Investigation of the effects of expectation values for radii on the determination of transition probabilities using WBEPM theory

Transition probabilities for some excited s-p and p-s transition arrays of neutral nitrogen have been calculated using the weakest bound electron potential model theory (WBEPMT) for the investigation of effects of expectation values of radii.We have used both numerical non-relativistic Hartree-Fock (NRHF) wave functions and numerical Coulomb approximation (NCA) wave functions to calculate expectation values of radii. The transition probability results obtained using the parameters determined with two different wave functions agree well with each other and accepted values taken from NIST for low values of transition probability. However, the NRHF wave functions present better results for p-s transitions, while NCA wave functions are better in s-p transitions for large values of transition probability.     

Host rock dolomitization and secondary porosity development in the Upper Devonian Cairn Formation of the Fairholme carbonate complex (South‐west Alberta,Canadian Rockies): diagenesis and geochemical modelling

The Upper Devonian carbonate reefs in West‐central Alberta are important petroleum reservoirs that are well‐known for their extensive secondary porosity. An outcrop analogue study indicates that an early matrix‐selective dolomitization event occurred which is characterized by a major Late Devonian sea water component with increased salinity because of evaporation. It is interpreted that the matrix (replacive) dolomite formed during the Famennian as the result of a combination of both seepage and latent reflux dolomitization, although an additional type or overprinting of later intermediate burial dolomitization cannot be excluded. Formation of the moulds is attributed mainly to the dissolution of undolomitized fossil cores, most typically stromatoporoids. Geochemical modelling indicates that carboxylic acid fluids have the highest potential for dissolving residual calcite in this case. Geochemical models consistent with this analysis and interpretations can reproduce the secondary porosity and suggest a viable dolomitization process for the localities studied.     

Syn-tectonic sedimentary evolution of the Miocene Çatallar Basin,southwestern Turkey

The Çatallar Basin is one of the Miocene basins located in the southern part of the Bey Da?lar? Massif (SW Turkey). This basin has been reinvestigated and new stratigraphic and sedimentological data are now presented. The Çatallar Basin lies in paraconformity on the Bey Da?lar? carbonate platform of Late Cretaceous to Palaeogene age. It consists of an impersistent, shallow-marine carbonate base (Karabay?r formation, Late Oligocene to Early Burdigalian) followed by an onlapping detrital sequence including the Akçay and Ba?beleni formations (Langhian to Serravallian). The Akçay formation mainly contains turbidites in which several debris-flows and olistostromes are intercalated. The lowest debris flows derive from the local carbonate platforms of Cretaceous and Palaeogene age. Higher, the debris flows and olistostromes contain large carbonate blocks deriving from nearby sources (Bey Da?lar? platform carbonates), whereas the accompanying pebbles originate from the allochthonous ophiolitic units located farther to the north (Lycian Nappes) or to the east (Antalya Nappes). The origin of these ophiolitic detritus is a matter of debate. The new data obtained in this study favour a northern origin.     

Turbidites and their association with past earthquakes in the deep Çınarcık Basin of the Marmara Sea

Two gravity cores (CAG-3 and C-15) from the tectonically active, 1,276-m deep Çınarcık Basin of the Marmara Sea each include three sandy turbiditic mud units (1 mm–2 cm thick) with sharp basal contacts. The high benthic foraminifer content of these units suggests that the sediments were transported by turbidity currents from the upper slope region. These units represent the thin edges of turbidites thickening towards the subsiding north-eastern part of the basin, and contain quartz, detrital calcite, intact shells and shell fragments, smectite, pyrite framboids, muscovite, biotite, epidote and garnet. Their clay fractions are more enriched in smectite than those of adjacent layers. AMS 14C ages (957±43 a.d. and 578±31 a.d.) of two upper and middle turbiditic units in core C15 overlap with the historical İstanbul-Thrace (intensity=10) and İstanbul-Kocaeli (intensity=9) earthquakes of 26 October 986 and 15 August 553, respectively. This overlap, together with sedimentological characteristics, strongly suggests that the turbiditic units are related to the tectono-seismic activity of the North Anatolian Fault. The age of the lowest turbiditic unit in core C-3 was found to be 6,573±87 a b.p. (calendar) by AMS 14 C. In terms of chronostratigraphic relationships and lithological composition, the turbiditic units in core CAG-3 cannot be correlated with those in C15. This can be explained by gravity-controlled sedimentation causing wedging out of turbidites towards the edge of the basin.     

Multi-disciplinary earthquake researches in Western Turkey: Hints to select sites to study geochemical transients associated to seismicity

Warm and hot spring water as well as soil gas radon release patterns have been monitored in the Aegean Extensional Province of Western Turkey, alongside regional seismic events, providing a multi-disciplinary approach. In the study period of 20 months, seven moderate earthquakes with M _L between 4.0 and 4.7 occurred in this seismically very active region; two earthquakes with magnitude 5.0 also occurred near the study area. Seismic monitoring showed no foreshock activity. By contrast, hydro-geochemical anomalies were found prior to these seismic events, each lasting for weeks. The anomalies occurred foremost in conjunction with dip-slip events and seem to support the dilatancy and water diffusion hypothesis. Increased soil gas radon release was recorded before earthquakes associated with strike-slip faults, but no soil radon anomalies were seen before earthquakes associated with dip-slip faults. Geochemical anomalies were also noticeably absent at some springs throughout the postulated deformation zones of impending earthquakes. The reason for this discrepancy might be due to stress/strain anisotropies.     

