Arsenic Speciation in Lichens and in Coarse and Fine Airborne Particulate Matter by HPLC–UV–HG–AFS

A three-step sequential extraction procedure with Milli-Q, CaCl₂ and H₃PO₄ was applied for extraction of arsenic species in lichen transplants and airborne particulate matter (fine and coarse fractions). The samples used in this work were collected in 1994–1995 near coal-fired power plants. Both transplant lichens and airborne particulate matter were submitted to the same environment simultaneously. Arsenic species identification and quantification was performed by HPLC–UV–HG–AFS. Inorganic forms of arsenic (arsenite and arsenate) were present in significant amounts in most of the samples. Only in lichens also organic forms of arsenic (monomethyl arsonic acid and dimethyl arsinic acid) were identified which may indicate biotransformation of inorganic arsenic.     

Ground Surface Temperature History in Poland in the 16th–20th Centuries Derived from the Inversion of Geothermal Profiles

Ground Surface Temperature (GST) history in Poland was derived from the inversion of temperature-depth profiles in over 20 wells. Temperature histories for the period 1500 A.D. through 1977 A.D. agree well with the instrumental record of the surface-air temperature available for the last two centuries. A statistical correlation of the reconstructed histories (from the well temperature data) with the instrumental record (air temperature) from the homogeneous Warsaw series is high (>0.8). Functional space inversion (FSI) of the temperature data with depth shows that beginning in the early 19th century, temperatures warmed by 0.9 ± 0.1°C following a long period of colder climate before. The last number could be a minimal as higher warming was calculated using a simple model based on surface temperature for the observational period (homogenized Warsaw surface temperature series, Lorenc, 2000) and POM (pre-observational mean; Harris and Chapman, 1998) of –1.53^oC below the 1951–1980 mean temperature level.     

Detection and quantification of local anthropogenic and regional climatic transient signals in temperature logs from Czechia and Slovenia

The paper reports on detection and quantification of the impact of local anthropogenic structures and regional climatic changes on subsurface temperature field. The analyzed temperature records were obtained by temperature monitoring in a borehole in Prague-Spo?ilov (Czechia) and by repeated logging of a borehole in ?empeter (Slovenia). The observed data were compared with temperatures yielded by mathematical 3D time-variable geothermal models of the boreholes’ sites with the aim to decompose the observed transient component of the subsurface temperature into the part affected by construction of new buildings and other anthropogenic structures in surroundings of the boreholes and into the part affected by the ground surface temperature warming due to the surface air temperature rise. A direct human impact on the subsurface temperature warming was proved and contributions of individual anthropogenic structures to this change were evaluated. In the case of Spo?ilov, where the mean annual warming rate reached 0.034°C per year at the depth of 38.3?m during the period 1993–2008, it turned out that about half of the observed warming can be attributed to the air (ground) surface temperature change and half to the human activity on the surface in the immediate vicinity of the borehole. The situation is similar in ?empeter, where the effect of the recently built surface anthropogenic structures is detectable down to the depth of 80?m and the share of the anthropogenic signal on the non-stationary component of the observed subsurface temperature amounts to 30% at the depth of 50?m.     

Large-scale horizontal flows in the solar photosphere IV. On the vertical structure of large-scale horizontal flows

In the recent papers, we introduced a method utilised to measure the flow field. The method is based on the tracking of supergranular structures. We did not precisely know, whether its results represent the flow field in the photosphere or in some subphotospheric layers. In this paper, in combination with helioseismic data, we are able to estimate the depths in the solar convection envelope, where the detected large-scale flow field is well represented by the surface measurements. We got a clear answer to question what kind of structures we track in full-disc Dopplergrams. It seems that in the quiet Sun regions the supergranular structures are tracked, while in the regions with the magnetic field the structures of the magnetic field are dominant. This observation seems obvious, because the nature of Doppler structures is different in the magnetic regions and in the quiet Sun. We show that the large-scale flow detected by our method represents the motion of plasma in layers down to ～10 Mm. The supergranules may therefore be treated as the objects carried by the underlying large-scale velocity field.     

