Molybdenum in icelandic geothermal waters

Molybdenum concentrations in Icelandic geothermal waters lie in the range 1–70 ppb. Warm waters and dilute high-temperature waters which contain high concentrations of sulphide are lowest in molybdenum. No correlation is otherwise observed between molybdenum concentrations and temperature. Surface waters and cold ground waters do not contain detectable molybdenum (<1 ppb). It seems likely that leaching rate is the prime factor in limiting molybdenum levels in these waters. Within individual geothermal fields molybdenum concentrations are either approximately constant or they vary regularly across the field. This regular variation may often be correlated with variations in other solute concentrations and subsurface temperatures and is taken to indicate a control of molybdenum mobility by a temperature dependent equilibrium. The evidence suggests that the solubility of molybdenite is responsible. Molybdenite has not been found in active geothermal systems in Iceland but is known to occur in some New Zealand geothermal systems and it has been identified in hydrothermally altered Tertiary basalt formations at Reydarártindur in southeast Iceland. Boiling and mixing with cold water leads to molybdenite undersaturation and thus these processes favour leaching of molybdenum from the rock. On the other hand, conductive cooling leads to supersaturation which favours removal of molybdenum from solution.     

On the accuracy of location of local shocks on the territory of Czechoslovakia and adjacent areas

Summary The calculation procedures for determining epicentre parameters of weak near shocks with foci in Poland are discussed and tested for explosions with known epicentres.

---

m m¶rt; ¶rt; n¶rt;u num a uu m num nmua n auauu, u mu a mumuu u, n muu ¶rt;au uu mau. au mam nam (a. 4) nu nuuu na 71 u m ¶rt;u n¶rt; ¶rt; a auu ¶rt;a [11].

     

Effect of cofactors of adjusted and unadjusted quantities on their functions

aamuam uu am a (m u naamuu n) u u (a) uu a uu mu uu. mam (19), (28) naam, m amua am mau u m ¶rt; am amu: a) na ¶rt;um am, n n a uu am u uu a uu; ) ma ¶rt;um am, m aam uu a uu.     

Earthquake distribution and volcanism in Kamchatka,Kurile Islands,and Hokkaido Part 3: Southern Kuriles and Hokkaido

Summary The morphology of the Wadati-Benioff zone in the region of Southern Kuriles and Hokkaido, based on the distribution of 4015 earthquake foci, verified the existence of an intermediate depth aseismic gap and its relation to active andesitic volcanism. A paleosubduction zone activated by an intermediate depth collision with the active subduction zone was found and described.

---

u Wadati-Benioff amu uu - u a¶rt;, aa a an¶rt;uu 4015 a mu, nm¶rt;ua mau n¶rt; au u amu a¶rt;um au. a a¶rt;a u nuaa a na¶rt;uu, amuuuaa nmu mu amu ¶rt;uu.

     

Numerical modelling of time-harmonic seismic wave fields in simple structures by the Gaussian beam method. Part II

ma ama m n¶rt;u am[1]. u ama, m¶rt;au n unm ¶rt; uuauu ma m nau a¶rt;a. a uau ¶rt;m ma a muna . au mu mamau n [1], m m¶rt;au n ¶rt;am ¶rt;mam m mam ¶rt;a u amu aa mu. aumu amu, uauau n ma nuu ¶rt;a . m am ¶rt;am mumm mam a naama am, aa uu L ₀ au n. aa, m am mam namuu aum m L ₀ . amu aa mu u aumu amu, a m mam n ¶rt; u L ₀ . u uu L ₀ , anum¶rt; ma amu aa mu nuam, nu aua nam m, m uu L ₀ auum. aumu amu, u L ₀ um m uau m a uuu anum¶rt; u, mmmu a. uu L ₀ , uuu nam. ma uam mumm mam ¶rt;a ¶rt;u naama am. uau ¶rt;m ma anum¶rt; u ma muna S, S u SS.     

