Thermal regime of the continental lithosphere

Thermally, the lithosphere may be defined as that outer portion of the earth in which heat is transferred primarily by conduction. It generally includes the crust and part of the mantle. The thermal regime of continental lithosphere is determined by many factors including heat flow from the asthenosphere, the vertical and lateral variation of both thermal conductivity and radiogenic heat production, tectonic history, and such superficial processes as climatic history and the shallow hydrothermal regime. From studies of the global heat flow data set, two generalizations regarding continental lithosphere have arisen, namely that: 1) there is a negative correlation between heat flow and tectonic age of continental lithosphere; and 2) the thermal evolution of continental lithosphere is similar to that of ocean basins with the result that the “stable geotherm” is similar in both environments. When continental heat-flow data are studied from a regional rather than a global point of view, considerable doubt arises as to the general applicability of either statement. R. U. M. Rao and his associates have demonstrated that while Precambrian terranes do have demonstrably lower heat flows than, say, Tertiary terranes, the data are not normally distributed and it is not possible to establish a negative correlation between heat flow and age in any rigorous statistical way. The scatter in the relation may be explained in terms of the variations in the duration, intensity and even the sign of continental thermotectonic events in contrast to the simple situation (creation of new oceanic lithosphere at mid-ocean ridges) which prevails in the oceans. The scatter also is partially attributable to the large and laterally variable radiogenic component of heat flow on continents. For a province for which a heat flow-heat production relation has been established, much of the scatter in surface heat flow due to crustal radiogenic heat production versus age is eliminated by determining reduced heat flow (surface heat flow minus radiogenic component) as a function of tectonic age, but much scatter remains, and it is still not possible to establish a heat flux-age relation in a rigorous way. Primarily because of the spatial variability in radiogenic heat production, no single geotherm can be used to characterize the thermal regime of a stable continental terrane. Thus, while some sites on stable continental blocks may have a geotherm fortuitously similar to that for old ocean basins, there is no reason to expect that this will be true generally, and many stable continental terranes will be characterized by geotherms markedly different from the geotherm for old ocean basins.     

Lees's topographic correction in heat flow and the geothermal flux in Tasmania

Summary Lees's topographic correction for a simple idealized hill is discussed and extended to a monoclinal structure. It is valuable as giving very simply the order of magnitude of the correction. A number of new measurements of temperature in Tasmanian boreholes has been made and the previous rather high value of over 2 cal/cm² sec for the heat flux has been confirmed. The variation of thermal conductivity through the thickness of a differentiated tholeiite sheet has been measured and found to be in reasonably good agreement with values calculated from chemical and modal analyses.     

Behaviour of strontium in subsurface calcium chloride brines: Southern Israel and Dead Sea rift valley

Calcium chloride brines are, as a rule, relatively rich in strontium, but the enrichment is usually limited and is found to be related to the concentration of calcium. The limiting mechanisms were evaluated as a model which comprises simple interactions between minerals and solutions. Based on the known ranges of strontium concentration in minerals, mineral solubilities and partition coefficients of strontium (both poorly known in certain cases), six fields of $\text{Sr}\text{Ca}$ molar ratios were defined in terms of participating minerals and processes: (a) 0.38?1.56 × 10^{? 3} by dolomitization of calcite; (b) 1.5?2.2 × 10^{? 2} due to dolomitization of aragonite; (c) 0.4?1.4 × 10^{? 2} as a result of solution-reprecipitation of calcite; (d)0.12?0.20 through transformation of aragonite to calcite; (e)0.10?0.60 through equilibrium of the pair calcite-strontianite; and (f)0.01?0.08 by equilibrium with gypsum and celestite.The model was applied to the analysis of two groups of brines from southern Israel which are originated in the coastal plain (group C) and in the rift valley (group R). The low $\text{Mg}\text{Ca}$ ratios of both water groups point to dolomitization as the main subsurface modifying process. $\text{Sr}\text{Ca}$ ratios of brines belonging to group C are consistent with dolomitization of aragonitic surface sediments at the beginning of their evolution. Brines of group R bear evidence to a similar pathway at the beginning of their evolution, but most of them were further affected by interaction with limestone.     

In vitro screening for endocrine disruptive activity in selected South African harbours and river mouths

Various waterborne anthropogenic contaminants disrupt the endocrine systems of wildlife and humans, targeting reproductive pathways, among others. Very little is known, however, regarding the occurrence of endocrine disruptive activity in South African freshwater ecosystems, and coastal ecosystems have not been studied in this regard. In a first attempt to investigate endocrine disruptive activity in South African coastal waters, surface water samples collected from harbours, river mouths and estuaries in three metropolitan municipalities, eThekwini (which includes Durban), Nelson Mandela (specifically Port Elizabeth Harbour) and City of Cape Town, were screened for (anti) oestrogenicity and (anti)androgenicity using recombinant yeast bioassays. Moreover, levels of the female hormone 17β-(o)estradiol (E2) were determined in all samples, as well as a selection of hydrocarbons in the eThekwini samples. A high proportion of samples collected from eThekwini were oestrogenic, whereas none from Port Elizabeth Harbour and only a single river mouth sampled in the City of Cape Town were oestrogenic. E2 was detected in all the samples tested, but at higher concentrations at the eThekwini and City of Cape Town localities than Port Elizabeth Harbour. In addition, the recombinant yeast assays revealed that anti-androgenicity was widespread, being detected in the majority of samples screened apart from those representing Port Elizabeth Harbour. Conversely, no anti-oestrogenic or androgenic activity was detected. Anti-androgenicity did not associate with hydrocarbon loads, providing evidence that other anti-androgens were responsible for the observed activity. The present data suggest potential reproductive disruption in marine and estuarine fauna inhabiting the eThekwini and City of Cape Town regions.     

