Implications for behavior of volatile elements during impacts—Zinc and copper systematics in sediments from the Ries impact structure and central European tektites

Moldavites are tektites genetically related to the Ries impact structure, located in Central Europe, but the source materials and the processes related to the chemical fractionation of moldavites are not fully constrained. To further understand moldavite genesis, the Cu and Zn abundances and isotope compositions were measured in a suite of tektites from four different substrewn fields (South Bohemia, Moravia, Cheb Basin, Lusatia) and chemically diverse sediments from the surroundings of the Ries impact structure. Moldavites are slightly depleted in Zn (~10–20%) and distinctly depleted in Cu (>90%) relative to supposed sedimentary precursors. Moreover, the moldavites show a wide range in δ⁶⁶Zn values between 1.7 and 3.7‰ (relative to JMC 3‐0749 Lyon) and δ⁶⁵Cu values between 1.6 and 12.5‰ (relative to NIST SRM 976) and are thus enriched in heavy isotopes relative to their possible parent sedimentary sources (δ⁶⁶Zn = ?0.07 to +0.64‰; δ⁶⁵Cu = ?0.4 to +0.7‰). In particular, the Cheb Basin moldavites show some of the highest δ⁶⁵Cu values (up to 12.5‰) ever observed in natural samples. The relative magnitude of isotope fractionation for Cu and Zn seen here is opposite to oxygen‐poor environments such as the Moon where Zn is significantly more isotopically fractionated than Cu. One possibility is that monovalent Cu diffuses faster than divalent Zn in the reduced melt and diffusion will not affect the extent of Zn isotope fractionation. These observations imply that the capability of forming a redox environment may aid in volatilizing some elements, accompanied by isotope fractionation, during the impact process. The greater extent of elemental depletion, coupled with isotope fractionation of more refractory Cu relative to Zn, may also hinge on the presence of carbonyl species of transition metals and electromagnetic charge, which could exist in the impact‐induced high‐velocity jet of vapor and melts.     

Nonequilibrium Processes in the Solar Corona,Transition Region,Flares, and Solar Wind <Emphasis Type="Italic">(Invited Review)</Emphasis>

We review the presence and signatures of the non-equilibrium processes, both non-Maxwellian distributions and non-equilibrium ionization, in the solar transition region, corona, solar wind, and flares. Basic properties of the non-Maxwellian distributions are described together with their influence on the heat flux as well as on the rates of individual collisional processes and the resulting optically thin synthetic spectra. Constraints on the presence of high-energy electrons from observations are reviewed, including positive detection of non-Maxwellian distributions in the solar corona, transition region, flares, and wind. Occurrence of non-equilibrium ionization is reviewed as well, especially in connection to hydrodynamic and generalized collisional-radiative modeling. Predicted spectroscopic signatures of non-equilibrium ionization depending on the assumed plasma conditions are summarized. Finally, we discuss the future remote-sensing instrumentation that can be used for the detection of these non-equilibrium phenomena in various spectral ranges.     

Comparative Study of the Three-Dimensional Thermodynamical Structure of the Inner Corona of Solar Minimum Carrington Rotations 1915 and 2081

Using differential emission measure tomography (DEMT) based on time series of EUV images, we carry out a quantitative comparative analysis of the three-dimensional (3D) structure of the electron density and temperature of the inner corona (\(r<1.25\,\mathrm{R}_{\odot}\)) between two specific rotations selected from the last two solar minima, namely Carrington Rotations (CR)1915 and CR-2081. The analysis places error bars on the results because of the systematic uncertainty of the sources. While the results for CR-2081 are characterized by a remarkable north–south symmetry, the southern hemisphere for CR-1915 exhibits higher densities and temperatures than the northern hemisphere. The core region of the streamer belt in both rotations is found to be populated by structures whose temperature decreases with height (called “down loops” in our previous articles). They are characterized by plasma \(\beta\gtrsim1\), and may be the result of the efficient dissipation of Alfvén waves at low coronal heights. The comparative analysis reveals that the low latitudes of the equatorial streamer belt of CR-1915 exhibit higher densities than for CR-2081. This cannot be explained by the systematic uncertainties. In addition, the southern hemisphere of the streamer belt of CR-1915 is characterized by higher temperatures and density scale heights than for CR-2081. On the other hand, the coronal hole region of CR-1915 shows lower temperatures than for CR-2081. The reported differences are in the range \({\approx}\,10\,\mbox{--}\,25\%\), depending on the specific physical quantity and region that is compared, as fully detailed in the analysis. For other regions and/or physical quantities, the uncertainties do not allow assessing the thermodynamical differences between the two rotations. Future investigation will involve a DEMT analysis of other Carrington rotations selected from both epochs, and also a comparison of their tomographic reconstructions with magnetohydrodynamical simulations of the inner corona.     

