Effect of organic solvent type on the removal of nitrate ion using liquid membrane technique

In this study, the removal of nitrate ions from aqueous solutions with liquid membrane technique has been investigated for different organic solvent types in which solubilized tetradecyl trimethyl ammonium bromide (TDTMABr) as carrier. n-butyl alcohol, chloroform, and mixture of chloroform + n-hexane (n-hexane 85% + chloroform 15%) were used as organic solvent. Kinetic parameters (k _1d, k _2m, k _2a, t _max, R _m^max, J _m^max, J _a^max) were calculated from obtained data. time R _a values of mixture, butyl alcohol, and chloroform are 0.81, 0.78, and 0.55, respectively. Similarly R _d, R _m, and t _max values of the mixture equal to 0.14, 0.04, and 87.92 min, respectively. This behavior of the system shows the organic solvent type is an effective parameter on separation yield. It can be concluded that the mixture is the most effective organic solvent type among the investigated ones, because liquid membrane systems should be operated within the range of having the R _m, R _d, and t _max values are minimum while R _a values are maximum.     

Geochemical characteristics of Kırka (Sarıkaya) borate deposit,northwestern Anatolia,Turkey

The K?rka borate deposit was deposited in a Miocene lacustrine basin which is closely associated with volcanic activity which lasted from Paleogene to the beginning of Quaternary. Borate mineralization alternates with claystone, mudstone, tuff and fine-layered limestone and mostly shows a lenticular structure. The mineral paragenesis is composed of borax, tincalconite, ulexite, kurnakovite, probertite, tunellite, colemanite, dolomite, smectite group minerals, illite and some firstly reported minerals for the K?rka deposit including hydrochloroborite, brianroulstonite, hilgardite-4M and searlesite minerals. In comparison to average values of earth crust, concentrations of Cs, Sr, Li, As and Se were significantly enriched with respective rates of 21, 15, 14, 3 and 188 folds. Regarding KY, KS1 and KS2 locations, there are differences in both element abundances and their geochemical tendencies which are attributed to variations in discharge regime and physico-chemical conditions of the depositional environment. Independent behaviour of B₂O₃ might indicate that boron is not associated with clays and carbonates and, therefore, most part of boron must be derived from volcanic activity (hydrothermal solutions, gases). REE data indicate that the K?rka borate deposit was formed in a sedimentary environment where highly alkaline (high pH) hydrothermal solutions also took part in borate precipitation process.     

Observations of aδ Scuti-like pulsator: HR 7222

Visual and blue band photometric observations of the Scuti-type variable have been carried out. It has been found that LT Vul pulsates in the radial fundamental mode. Higher overtones such as third andn > 3 overtones have also been detected.     

Investigation of vertical mass changes in the south of Izmir (Turkey) by monitoring microgravity and GPS/GNSS methods

Journal of Earth System Science - The monitoring of gravity changes in a region enables the investigation of regional structural elements depending upon the changes in load compensation. This...     

Determination of near-surface structures from multi-channel surface wave data using multi-layer perceptron neural network (MLPNN) algorithm

This study proposes the use of multi-layer perceptron neural networks (MLPNN) to invert dispersion curves obtained via multi-channel analysis of surface waves (MASW) for shear S-wave velocity profile. The dispersion curve used in inversion includes the fundamental-mode dispersion data. In order to investigate the applicability and performance of the proposed MLPNN algorithm, test studies were performed using both synthetic and field examples. Gaussian random noise with a standard deviation of 4 and 8% was added to the noise-free test data to make the synthetic test more realistic. The model parameters, such as S-wave velocities and thicknesses of the synthetic layered-earth model, were obtained for different S/N ratios and noise-free data. The field survey was performed over the natural gas pipeline, located in the Germencik district of Ayd?n city, western Turkey. The results show that depth, velocity, and location of the embedded natural gas pipe are successfully estimated with reasonably good approximation.     

