Mass balance of mercury in the Mediterranean Sea

The Mediterranean Basin is rich in mercury from natural and anthropogenic sources. During an extensive research from 2002–2005, measurements of different mercury forms were carried out in the Mediterranean Sea by the Italian research vessel Urania as a part of the Med Oceanor and MERCYMS projects funded by the EU Framework programme. Further on, transport and fate of mercury forms was simulated in water and air compartments by two different models, and an approximate coupling of both models was performed. The new 3-dimensional model PCFLOW3D was completed with the first version of a biogeochemical module which deals with various mercury species in dissolved and particulate forms. Exchange with the bottom and the atmosphere, methylation, demethylation, reduction and oxidation were taken into account. Based on the integrated hydrodynamic-atmospheric model and results of field measurements the mass balance of total mercury in the Mediterranean Sea was determined in order to estimate main sources and sinks and simulate future trends of mercury contamination in the Mediterranean. The following terms were taken into account: sources of mercury from major rivers and from point sources, exchange with the Atlantic Ocean and the Black Sea, estimated natural sources from geotectonic active areas in the sea, exchange with bottom sediments, and evasion to and deposition from the atmosphere.     

Spatial variations and controls of acid mine drainage generation

Spatial variations of historical and ongoing pyrite oxidation rates were quantified near the Nanisivik Mine on Baffin Island in northern Canada. The variations observed depend mainly on the degree of water saturation, pH and temporal trends in mineral reactivity. Maximum oxidation rates were observed in an untreated tailings spill, while minimum oxidation rates were noted for tailings deposited under water. Spatial trends in oxidation rates were in the order of three orders of magnitude. Spatial trends were only possible to quantify by a combination of closed chambers (well-drained conditions) and micro sensors (water-covered conditions). Oxygen uptake rates in tailings at various ages (up to 7 years) indicate a decrease by more than a factor of 3 over time. Total oxygen uptake over 7 years was calculated and found to be in a fair agreement with the overall pyrite depletion evaluated as high-resolution mineral mass balance (by quantitative powder X-ray diffraction).     

Modification of the degree-day formula for diurnal meltwater generation and refreezing

Theoretical and Applied Climatology - The standard degree-day, temperature-index approach to calculating snowmelt generation and refreezing (the SDD method) is convenient and popularly used but...     

Late cretaceous volcanogenic flysch and diabase-chert formations in the Yugoslav Inner Dinarides

In the Turonian and Maastrichtian, the “Diabase-chert Formation” and the “Volcanogenic flysch” were formed as two specific rock series, due to the synchronous basic volcanism of the Drenica area in Kosovo (Yugoslavia). Comparison with other localities of the Inner Dinarides has proved that, regardless of their different stratigraphic position, each of these two formations exhibits in individual localities great lithological and structural similarities. Both formations are associated with large tectonic zones with ophiolitic occurrences which extend from the Alps through the Yugoslav Inner Dinarides, northern and northeastern Greece, part of Turkey (Asia Minor) and further southeast.The Diabase-chert Formation is a lateral facies of Turnonian limestone. It is represented by a characteristic regime of a specific geochemical character, brought about by synchronous basic volcanism, and by the introduction of volcanogenic components — these factors are responsible for great lithological diversity and very rapid lateral and vertical changes. A certain consistency in the lithological composition is only noticable in the closing horizons of this formation at its transition into limestone sediments.The volcanogenic flysch was formed as a result of subvolcanic activity synchronous with flysch sedimentation whereby semi-consolidated flysch sediments acquired certain volcanogenic-sedimentary characteristics. The most intensively disturbed parts around submarine flows of diabase have been recognized as the “zone of highly disturbed flysch”. The zone is conformably overlain by the stratified cherty-clayey zone. This continues into the “zone of ball sandstone”, and ends with the “zone of normal flysch”. Their newly acquired characteristics resulting from synchronous basic volcanism distinguish them clearly from normal flysch and make them a special type of flysch — the volcanogenic flysch.     