The theory of asynchronous relative motion I: time transformations and nonlinear corrections

Using alternative independent variables in lieu of time has important advantages when propagating the partial derivatives of the trajectory. This paper focuses on spacecraft relative motion, but the concepts presented here can be extended to any problem involving the variational equations of orbital motion. A usual approach for modeling the relative dynamics is to evaluate how the reference orbit changes when modifying the initial conditions slightly. But when the time is a mere dependent variable, changes in the initial conditions will result in changes in time as well: a time delay between the reference and the neighbor solution will appear. The theory of asynchronous relative motion shows how the time delay can be corrected to recover the physical sense of the solution and, more importantly, how this correction can be used to improve significantly the accuracy of the linear solutions to relative motion found in the literature. As an example, an improved version of the Clohessy-Wiltshire (CW) solution is presented explicitly. The correcting terms are extremely compact, and the solution proves more accurate than the second and even third order CW equations for long propagations. The application to the elliptic case is also discussed. The theory is not restricted to Keplerian orbits, as it holds under any perturbation. To prove this statement, two examples of realistic trajectories are presented: a pair of spacecraft orbiting the Earth and perturbed by a realistic force model; and two probes describing a quasi-periodic orbit in the Jupiter-Europa system subject to third-body perturbations. The numerical examples show that the new theory yields reductions in the propagation error of several orders of magnitude, both in position and velocity, when compared to the linear approach.     

Oxidation of copper(I) in seawater at nanomolar levels

The oxidation and reduction of nanomolar levels of copper in air-saturated seawater and NaCl solutions has been measured as a function of pH (7.17–8.49), temperature (5–35 °C) and ionic strength (0.1–0.7 M). The oxidation rates were fitted to an equation valid at different pH and ionic strength conditions in sodium chloride and seawater solutions:

The reduction of Cu(II) was studied in both media for different initial concentrations of copper(II). When the initial Cu(II) concentration was 200 nM, the copper(I) productions were 20% and 9% for NaCl and seawater, respectively. The effect of speciation of copper(I) reduced from Cu(II) on the rates was studied. The Cu(I) speciation is dominated by the CuCl₂⁻ species. On the other hand, the neutral chloride CuCl species dominates the Cu(I) oxidation in the range of 0.1 M to 0.7 M chloride concentrations.     

The determination of potential difference by the joint application of measured and synthetical gravity data: a case study in Hungary

In an elementary approach every geometrical height difference between the staff points of a levelling line should have a corresponding average g value for the determination of potential difference in the Earth’s gravity field. In practice this condition requires as many gravity data as the number of staff points if linear variation of g is assumed between them. Because of the expensive fieldwork, the necessary data should be supplied from different sources. This study proposes an alternative solution, which is proved at a test bed located in the Mecsek Mountains, Southwest Hungary, where a detailed gravity survey, as dense as the staff point density (~1 point/34 m), is available along a 4.3-km-long levelling line. In the first part of the paper the effect of point density of gravity data on the accuracy of potential difference is investigated. The average g value is simply derived from two neighbouring g measurements along the levelling line, which are incrementally decimated in the consecutive turns of processing. The results show that the error of the potential difference between the endpoints of the line exceeds 0.1 mm in terms of length unit if the sampling distance is greater than 2 km. Thereafter, a suitable method for the densification of the decimated g measurements is provided. It is based on forward gravity modelling utilising a high-resolution digital terrain model, the normal gravity and the complete Bouguer anomalies. The test shows that the error is only in the order of 10⁻³mm even if the sampling distance of g measurements is 4 km. As a component of the error sources of levelling, the ambiguity of the levelled height difference which is the Euclidean distance between the inclined equipotential surfaces is also investigated. Although its effect accumulated along the test line is almost zero, it reaches 0.15 mm in a 1-km-long intermediate section of the line.     

The IGS VTEC maps: a reliable source of ionospheric information since 1998

The International GNSS Service (IGS) Working Group on Ionosphere was created in 1998. Since then, the Scientific community behind IGS, in particular CODE, ESA, JPL and UPC, have been continuosly contributing to reliable IGS combined vertical total electron content (VTEC) maps in both rapid and final schedules. The details on how these products are being generated, performance numbers, proposed improvement as far as VTEC evolution trends during near one Solar Cycle, are summarized in this paper. The confirmation of (1) the good performance of the IGS combined VTEC maps, and (2) the characteristic VTEC variability periods, are two main results of this work.     

CPLat: first operational experimental processing center for SIRGAS in Argentina

The SIRGAS permanent GPS network which is in fact the IGS network densification for the American continent, consists today of more than 200 stations covering the continent and islands. It is currently processed by the IGS RNAAC SIR centre at Deutsches Geodätisches Forschungsinstitut producing weekly free solutions relying on IGS final orbits and EOP that contribute to the ITRF through IGS. By August 2006, the SIRGAS Working Group I had accepted five proposals for experimental processing centers within the region that would collaborate with IGS RNAAC SIR. One of them, Centro de Procesamiento La Plata (CPLat) in Argentina, began processing 60 stations on October 2006. By January 2007 CPLat reached operational capability, delivering weekly free solution SINEX files, with an internal consistency of 1.5 mm average for the horizontal components, and 3 mm in the vertical. Comparisons with IGS global and IGS RNAAC SIR weekly solutions were taken as external consistency indications, showing average RMS residuals of 1.8, 2.4 and 5 mm for the north, east, and vertical component, respectively. Analysis and comparison of adjusted solution time series from CPLat and other processing centers has proved to be highly valuable for solution QC, namely detection and identification of station anomalous behavior or modelling problems. These procedures will ensure the maintenance of the performance specifications for CPLat solutions. Action is being taken in order to guarantee the continuity of this effort beyond the experimental phase.