The importance of symbols in the region formation process

The aim in the article is to conceptualize the general foundations of research on the importance of regional symbolism in the process of region and regional identity formation. The article is founded on a critical analysis of works pertaining not only to the field of the new regional geography, but also to the field of regional marketing and/or branding, sociology, and semiology. The authors focus on meanings attributed to symbols and symbolism in literature, and observe which elements are viewed as regional symbols and how these symbols contribute to the process of regional development and institutionalization, especially in the formation of its symbolic shape. They examine the thematic and theoretical grounds, looking at identity, regional identity, and regional institutionalization. Next, regional symbols are defined and classified according to their types and forms, and their importance in the process of regional formation and institutionalization is discussed. The results show that symbols of any type can play an important role in a region’s marketing, and become the key image associated with a region. The authors conclude that regional symbols are a significant feature of the formation of a region and its identity, both outwardly (the external image of a region) and inwardly (concerning the inhabitants’ relationships with their region).     

Discontinuous Nature of the Lower Part of the South American Wadati-Benioff Zone in The Arica Elbow Region

The Arica Elbow region represents that part of Andean South America where the azimuth of the strike of the Peru-Chile trench changes from 150° to 190°. The area under study is roughly bounded by latitudes 17 °S and 23 °S, The shape of the Wadati-Benioff zone was studied in terms of the distribution of ISC hypocentres dated between 1964 and 1993. A system of 22 vertical cross-sections, perpendicular to the trench axis, and a map of epicentres was used to derive the detailed shape of the Wadati-Benioff zone of the presently descending slab. The distribution of earthquake foci indicates a fingerlike shape of the lower part of the Wadati-Benioff zone beneath the aseismic gap. The slab length shows small changes around 350 km in the northern sections, pronounced length oscillations between 350 and 750 km in the neighbouring central sections and a constant value of 650 km in the southern sections. The dip and thickness of the Wadati-Benioff zone are practically constant in all sections. Fault plane solutions, separated spatially into three zones, were used to estimate the state of stress in the slab.     

The BanskáŠtiavnica ore district: relationship between metallogenetic processes and the geological evolution of a stratovolcano