Implications of 2007’s Earthquake Activity in Eğirdir Lake (SW Anatolia) Based on Moment Tensor Solutions and Inversion of Stress State

We analyzed the waveforms of the small- to moderate-sized earthquakes that took place in the northern part of the inner Isparta Angle (IA) to retrieve their source parameters and combine these results with the focal mechanism solutions of the larger events that occurred in 2007 in E?irdir Lake at the apex of IA. In total, source mechanisms of 20 earthquakes within the magnitude range 3.5 < M < 5.0 were calculated using a regional moment tensor inversion technique. The inversion of the focal mechanisms yields an extensional regime with a NNE–SSW (N38°E) trending σ ₃ axis. Inversion results are related to a mainly WNW–ESE oriented normal fault beneath E?irdir Lake. The R value of a NNE–SSW extensional regime is 0.562 showing a triaxial stress state in the region. The current stress regime results from complex subduction processes such as slab pull, slab break-off, roll-back and/or retreating mechanism along the Hellenic and Cyprus arcs and the southwestward extrusion of the Anatolian block since the early Pliocene.     

Simulation of the earthquake-induced collapse of a school building in Turkey in 2011 Van Earthquake

Collapses of school or dormitory buildings experienced in recent earthquakes raise the issue of safety as a major challenge for decision makers. A school building is ‘just another structure’ technically speaking, however, the consequences of a collapse in an earthquake could lead to social reactions in the complex aftermath of a seismic tremor more than any other type of structure may possibly cause. In this paper a school building that collapsed during 2011 Tabanli, Van Earthquake in eastern Turkey, is analysed in order to identify the possible reasons that led to collapse. Apart from the inherent deficiencies of RC buildings built in Turkey in the 80's and 90's, its structural design exhibits a strikingly high asymmetry. In the analyses conducted, much attention has been given to the direction of the earthquake load and its coincidence with the bi-axial structural response parameters. The failure of the structure to comply with the 1975 Code, in vigor at the time of construction, has also been evaluated with respect to the structure’s collapse. Among the parameters that controlled the collapse, the high plan asymmetry and the coincidence of the vulnerable directions with the dominant shaking direction were critical, as well as the underestimation of the seismic hazard and the lateral design force level, specified by the then Turkish Earthquake Code.     

Petrochemical evidence of magma mingling and mixing in the Tertiary monzogabbroic stocks around the Bafra (Samsun) area in Turkey: implications of coeval mafic and felsic magma interactions

Miocene aged calc-alkaline mafic host stocks (monzogabbro) and felsic microgranular enclaves (monzosyenite) around the Bafra (Samsun) area within Tertiary volcanic and sedimentary units of the Eastern Pontides, Northeast Turkey are described for the first time in this paper. The felsic enclaves are medium to fine grained, and occur in various shapes such as, elongated, spherical to ellipsoidal, flame and/or rounded. Most enclaves show sharp and gradational contacts with the host monzogabbro, and also show distinct chilled margins in the small enclaves, indicating rapid cooling. In the host rocks, disequilibrium textures indicating mingling or mixing of coeval mafic and felsic magmas are common, such as, poikilitic and antirapakivi textures in feldspar phenocrysts, sieve textured-patchy-rounded and corroded plagioclases, clinopyroxene megacrysts mantled by bladed biotites, clinopyroxene rimmed by green hornblendes, dissolution in clinopyroxene, bladed biotite, and acicular apatite. The petrographical and geochemical contrasts between the felsic enclaves and host monzogabbros may partly be due to a consequence of extended interaction between coeval felsic and mafic magmas by mixing/mingling and diffusion. Whole-rock and Sr-Nd isotopic data suggests that the mafic host rocks and felsic enclaves are products of modified mantle-derived magmas. Moreover, the felsic magma was at near liquidus conditions when injected into the mafic host magma, and that the mafic intrusion reflects a hybrid product formed due to the mingling and partial (incomplete) mixing of these two magmas.