东天山伊吾二叠纪花岗质杂岩体的锆石定年、地球化学及其构造意义

伊吾花岗质杂岩体主要由二长花岗岩和碱长花岗岩构成。锆石LA-ICP-MS U-Pb定年分析得到二长花岗岩和碱长花岗岩的侵位年龄分别为284.6±1.4Ma和284.0±1.1Ma。结合地质证据,此年龄表明该杂岩体形成于碰撞之后的二叠纪早期挤压-伸展转折阶段。岩石学、地球化学和同位素等方面的对比研究表明这两种岩石为同一岩浆演化的产物。与二长花岗岩相比,碱长花岗岩表现为硅、碱的含量较高,而铝的含量较低;富Th、U、Nb、Ta,贫Sr、P、Ti、Sm;DI和Rb/Sr升高,Nb/Ta和Zr/Hf下降,从二长花岗岩到碱长花岗岩表现出连续分异演化的趋势。计算得到二长花岗岩和碱长花岗岩的模式年龄(t_(DM))分别为693Ma和763Ma,ε_(Nd)(t)分别为+4.53和+4.64,(~(87)Sr/~(86)Sr)_i分别为0.703858和0.703855,表现出高ε_(Nd)(t)低(~(87)Sr/~(86)Sr)_i的特征。这些特征表明,伊吾岩体的岩浆来自新元古代时从亏损地幔分离出来的初生地壳源区。二长花岗岩岩浆是这种初生地壳岩浆演化的产物,而碱长花岗岩形成于二长花岗岩母岩浆经斜长石、磷灰石、钛铁氧化物、榍石、独居石、褐帘石和锆石等矿物分离结晶后的残留岩浆。     

Regional‐scale mapping of groundwater discharge zones using thermal satellite imagery

Mapping groundwater discharge zones at broad spatial scales remains a challenge, particularly in data sparse regions. We applied a regional scale mapping approach based on thermal remote sensing to map discharge zones in a complex watershed with a broad diversity of geological materials, land cover and topographic variation situated within the Prairie Parkland of northern Alberta, Canada. We acquired winter thermal imagery from the USGS Landsat archive to demonstrate the utility of this data source for applications that can complement both scientific and management programs. We showed that the thermally determined potential discharge areas were corroborated with hydrological (spring locations) and chemical (conservative tracers of groundwater) data. This study demonstrates how thermal remote sensing can form part of a comprehensive mapping framework to investigate groundwater resources over broad spatial scales. Copyright © 2013 John Wiley & Sons, Ltd.     

John’s creek valley: a mountainous catchment for long-term interdisciplinary human-environment system research in Upper Styria (Austria)

The John’s creek valley (Johnsbachtal) is presented as a long-term, interdisciplinary cooperation platform in upper Styria (Austrian Alps) that brings together the interests and knowledge of persons with different backgrounds (scientists, teachers, students, as well as local actors and the population) with the central aim to generate mutual benefit for all involved parties. It covers an area of around 65 km² with elevations between 600 and 700 m in the valley to over 2,300 m in the summit regions. Annual mean temperature ranges from approximately 8 °C in the lower elevations of the valley to below 0 °C in the summit regions. Annual precipitation mounts to values of 1,500 mm and more than 1,800 mm in the lower elevations and summit regions, respectively. To allow for a long-term monitoring of the complex meteorological and hydrological conditions in the area, a hydroclimatological monitoring network has been installed that is described in detail in this paper. A special characteristic of the installed meteorological stations is that they cover a large range of altitudes and, therefore, allow to capture the gradients in meteorological variables induced by the complex Alpine topography. Furthermore, the hydroclimatological monitoring network in John’s creek valley is largely independent of regular third-party project funding, and therefore, not temporarily limited in its existence. A number of catchment research activities that cover a variety of disciplines (e.g., climatology, hydrology, (hydro)geology, geomorphology) and that largely benefit from the hydroclimatological data recorded in John’s creek valley are presented together with preliminary results. The latter include spatial distributions of meteorological and hydrological variables (e.g., precipitation, evapotranspiration and snowmelt) calculated for the test site using the hydrometeorological model AMUNDSEN. Furthermore, the results of hydrogeological investigations that have been carried out at the Etzbach spring are presented and discussed.