Relationship between Late Pleistocene sea‐level variations,carbonate platform morphology and aragonite production (Maldives,Indian Ocean)

A piston core from the Maldives carbonate platform was investigated for carbonate mineralogy, grain‐size distributions, calcium carbonate content and organic carbon. The sedimentary record was linked to Late Pleistocene sea‐level variations, using an age model based on oxygen isotopes obtained from planktonic foramanifera, nannofossil biostratigraphy and ¹⁴C age determinations. The correlation between the sedimentary record and Late Pleistocene sea‐level showed that variations in aragonite and mud during the past 150 000 years were clearly related to flooding and sea floor exposure of the main lagoons of the atolls of the Maldives carbonate platform. Platform flooding events were characterized by strongly increased deposition of aragonite and mud within the Inner Sea of the Maldives. Exposure events, in contrast, can be recognized by rapid decreases in the values of both proxy records. The results show that sediments on the Maldives carbonate platform contain a continuous record of Pleistocene sea‐level variations. These sediments may, therefore, contribute to a better understanding of regional and even global sea‐level changes, and yield new insights into the interplay between ocean currents and carbonate platform morphology.     

Liquefaction-induced settlement,site effects and damage in the vicinity of Yalova City during the 1999 Izmit earthquake,Turkey

Yalova City (Turkey) is in a tectonically active location that is particularly affected by the northern branch of the North Anatolian Fault Zone. Magnitudes 7.4 and 7.2 earthquakes in 1999 caused great destruction in Yalova. The heavy damage to buildings and other civil engineering structures was mainly due to liquefaction-induced settlement and site effects such as resonance and amplification. In the first phase of this study, the soil liquefaction potential index (PL) and the induced soil settlement were estimated. In the second phase, the effects on sites in Yalova soil were investigated using microtremor and earthquake data. The fundamental periods and amplification in soft soil were compared with microtremor data and strong ground motion records obtained by a local array of eight accelerograph stations deployed in Yalova. Thirty-seven ‘single site’ ambient noise measurements were taken in a dense grid of points covering the centre of the city. A comparison between fundamental periods obtained from strong ground motion records and from microtremor measurements showed similarities, in the 0.1–5 Hz range. Finally, soil liquefaction and amplification (or resonance) were divided into regions according to the extent of damage and the geotechnical/geophysical results.     

Kizilcaören ore-bearing complex with carbonatites (northwestern Anatolia,Turkey): Formation time and mineralogy of rocks

The results of isotope-geochronological and mineralogical studies of the rocks making up the Kizilcaören fluorite-barite-REE deposit, northwestern Anatolia, Turkey are discussed in the paper. The ore is a constituent of the subvolcanic complex localized in a large fault zone. The complex combines (from earlier to later rocks): (1) phonolite and trachyte stocks, (2) carbonatite and carbonate-silicate dikelike bodies; and (3) fluorite-barite-bastnaesite ore in the form of thick homogeneous veins and cement in breccia. The K-Ar dating of silicate igneous rocks and carbonatites shows that they were formed in the Chattian Age of the Oligocene 25–24 Ma ago. Mineralogical observations show that the ore is the youngest constituent in the rock complex. Supergene alteration deeply transformed ore-bearing rocks, in particular, resulting in leaching of primary minerals, presumably Ca-Mn-Fe carbonates, and in cementation of the residual bastnaesitefluorite framework by Fe and Mn hydroxides. Most of the studied rocks contain pyrochlore, LREE fluorocarbonates, Nb-bearing rutile, Fe-Mg micas, and K-feldspar. The genetic features of the deposit have been considered. In general, the ore-bearing rock complex is compared in the set of rocks and their mineralogy and geochemistry with deposits of the Gallinas Mountains in the United States, the Arshan and Khalyuta deposits in the western Transbaikalia region, and Mushugai-Khuduk deposit in Mongolia. The Kizilcaören deposit represents a variant of postmagmatic mineralization closely related to carbonatite magmatism associated with alkaline and subalkaline intermediate rocks.     

Assessment of spatial distribution and possible sources of heavy metals in the soils of Sariseki-Dörtyol District in Hatay Province (Turkey)

In this study, total heavy metal content of soil and their spatial distribution in Sar?seki-Dörtyol district were analyzed and mapped. Variable distance grids (0.5, 1.0 and 2.0 km) were established, with a total of 102 soil samples collected from two different soil depths (0–5 and 5–20 cm) at intersections of the grids (51 sampling point). Soil samples were analyzed for heavy metals (Cd, Co, Cr, Cu, Pb, Zn, Mn, Fe, and Ni). The most proper variogram models for the contents of all heavy metal were spherical and exponential ones. The ranges of semivariograms were between 1.9 and 31.1 km. According to the calculated geoaccumulation (I _geo) values, samples from both soil depths were classified as partly to highly polluted with Cd and Ni and partly polluted with Cr and as partly polluted-to-not polluted with Pb and not polluted with Cu, Fe and Mn. Similar results were also obtained when evaluated by the enrichment factor. The contamination levels of the heavy metals were Ni > Cd > Cr > Pb > Zn > Cu > Co > Fe > Mn in decreasing order. The soils in the study area are contaminated predominantly by Cd and Ni, which may give rise to various health hazards or diseases. Cadmium pollution results primarily from industrial activities and, to a lesser extent, from vehicular traffic, whereas Ni contents in the study area result from parent material, phosphorus fertilizer, industries, and vehicles.     