Timing, styles, and kinematics of Cambro–Ordovician extension in the Teplá–Barrandian Unit, Bohemian Massif, and its bearing on the opening of the Rheic Ocean

This paper describes late Cambrian dikes and Early Ordovician volcano-sedimentary successions of the Prague Basin, Bohemian Massif, to discuss the timing and kinematics of breakup of the northern margin of Gondwana. Andesitic dikes indicate minor E–W crustal extension in the late Cambrian, whereas the Tremadocian to Dapingian lithofacies distribution and linear array of depocenters suggest opening of this Rheic Ocean rift-related basin during NW–SE pure shear-dominated extension. This kinematic change was associated with the onset of basic submarine volcanism, presumably resulting from decompression mantle melting as the amount of extension increased. We conclude from these inferences and from a comparison with other Avalonian–Cadomian terranes that the rifting along the northern Gondwana margin was a two-stage process involving one major pulse of terrane detachment in the early Cambrian and one in the Early Ordovician. While the geodynamic cause for the former phase remains unclear, but still may include effects of Cadomian subduction (roll-back, slab break-off), isostatic rebound, or mantle plume, the incipient stage of the latter phase may have been triggered by the onset of subduction of the Iapetus Ocean at around 510 Ma, followed by advanced extension broadly coeval (Tremadocian to Darriwilian) in large portions of the Avalonian–Cadomian belt. Unequal amounts of extension resulted in the separation and drift of some terranes, while other portions of the belt remained adjacent to Gondwana.     

High-Frequency and Low-Frequency Variability in Stochastic Daily Weather Generator and Its Effect on Agricultural and Hydrologic Modelling

The high-frequency and low-frequency variabilities, which are often misreproduced by the daily weather generators, have a significant effect on modelling weather-dependent processes. Three modifications are suggested to improve the reproduction of the both variabilities in a four-variate daily weather generator Met&Roll: (i) inclusion of the annual cycle of lag-0 and lag-1 correlations among solar radiation, maximum temperature and minimum temperature, (ii) use of the 3rd order Markov chain to model precipitation occurrence, (iii) applying the monthly generator (based on a first-order autoregressive model) to fit the low-frequency variability. The tests are made to examine the effects of the three new features on (i) a stochastic structure of the synthetic series, and on (ii) outputs from CERES-Wheat crop model (crop yields) and SAC-SMA rainfall-runoff model (monthly streamflow characteristics, distribution of 5-day streamflow) fed by the synthetic weather series. The results are compared with those obtained with the observed weather series.Results: (i) The inclusion of the annual cycle of the correlations has rather ambiguous effect on the temporal structure of the weather characteristics simulated by the generator and only insignificant effect on the output from either simulation model. (ii) Increased order of the Markov chain improves modelling of precipitation occurrence series (especially long dry spells), and correspondingly improves reliability of the output from either simulation model. (iii) Conditioning the daily generator on monthly generator has the most positive effect, especially on the output from the hydrological model: Variability of the monthly streamflow characteristics and the frequency of extreme streamflows are better simulated. (iv) Of the two simulation models, the improvements related to the three modifications are more pronounced in the hydrological simulations. This may be also due to the fact that the crop growth simulations were less affected by the imperfections of the unmodified version of Met&Roll.     

K-guarding of polyhedral terrain

Site visibility analysis is an important research topic with many applications in Geographical Information Systems. This paper introduces a new paradigm in terrain guarding, called k-guarding. K-guarding is a generalization of the classic guarding problem where, instead of only one guard, each surface patch is guarded by at least k guards. Afterwards, two optimization problems based on k-guarding are defined: an optimum k-guarding, and a constrained k-guarding. There are three heuristic approaches—k-greedy add, k-stingy drop, and k-reverse greedy—that are proposed as a solution to the above-mentioned optimization problems. The first two are known approaches adapted to k-guarding, while k-reverse greedy is a new, original heuristic. The heuristics are compared using actual topographic surfaces. It is shown that our approach (k-reverse greedy) gives on average the best near optimum solutions. The most surprising finding of the experiments is that the combination of heuristics introduced here yields even better results.