Magnetic susceptibility anisotropy of deformed rocks

¶rt;au uu aum nuuumu u aumnuu ¶rt; aa aam n¶rt; am amuu u namuu ¶rt;au. amu uu aumnuu nuuumu, a amu ¶rt;au, m ¶rt;mu au ma nma aaumu m¶rt; ¶rt;a, m a amu uu aum m mnu n¶rt;u ¶rt; mm uaum amua n¶rt; ¶rt;au. u aumnuu nu a namu ¶rt;auu(<1%) a uuu m nuuumu _i uaum amua. u aumnuu ¶rt;mu uu uum aauuau ¶rt;ua am m uu, m, m ¶rt; u au namu ¶rt;auu.     

Motion of particles in turbulent flow: Hyperbolicity,strange attractors and dynamic stochasticity of a system

¶rt;naa, m ma um uu maunuu m am muu ¶rt;uauu um. nua a mau ammama a, n¶rt; mnu ma u u au uu u¶rt;mu.     

Germanium in Icelandic geothermal systems

Germanium concentrations in geothermal waters in Iceland lie mostly in the range 2–30 ppb. There is an overall positive relation between the germanium content of the water and its temperature. Most of the germanium occurs as Ge(OH)^?₅in solution but Ge(OH)₄ may also be present in significant amounts in saline waters when above 200°C. Evidence indicates that aqueous germanium concentrations are controlled by exchange reactions where it substitutes for silica in silicates and iron in sulphides. It is the rate of dissolution and the relative abundance of the alteration minerals which take up germanium to a variable extent that ultimately fix Ge(OH)₄ concentrations in the water. This, together with water pH, fixes total dissolved germanium. It is mostly the primary rock composition that dictates the relative abundance of the alteration minerals. Conductive cooling in upflow zones favours removal of germanium from solution. During the initial stages of boiling of rising hot water dissolution is enhanced but precipitation at later stages.Thermodynamic data of various aqueous germanium species and several minerals are summarized and dissociation constants and solubilities estimated at elevated temperatures using available predictive methods.     

Description and interpretation of the composition of fluid and alteration mineralogy in the geothermal system,at Svartsengi,Iceland

The bulk composition and mineralogy of hydrothermally altered tholeiite, along with the composition and speciation of fluid, have been determined for a well-defined alteration zone at 240°C and 110 bars at Svartsengi, Iceland. Mass balances between the geothermal fluid and altered tholeiite, relative to a seawater/fresh water mixture and unaltered tholeiite, indicate the overall reaction per 1000 cm³ is: 1325 gm plagioclase + 1228 gm pyroxene + 215 gm oxide-minerals break down to form 685 gm chlorite + 636 gm albite + 441 gm quartz + 249 gm epidote + 266 gm calcite + 201 gm oxide-minerals + 15 gm pyrite, requiring an influx of 123 gm CO₂, 10 gm H₂S and 4 gm Na₂O and a release of 57 gm SiO₂, 35 gm FeO, 21 gm CaO, 8 gm MgO and 4 gm K₂O.Principal reactions, deduced from textural evidence, include Na-Ca exchange in plagioclase, precipitation of quartz, calcite and anhydrite, and formation of chlorite and epidote by reactions between groundmass minerals and fluid.Thermodynamic analyses of authigenic minerals and downhole fluid indicate that the fluid maintains a state close to equilibrium with the secondary mineral phases chlorite, epidote, albite, quartz, calcite, prehnite, anhydrite, pyrite and magnetite, whereas remnant primary labradorite and augite are out of equilibrium with the fluid.Water/rock ratios for the system are determined under a variety of assumptions. However, the open nature of the system makes comparisons with experimental and theoretical closed system studies ambiguous.     

Regionally metamorphosed greisens of the Moldanubicum

The orthogneiss bodies of the Moldanubicum in the western part of the Bohemian-Moravian Heights (eskomoravská vrchovina) are apoleucogranites, presumably of Precambrian age and probably of anatectic origin. Most orthogneiss bodies have been shown to contain greisens transformed by regional metamorphism. The greisens have maintained their identity during regional metamorphism below higher almandine-amphibolite facies grade, i.e. over the stability field of muscovite. Massive quartz (metamorphosed vein quartz) is frequent, and mineralization is associated with it in a few localities. Greisens in orthogneisses may serve as evidence of magmatic origin.