Current velocity forecasting in straits with artificial neural networks,a case study: Strait of Istanbul

Owing to their complex character, modeling flow patterns of narrow straits has always been a challenge, even with the numerical techniques of today. This study was aimed at predicting vertical current profiles of a given point in a narrow strait, the Strait of Istanbul. On account of the speed and simplicity it offers, and of its remarkable success in solving complex problems, the feed forward back propagation (FFBP) artificial neural network (ANN) technique was chosen for this study. The model was built on 7039 hours of concurrent measurements of current profiles, meteorological conditions, and surface elevations. The model predicted 12 outputs of East and North velocity components at different depths in a given location. Various alternative models with different inputs and neuron numbers were evaluated attaining the best model by trial and error. Predictions from proposed ANN model were in accordance with the observations with average root mean square error of 0.16 m/s. The same input parameters were then used to build models that predicted current velocities 1–12 h into the future. Results of these predictions show good overall agreement with observations and that FFBP ANN can be used as a reliable tool for forecasting current profiles in straits.     

Continuous resistivity profiling survey in Mersin Harbour, Northeastern Mediterranean Sea

No detailed information has previously been available on the geological and geophysical characteristics of the sea floor and the underlying strata of Mersin Harbour, Northeastern Mediterranean Sea (Turkey). Continuous resistivity profiling (CRP) and borehole data from Mersin Harbour were used to interpret geoelectric stratigraphy of Neogene-Quaternary sediments in the area. This represents one of few such detailed case studies that have applied these valuable CRP techniques for the purpose of marine stratigraphic imaging. It was found that the Neogene-Quaternary sedimentary succession in the area consists of three geoelectric units (GU1, GU2, and GU3 from base to top). The lowest unit, GU1, has a resistivity value of greater than 20.0 ohm-m and consists of Miocene aged limestone and marl. The middle unit, GU2, is characterized by resistivity values ranging from 3.0 to 20.0 ohm-m. Its thickness is greater than 90 m, with the upper section being composed of stiff clay sequences which are Plio-Pleistocene in age. The uppermost unit, GU3, has resistivity values varying from 1.0 to 3.0 ohm-m. This unit displays a maximum thickness of 15 m, and is composed of Holocene muds together with gravel, sand, silt and clay (sometimes incorporating shells) materials of the Plio-Pleistocene age and their various mixtures, silty/clay limestone, and conglomerate sandstone. Comparisons of the geoelectric units with the depositional sequences interpreted from the available seismic data outwith, but close to, Mersin Harbour reveal that the geoelectric unit GU3 corresponds to the depositional sequences C (mainly Holocene) and B (mainly Plio-Pleistocene). The geoelectric unit GU2 partly correlates with the depositional sequence B which appears to be Plio-Pleistocene in age. The geoelectric unit GU1, which has not been encountered in previous seismic surveys, is a new discovery within Mersin Harbour. Limited correlation between the seismic and resistivity structures in the study area is attributed to differences in the acoustic impedance and resistivity contrasts of sub-bottom layers, as well as the penetration versus resolution performance of the systems.     

Relatedness between contemporary and subfossil cladoceran assemblages in Turkish lakes

Cladocerans are valuable indicators of environmental change in lakes. Their fossils provide information on past changes in lake environments. However, few studies have quantitatively examined the relationships between contemporary and sub-fossil cladoceran assemblages and no investigations are available from Mediterranean lakes where salinity, eutrophication and top-down control of large-bodied cladocerans are known to be important. Here we compared contemporary Cladocera assemblages, sampled in summer, from both littoral and pelagic zones, with their sub-fossil remains from surface sediment samples from 40 Turkish, mainly shallow, lakes. A total of 20 and 27 taxa were recorded in the contemporary and surface sediment samples, respectively. Procrustes rotation was applied to both the principal components analysis (PCA) and redundancy analysis (RDA) ordinations in order to explore the relationship between the cladoceran community and the environmental variables. Procrustes rotation analysis based on PCA showed a significant accord between both littoral and combined pelagic–littoral contemporary and sedimentary assemblages. RDA ordinations indicated that a similar proportion of variance was explained by environmental variation for the contemporary and fossil Cladocera data. Total phosphorus and salinity were significant explanatory variables for the contemporary assemblage, whereas salinity emerged as the only significant variable for the sedimentary assemblage. The residuals from the Procrustes rotation identified a number of lakes with a high degree of dissimilarity between modern and sub-fossil assemblages. Analysis showed that high salinity, deep water and high macrophyte abundance were linked to a lower accord between contemporary and sedimentary assemblages. This low accord was, generally the result of poor representation of some salinity tolerant, pelagic and macrophyte-associated taxa in the contemporary samples. This study provides further confirmation that there is a robust relationship between samples of modern cladoceran assemblages and their sedimentary remains. Thus, sub-fossil cladoceran assemblages from sediment cores can be used with confidence to track long-term changes in this environmentally sensitive group and in Mediterranean lakes, subjected to large inter-annual variation in water level, salinity and nutrients.