Cotton Fiber/ZrO2, A New Material for Adsorption of Cr(VI) Ions in Water

The natural cotton fiber was used to synthesize an anion exchange, containing ZrO₂ film on its surface, NCFZC (natural cotton fiber/ZrO₂ composite). This anion exchanger was produced by the reaction of the zirconium oxychloride and hydroxyl groups on surface of the natural cotton fiber. The material was used for Cr(VI) ions adsorption studies. Adsorption equilibrium time and optimum pH for Cr(VI) adsorption were found to be 6 h and 4.0, respectively. The Langmuir and Temkin isotherms were used to models adsorption equilibrium data. The adsorption capacity of NCFZC was found to be 1.33 mmol/g. Kinetic studies showed that the rate of adsorption of Cr(VI) on NCFZC obeyed a pseudo‐second‐order kinetic model.     

Pegmatite Emplacement in the Seridó Belt, Northeastern Brazil: Late Stage Kinematics of the Brasiliano Orogen

Geometric and kinematic analysis was performed in an area located in the central part of the Seridó Belt (NE Brazil), where supracrustal rocks affected by polyphase deformation are well exposed. The first event recognized in this area (and regionally known as the D₂ deformation) is characterized by top to the south thrust tectonics while a second one (D₃ deformation) is marked by upright folds, strike-slip or transpressive shear zones and the development of flower structures. Major pegmatite swarms were emplaced during and late as regards the second event (dated ca. 580 Ma), being part of the Brasiliano orogeny; similar dyke swarms are known from the Nigerian Shield. These pegmatite swarms provide reliable kinematic markers of the late evolutionary stage of the Neoproterozoic Trans-Sahara-Borborema collisional belt. Mineralogical, geometric and kinematic features support two stages of pegmatite emplacement during the strike-slip event: (i) older, syn-D₃ homogeneous pegmatites intruded mostly along lithological and structural discontinuities, such as foliation surfaces; (ii) late, D₃ heterogeneous pegmatites were emplaced along tension gashes and other dilation structures. The heterogeneous pegmatites are economically more important, being exploited for precious metals and stones, as well as industrial minerals.     

Effects of the number of stations and time resolution on derivation

For at least 30 years now it has been well known that the Dst index can be modelled using the solar wind as input. Since then, many attempts have been made to improve the predictability of Dst using different approaches. These attempts are useful, for instance, to understand which features of the solar wind–magnetosphere interactions are most important in producing magnetospheric activity and how the Dst index would improve the space weather forecast. The Dst index is by far the most reliable and simple indication that a magnetic storm is in progress. In this work, the effect of using more than four magnetic stations and shorter time intervals than the hourly averages used in Sugiura's procedures is evaluated. The discussion is based on the results presented by Burton in 1975 and Feldstein in 1984 considering 4 or 12 magnetic stations and time averages of 2.5 min for a magnetic disturbed period that occurred from February 7–28, 1967, including two geomagnetic storms. The analysis has shown that the global representation of a magnetic storm by the standard Dst (Sugiura) is well preserved either using 4, 6, 12 magnetic stations or using 1 h, 2.5 min 1 min averages. A brief review of the current understanding of Dst has been included to support the discussions. The analysis performed has shown that a more refined Dst index (time and number of stations>4) would be useful to investigate the intrinsic processes and the different current systems involved in the ring current development during magnetic storms; the standard Dst, as it is conceived, is quite adequate to monitor geomagnetic storms and identify their overall features; concerning the magnetic stations normally considered, the inclusion of higher magnetic latitude stations (>35) may underestimate the observed Dst.     

Two Brazilian archaeological sites investigated by GPR: Serrano and Morro Grande

The application of the ground penetrating radar (GPR) at two archaeological sites, Serrano and Morro Grande, situated in Araruama County, Rio de Janeiro, Brazil, aids the study of a prehistoric indigenous culture, associated with the “Tupinambá” that inhabited the region during prehistoric times.The archaeological remains of the study area are mainly characterized by pottery artifacts for several uses, including funerary urns, which were buried within layers of sand and clay. Several profiles were acquired using a RAMAC system, with a 200 and 400 MHz frequency antennae. At the Serrano site, the profiles were acquired around some partially exposed pottery shards, due to sand exploitation. The resultant profiles provided a response model to guide the interpretation of new profiles acquired at other sites in the area, which present similar characteristics.The results showed the great importance of the dielectric permittivity contrast which exists between the targets and the host media, in order for possibly significant features to be identified in radar data.     