The Banská?tiavnica ore district is in the central zone of the largest stratovolcano in the Central Slovakia Neogene Volcanic Field, which is situated at the inner side of the Carpathian arc over the Hercynian basement with the Late Paleozoic and Mesozoic sedimentary cover. Volcanic rocks of the High-K orogenic suite are of the Badenian through Pannonian age (16.5–8.5?Ma). Their petrogenesis is closely related to subduction of flysch belt oceanic basement underneath the advancing Carpathian arc and to back-arc extension processes. The stratovolcano includes a large caldera 20?km in diameter and a late-stage resurgent horst in its centre, exposing a basement and extensive subvolcanic intrusive complex. The following stages have been recognized in the evolution of the stratovolcano: (1)?formation of a large pyroxene/hornblende-pyroxene andesite stratovolcano; (2)?denudation, emplacement of a diorite intrusion; (3) emplacement of a large granodiorite bell-jar pluton within the basement; (4) emplacement of granodiorite/quartz-diorite porphyry stocks and dyke clusters around the pluton; (5) caldera subsidence and its filling by biotite-hornblende andesite volcanics, emplacement of quartz-diorite porphyry sills and dykes at the subvolcanic level; (6)?renewed activity of andesites from dispersed centres on slopes of the volcano; (7) uplift of a resurgent horst accompanied by rhyolite volcanics and granite porphyry dykes. The following types of ore deposits (mineralizations) have been identified in the Banská?tiavnica ore district: 1. Quartz-pyrophyllite-pyrite high-sulphidation system at ?obov, related to the diorite intrusion. 2. Magnetite skarn deposits and occurrences?at contacts of the granodiorite pluton with Mesozoic carbonate rocks. Magnetite ores occur as lenses in the calcic skarns. 3.?Stockwork/disseminated base metal deposit along an irregular network of fractures in apical parts of the granodiorite pluton and in remnants of basement rocks. Mineral paragenesis is simple, with leading sphalerite and galena and minor chalcopyrite and pyrite. In overlying andesites the mineralization is accompanied by metasomatic quartzites and argillites with pyrophyllite, kaolinite, illite and pyrite. 4. Porphyry/skarn copper deposits and occurrences related to granodiorite/quartz-diorite porphyry dyke clusters and stocks around the granodiorite intrusion. The mineralized zone is represented by accumulations of chalcopyrite in exo- and endo-skarns, usually of the magnesian type affected by serpentinization. Besides chalcopyrite, pyrhotite, minor bornite, chalcosite, tennantite and magnetite, rare molybdenite and gold are present. The alteration pattern around productive intrusions includes an external zone of propylitization, a zone of argillitic alteration (kaolinite – illite – pyrite) and an internal zone of phyllic alteration (quartz – sericite – pyrite). Biotitization is rare and limited to porphyry intrusions. 5. Intrusion related “mesothermal” gold deposit in an andesitic environment just above the granodiorite intrusion. Gold of high fineness with base metal mineralization is contained in brecciated and/or banded quartz veins of subhorizontal orientation, parallel to the surface of granodiorite pluton. At least the first phase of mineralization is older than quartz-diorite porphyry sills, which separate granodiorite and blocks of mineralized andesite. 6. Hot spring type advanced argillic systems in the caldera filling. Silicites and opalites accompanied by kaolinite, alunite and pyrite grade downward into smectite dominated argillites. 7. Vein type epithermal precious/base metal deposits and occurrences as a result of the long lasting interaction among structural evolution of the resurgent horst and evolving hydrothermal system, extensive intrusive complex and deep seated siliceous magma chamber serving as heat and magmatic fluid source. Three types of epithermal veins occur in a zonal arrangement: (a) base metal veins ± Au with transition to Cu?±?Bi mineralization at depth in the east/central part of the horst, (b)?Ag – Au veins with minor base metal mineralization and (c) Au – Ag veins located at marginal faults of the horst. Isotopic composition of oxygen and hydrogen in hydrothermal fluids indicate mixing of magmatic and meteoric component (with generally increasing proportion of meteoric component towards younger mineralization periods?). Veins are accompanied by zones of silicification, adularization and sericitization, indicating a low sulphidation environment. 8.?Replacement base metal mineralization of a limited extent in the Mesozoic carbonate rocks next to sulphide rich epithermal base metal veins.     

Implementation of Solute Transport in the Vadose Zone into the “HYDRUS Package for MODFLOW”

The “HYDRUS package for MODFLOW” is an existing MODFLOW package that allows MODFLOW to simultaneously evaluate transient water flow in both unsaturated and saturated zones. The package is based on incorporating parts of the HYDRUS-1D model (to simulate unsaturated water flow in the vadose zone) into MODFLOW (to simulate saturated groundwater flow). The coupled model is effective in addressing spatially variable saturated-unsaturated hydrological processes at the regional scale. However, one of the major limitations of this coupled model is that it does not have the capability to simulate solute transport along with water flow and therefore, the model cannot be employed for evaluating groundwater contamination. In this work, a modified unsaturated flow and transport package (modified HYDRUS package for MODFLOW and MT3DMS) has been developed and linked to the three-dimensional (3D) groundwater flow model MODFLOW and the 3D groundwater solute transport model MT3DMS. The new package can simulate, in addition to water flow in the vadose zone, also solute transport involving many biogeochemical processes and reactions, including first-order degradation, volatilization, linear or nonlinear sorption, one-site kinetic sorption, two-site sorption, and two-kinetic sites sorption. Due to complex interactions at the groundwater table, certain modifications of the pressure head (compared to the original coupling) and solute concentration profiles were incorporated into the modified HYDRUS package. The performance of the newly developed model is evaluated using HYDRUS (2D/3D), and the results indicate that the new model is effective in simulating the movement of water and contaminants in the saturated-unsaturated flow domains.