Trace and rare-earth element behaviors during alteration and mineralization in the Attepe iron deposits (Feke-Adana,southern Turkey)

Hydrothermal-metasomatic iron ores consisting mainly of siderite, ankerite and hematite are located in the Lower–Middle Cambrian limestone marbles of the Eastern Taurus Belt. The siderite, ankerite, hematite and host rock samples from the deposits have been investigated for major, trace, and rare-earth elements (REE) to evaluate the element mobility and mass transfer during fluid–rock interactions.     

Geochemical constraints on the genesis of the Sarıcakaya intrusive rocks,Turkey: Late Paleozoic crustal melting in the central Sakarya Zone

The Sakarya Zone is intruded by several Late Paleozoic granitoids, of which the Sar?cakaya intrusive rocks in the central Sakarya (Eski?ehir) region, is the least-studied. The Sar?cakaya intrusive rocks consist mainly of quartz diorite-granodiorite, granodiorite and granite. They are, geochemically, divided into two groups: diorites and granites. The former is medium-K and calc-alkaline (mainly I-type), whereas the latter is high-K to shoshonite and calcic (I-type). Typical minerals for both rock types are plagioclase, K-feldspar, quartz, biotite, hornblende and Fe–Ti oxides. Chondrite-normalized REE patterns for the Sar?cakaya intrusive rocks are moderately fractionated and have small negative Eu anomalies. They are enriched in LILE and LREE relative to HFSE showing characteristics of arc-related granitoids. Geochemical characteristics of the Sar?cakaya intrusive rocks indicate a hybrid origin through partial melting of lower crustal source rocks.     

Periodic motions around pulsating stars

The periodic motion of a test particle (dust, grain, or a larger body) around a pulsating star with a luminosity oscillation of small amplitude (featured by a small parameterB) is being studied. The perturbations of all orbital elements are determined to first order inB, by using Delaunay-type canonical variables and a method whose bases were put forth by von Zeipel. According to the value of the ratio oscillation frequency/dynamic frequency, three possible situations are pointed out: nonresonant (NR), quasi-resonant (QR), and resonant (R). The solution of motion equations shows that only in the (QR) and (R) cases there are orbital parameters (argument of periastron and mean anomaly) affected by secular perturbations. These solutions (which indicate a secularly stable motion in a first approximation) are valid over prediction times of orderB ^–1 in the (NR) case andB ^–1/2 in the (QR) and (R) cases. The theory may be applied to various astronomical situations.     

Coprecipitation with Cu(II)‐4‐(2‐Pyridylazo)‐resorcinol for Separation and Preconcentration of Fe(III) and Ni(II) in Water and Food Samples

The coprecipitation method is widely used for the preconcentration of trace metal ions prior to their determination by flame atomic absorption spectrometry (FAAS). A simple and sensitive method based on coprecipitation of Fe(III) and Ni(II) ions with Cu(II)‐4‐(2‐pyridylazo)‐resorcinol was developed. The analytical parameters including pH, amount of copper (II), amount of reagent, sample volume, etc., were examined. It was found that the metal ions studied were quantitatively coprecipitated in the pH range of 5.0–6.5. The detection limits (DL) (n = 10, 3s/b) were found to be 0.68 µg L^?1 for Fe(III) and 0.43 µg L^?1 for Ni(II) and the relative standard deviations (RSD) were ≤4.0%. The proposed method was validated by the analysis of three certified reference materials (TMDA 54.4 fortified lake water, SRM 1568a rice flour, and GBW07605 tea) and recovery tests. The method was successfully applied to sea water, lake water, and various food samples.     

Color Removal from Synthetic Textile Wastewater by Sono‐Fenton Process

In this study, the oxidative decolorization of C.I. reactive yellow 145 (RY 145) from synthetic textile wastewater including RY 145 and polyvinyl alcohol by Fenton and sono‐Fenton processes which are the combination of Fenton process with ultrasound has been carried out. The effects of some operating parameters which are the initial pH of the solution, the initial concentration of Fe²⁺, H₂O₂, and the dye, temperature, and agitation speed on the color and chemical oxygen demand (COD) removals have been investigated. The optimum conditions have been found as [Fe²⁺] = 20 mg/L, [H₂O₂] = 20 mg/L, pH 3 for Fenton process and [Fe²⁺] = 20 mg/L, [H₂O₂] = 15 mg/L, pH 3 for sono‐Fenton process by indirectly sonication at 35 kHz ultrasonic frequency and 80 W ultrasonic power. The color and COD removal efficiencies have been obtained as 91 and 47% by Fenton process, and 95 and 51% by sono‐Fenton processes, respectively. Kinetic studies have been performed for the decolorization of RY 145 under optimum conditions at room temperature. It has been determined that the decolorization has occurred rapidly by sono‐Fenton process, compared to Fenton process.     