Effect of the alkaline industrial residues fly ash,green liquor dregs,and lime mud on mine tailings oxidation when used as covering material

The potential to use the alkaline residue products fly ash, green liquor dregs, and lime mud originating from paper mills as dry cover materials to seal tailings has been investigated. Metals concentration in lime mud and fly ash had the lowest and highest contents, respectively. The tailings (<1 % sulfur content, primarily pyrite) were disposed about 50 years ago and originated from the former Rönnskär mine site in Sweden. The results of chemical composition analysis show that the raw unoxidized tailings are active toward oxidation, while the components of the adjacent oxidized tailings are not. To quantify the release of metals from the tailings and to evaluate the effect of a sealing layer on oxidation and weathering of the tailings, batch leaching tests were conducted in which leachate from alkaline residue materials was fed to the tailings. The results show that a higher concentration of most trace elements is leached from the unoxidized tailings than from the oxidized tailings. Except As and Cr, the rest of analyzed metals (Cd, Cu, Ni, Pb) became immobilized in response to the increased pH as a consequence of the amendment. The three tested alkaline amendments show a similar potential for preventing the release of metals (with the exception of As and Cr) from the tailings. Under either aerobic or anaerobic conditions, microbial activity was found to be of minor importance. XRD analysis of the field samples revealed that it was feasible to use alkaline residue products in covering tailings, and that it was advantageous to use ash as a cover material more than dregs.     

Settling of Kaolinite in Different Aqueous Environment

Settling characteristics of soils carry great importance for geotechnical engineers since sediments properties are formed during the settling of soil particles in an aqueous environment. In this study, settling characteristics of kaolinite are investigated. Different ionic strengths of NaCl, CaCl₂ and AlCl₃ were considered as a function of pH in aqueous environment of varying solid concentrations. Factors affecting the settling characteristics and fabric of kaolinitic sediments have been identified. The results of the study reveal that kaolinite settles in either flocculated or dispersed forms depending on pH and ion concentration. Flocculated settling occurs in acidic pH due to formation of flocs in edge-to-face structure with increasing positive charges at the particle edges. Dispersed settling occurs in alkaline pHs when ionic strength is low. When ionic strength is increased in alkaline pHs, kaolinite particles settle in flocculated form. Furthermore, the results show that pH has a significant role on the final sediment thickness or void ratio of kaolinite. Densely packed structures in alkaline and loosely packed structures in acidic aqueous environments are formed depending on pH level. Results also show that as the solid concentration increases, the settling rate decreases due to buoyancy effect. Finally, the zeta potential of kaolinite is correlated with the final sediment thickness or void ratio of kaolinite as a function of pH. This correlation proves that there is a good agreement between zeta potential and the final sediment thickness or void ratio, especially when the soil is settled in a dispersed form.     

Late Quaternary palaeoenvironment of northern Guatemala: evidence from deep drill cores and seismic stratigraphy of Lake Petén Itzá

Long sediment cores were collected in spring 2006 from Lake Petén Itzá, northern Guatemala, in water depths ranging from 30 to 150 m, as part of an International Continental Scientific Drilling Program project. The sediment records from deep water consist mainly of alternating clay, gypsum and carbonate units and, in at least two drill sites, extend back >200 kyr. Most of the lithostratigraphic units are traceable throughout the basin along seismic reflections that serve as seismic stratigraphic boundaries and suggest that the lithostratigraphy can be used to infer regional palaeoenvironmental changes. A revised seismic stratigraphy was established on the basis of integrated lithological and seismic reflection data from the basin. From ca 200 to ca 85 ka, sediments are dominated by carbonate‐clay silt, often interbedded with sandy turbidites, indicating a sediment regime dominated by detrital sedimentation in a relatively humid climate. At ca 85 ka, an exposure horizon consisting of gravels, coarse sand and terrestrial gastropods marks a lake lowstand or partial basin desiccation, indicating dry climate conditions. From ca 85 to ca 48 ka, transgressive carbonate‐clay sediments, overlain by deep‐water clays, suggest a lake level rise and subsequent stabilization at high stage. From ca 48 ka to present, the lithology is characterized by alternating clay and gypsum units. Gypsum deposition correlates with Heinrich Events (i.e. dry climate), whereas clay units coincide with more humid interstadials.     

Daily suspended sediment estimation using neuro-wavelet models

This paper proposes the application of neuro-wavelet technique for modeling daily suspended sediment–discharge relationship. The neuro-wavelet models are obtained by combining two methods, artificial neural networks (ANN) and discrete wavelet transform. The accuracy of the neuro-wavelet and the ANN models is compared with each other in suspended sediment load estimation. The daily streamflow and suspended sediment data from two stations on Tongue River in Montana are used as case studies. The comparison results reveal that the suggested model could increase the estimation accuracy.     

An Experimental and Theoretical Approach on the Modeling of Sliding Response of Rock Wedges under Dynamic Loading

The stability of rock slopes under dynamic loading in mining and civil engineering depends upon the slope geometry, mechanical properties of rock mass and discontinuities, and the characteristics of dynamic loads with time. The wedge failure is one of the common forms of slope failures. The authors presented some stability conditions for rock wedges under dynamic loading and they confirmed their validity through the laboratory experimental studies in a previous paper in 2000, which is often quoted by others to validate their softwares, including some commercial software. In this study, the authors investigate the sliding responses of rock wedges under dynamic loads rather than the initiation of wedge sliding. First, some laboratory model tests are described. On the basis of these model tests on rock wedges, the theoretical model proposed previously is extended to compute the sliding responses of rock wedges in time domain. The proposed theoretical model is applied to simulate the sliding responses of rock wedge model tests and its validity is discussed. In the final part, the method proposed is applied to actual wedge failures observed in 1995 Dinar earthquake and 2005 Pakistan–Kashmir earthquake, and the results are discussed.