interpretation, in an attempt to not only support the identification of the anthropic contribution to the formation of Cocina Cave strata, but also to characterize and confirm different natural and occupational episodes, particularly those associated with hunter-gatherer, early agriculturalist, and shepherd activities. Sediments were collected from different excavation areas and analysed for major elements, trace elements, rare earth elements (REE), soil organic matter (SOM) amounts and pH. Multivariate statistics were employed to group samples according to their elemental profile, and these were then compared to the archaeological temporal interpretation. The obtained results showed that REE amount and fractionation geochemical processes were regulated by carbonates, phosphates and pH. The use of REE as markers was particularly useful as their concentrations and their calculated ratios and anomaly distributions were demonstrated to be highly consistent with the archaeological stratigraphical interpretation. 相似文献
Geoarchaeological investigations on the northeastern shore of Lake Ohrid revealed 3.5 m thick deepwater lacustrine sediments overlying terrestrial vegetation macrofossils, worked wood and abundant potsherds dated to the Late Bronze Age (LBA). Distinct contact of deepwater sediment with the sub-aerial weathered limestone bedrock point to a sudden increase in lake level. According to radiocarbon data, catastrophic flooding occurred shortly after 1214 yr bc. Because the area is located in a highly active seismic zone, we propose that this event was caused by tectonically induced, metre-scale coseismic subsidence related to faults bordering the Ohrid alluvial plain. Moreover, this event coincides well with a dramatic switch in the habitation and settlement strategy in the region. More important, however, is the finding that the age of the proposed massive tectonic event and change in habitation lies within the interval of the proposed ‘earthquake storm’ in the eastern Mediterranean dated to 1225–1175 bc. As the Ohrid-Korça zone belongs to the same tectonic province, a relationship between the abovementioned earthquakes and the proposed event can be expected. This research therefore might provide the first direct evidence of a large-scale earthquake event linkable to the LBA collapse of Europe's first urban civilisation in the Aegean. 相似文献
Acta Geotechnica - The experimental data dealing with the so-called small strain stiffness of soils are indispensable in developing and calibrating advanced numerical models. A literature review... 相似文献
Having a better understanding of air pollutants in railway systems is crucial to ensure a clean public transport. This study measured, for the first time in Brazil, nanoparticles (NPs) and black carbon (BC) on two ground-level platforms and inside trains of the Metropolitan Area of Porto Alegre (MAPA). An intense sampling campaign during thirteen consecutive months was carried out and the chemical composition of NPs was examined by advanced microscopy techniques. The results showed that highest concentrations of the pollutants occur in colder seasons and influenced by variables such as frequency of the trains and passenger densities. Also, internal and external sources of pollution at the stations were identified. The predominance of NPs enriched with metals that increase oxidative stress like Cd, Fe, Pb, Cr, Zn, Ni, V, Hg, Sn, and Ba both on the platforms and inside trains, including Fe-minerals as hematite and magnetite, represents a critical risk to the health of passengers and employees of the system. This interdisciplinary and multi-analytical study aims to provide an improved understanding of reported adverse health effects induced by railway system aerosols. 相似文献
Empirical evidence has shown that particle breakage affects the mechanical behaviour of granular materials. The source of this mechanism takes place at the particle scale, and the main consequence on the macromechanical behaviour is increasing compressibility. Due to the inverse correlation between particle size and particle crushing strength, coarse rockfill materials are particularly vulnerable to mechanical degradation due to particle breakage. However, such coarse materials do not fit in standard laboratory devices, and the alternative of large sample testing is usually unavailable or too expensive. Alternatively, recent works have proposed multi-scale approaches using the discrete element method (DEM) to carry out numerical testing of coarse crushable materials, although few studies have focused on size effects. This article presents the application of a DEM bonded-cell model to study particle size-strength correlation on angular rock aggregates. Each particle is modelled by a cluster of perfectly rigid polyhedral cells with Mohr–Coulomb contact law. Constant cell density within particles implies that the presence of potential fragmentation planes increases with size. Therefore, particle strength decreases with size. A comprehensive sensitivity analysis was carried out through 1477 particle crushing simulations in a given particle size. Based on published experimental data on calcareous rock aggregates, part of the simulations were used for calibration, and 97 additional simulations of a coarser size fraction were performed for validation. The results show a good agreement with the empirical data in terms of size effect and data scatter through Weibull statistics.