Flash flood inundation map preparation for wadis in arid regions

Flood inundation maps are dependent on the topographic and geomorphologic features of a wadi (drainage basin) in arid regions, which are most susceptible for potential flash flood occurrences, such as in the southwestern part of the Kingdom of Saudi Arabia. It is not possible to control the potential flood hazards by using only technological instruments that forewarn the occurrences or imminence. Additionally, it would be better to prepare flood risk maps so as to delineate the risky areas to educate the administrators and local settlers. The availability of these maps is the key requirement for any urban development that entails land use allocation, identification of dam, tunnel, highway, bridge sites, and infrastructure locations for sustainable future. This paper suggests the necessary steps in flood inundation map preparation after determining the possible flood discharge. For this purpose, a set of critical cross-sections along the possible flood plain are taken in the field with surveying methods and measurements. The calculation of the average flow velocity in each section is calculated according to the cross-section geometric, hydraulic, and material properties. Synthetic rating curves (SRC) are prepared for each cross section, which are very useful especially in arid and semi-arid regions where there are no perennial surface water flows for natural rating curve measurements. All the SRCs appear in the form of power function which relates the flow depth to discharge in a given cross section. It is then possible to calculate the flood depth in the cross section through its SRC. Depending on the cross-section shape, the flood width can be calculated. The connection of a series of widths on a scaled topographic map delineates the flood inundation area. If digital elevation map (DEM) is available, then the SRCs can be integrated with these maps and the flood inundation delineation can be achieved automatically. Since DEMs are not available, the topographic maps are used for this purpose in order to delineate flood inundation areas within wadis Hali and Yiba from the southwestern Kingdom of Saudi Arabia.     

Relatedness between contemporary and subfossil cladoceran assemblages in Turkish lakes

Cladocerans are valuable indicators of environmental change in lakes. Their fossils provide information on past changes in lake environments. However, few studies have quantitatively examined the relationships between contemporary and sub-fossil cladoceran assemblages and no investigations are available from Mediterranean lakes where salinity, eutrophication and top-down control of large-bodied cladocerans are known to be important. Here we compared contemporary Cladocera assemblages, sampled in summer, from both littoral and pelagic zones, with their sub-fossil remains from surface sediment samples from 40 Turkish, mainly shallow, lakes. A total of 20 and 27 taxa were recorded in the contemporary and surface sediment samples, respectively. Procrustes rotation was applied to both the principal components analysis (PCA) and redundancy analysis (RDA) ordinations in order to explore the relationship between the cladoceran community and the environmental variables. Procrustes rotation analysis based on PCA showed a significant accord between both littoral and combined pelagic–littoral contemporary and sedimentary assemblages. RDA ordinations indicated that a similar proportion of variance was explained by environmental variation for the contemporary and fossil Cladocera data. Total phosphorus and salinity were significant explanatory variables for the contemporary assemblage, whereas salinity emerged as the only significant variable for the sedimentary assemblage. The residuals from the Procrustes rotation identified a number of lakes with a high degree of dissimilarity between modern and sub-fossil assemblages. Analysis showed that high salinity, deep water and high macrophyte abundance were linked to a lower accord between contemporary and sedimentary assemblages. This low accord was, generally the result of poor representation of some salinity tolerant, pelagic and macrophyte-associated taxa in the contemporary samples. This study provides further confirmation that there is a robust relationship between samples of modern cladoceran assemblages and their sedimentary remains. Thus, sub-fossil cladoceran assemblages from sediment cores can be used with confidence to track long-term changes in this environmentally sensitive group and in Mediterranean lakes, subjected to large inter-annual variation in water level, salinity and nutrients.     

Monthly spatial rainfall correlation functions and interpretations for Turkey

Abstract

Monthly spatial rainfall distribution features and their effects on spatial correlation patterns are significant in any regional study. In this paper, first a number of statistical terms and properties are explained with reference to the spatial correlation functions (SCFs). This is followed by the analysis of a theoretical spatial correlation model and its parameter estimation. Monthly empirical SCFs are examined in relation to spatial rainfall characteristics. In order to obtain a definite pattern, the SCF values are averaged in successive equal-distance groups. This average spatial correlation function shows a decreasing pattern with distance. Some interpretations of these spatial correlation functions are given for Turkey with discussion of the results obtained.     

Physical parameters of some close binaries: ET Boo,V1123 Tau,V1191 Cyg,V1073 Cyg and V357 Peg

With the aim of providing new and up-to-date absolute parameters of some close binary systems, new BVR CCD photometry was carried out at the Ankara University Observatory (AUG) for five eclipsing binaries, ET Boo, V1123 Tau, V1191 Cyg, V1073 Cyg and V357 Peg between April, 2007 and October, 2008. In this paper, we present the orbital solutions for these systems obtained by simultaneous light and radial velocity curve analyses. Extensive orbital solution and absolute parameters for ET Boo system were given for the first time through this study. According to the analyses, ET Boo is a detached binary while the parameters of four remaining systems are consistent with the nature of contact binaries. The evolutionary status of the components of these systems are also discussed by referring to their absolute parameters found in this study.