Interactive effects of environmental variability and human impacts on the long-term dynamics of an Amazonian floodplain lake and a South Atlantic coastal lagoon

Human activities are exposing freshwater ecosystems to a wide range of stressors, whose direct and indirect effects can be alleviated or exacerbated through interactive effects with dynamic environmental drivers. This study used long-term data from two Neotropical lacustrine freshwater systems (Batata Lake, an Amazonian floodplain lake and Imboassica lagoon, an Atlantic coastal lagoon) subjected to different kinds of environmental fluctuations (i.e., flood pulse and sandbar opening) and anthropogenic impacts (i.e., siltation and eutrophication). Our objective was to determine whether the effects of human perturbations are contingent on modifications of important biotic and abiotic characteristics through environmental variability. For both ecosystems, environmental variability consistently interacted with anthropogenic perturbations to alter most of the variables analyzed, such as nutrient dynamics, chlorophyll-a concentration, zooplankton and benthic invertebrate species richness, and temporal community stability, which indicates that interactive effects between environmental variability and anthropogenic perturbations may impact a myriad of ecosystem properties. Furthermore, the nature of these interactive effects was highly dependent on the variable considered and on the ecosystem analyzed. For example, at Imboassica lagoon, sandbar openings interacted synergistically with trophic state to increase the phosphorus concentration in the water column. At Batata Lake, flooding generally alleviated the negative effects of siltation on species richness by both diluting inorganic suspended material concentration and by promoting local recruitment from the regional species pool. Such results indicate that our ability to understand and predict the outcome of anthropogenic impacts on inland aquatic systems can be hampered if we consider human stressors as “static” phenomena disconnected from dynamic interactions with major local environmental drivers.     

Shear effects on hollow section piers under seismic actions: experimental and numerical analysis

Shear effects are often a very important issue on the seismic behaviour of piers, particularly for hollow section bridge piers. In fact, for this type of piers the cyclic response is similar to that of a structural wall in which both the transverse reinforcement ratio and the detailing can play an important role on its performance, even likely to be determinant in terms of the failure mechanism. On the other hand, codes and design guidelines are usually very conservative concerning shear capacity in order to avoid any shear failure mechanism likely to trigger well known catastrophic consequences. Therefore, research studies on this topic are still needed for a better understanding of pier cyclic shear response and also for improvement of the performance under seismic actions. Pursuing this general objective, this paper partially reports on an experimental/numerical campaign carried out on 1:4 reduced scale bridge piers in order to highlight and investigate shear-type problems. Within the scope of this paper, two specimens types were selected having equal rectangular hollow section (900 × 450 mm², 75 mm thick) but different transverse reinforcement detailing, namely one with a single stirrup per wall (representative of typical bridge construction without seismic design requirements) and another with multiple stirrups, according to Eurocode 8 provisions. Numerical simulations of the experimental results were also conducted aiming at contributing for complete and consistent interpretations of experimental results. Detailed modelling was performed allowing for realistic simulations of the non linear behaviour, particularly suitable when a significant shear component is involved. Therefore, the numerical strategy was based on a detailed 3D FEM discretization using a two-scalar variable damage model for the concrete constitutive law and a suitable cyclic behaviour law for steel bars represented by truss elements. Results have shown that shear deformation and failure modes are well simulated, while providing detailed insight concerning concrete damage pattern and distribution of yielding on the transverse and longitudinal reinforcement.     

Water Availability of Sub-Basins with Restrictions on Use under Climate Change Scenarios in Brazil

Water Resources - The Queima Pé Stream Basin (QPSB) and Ararão River Basin (ARB) in central Brazil have had recurrent problems with water scarcity. This may get worse under anthropogenic...     

Seismic fragility curves of as-built single-span masonry arch bridges

Masonry arch bridges are crucial elements in the railway transportation network throughout Europe. Although significant advances in seismic risk assessment of various bridge types have been made by developing fragility curves of generalized classes of structures, there are no comparable tools for masonry arch structures. In this context, this paper presents the construction of seismic fragility curves of single-span masonry bridges according to the limit analysis method. An iterative procedure is implemented to define the capacity curve of the equivalent single degree of freedom system through non-linear kinematic analysis. The process involves determination of the collapse mechanism, calculation of the limit load multiplier, and definition of the thrust line. The intrinsic variability of the seismic action is incorporated with the use of different sets of elastic spectra compatible with EC 8 Type-1 spectrum for various types of soil, with peak ground acceleration varying over the range 0.05–1.5 g. The fragility curves of the generalized classes of single-span masonry bridges are finally obtained from the effective ranges of the main geometric and material parameters affecting arch bridge capacity.     

Low Visibility Formation and Forecasting on the Northern Coast of Brazil

Visibility analysis and forecast at the Maceio International Airport in the Brazilian Northeast (NEB) was the principal goal of this investigation. Surface meteorological data of the Maceio International Airport were used for low visibility frequency study. Low visibility in NEB was provoked more frequently by light fog (LF) formation (1,098 or 92 h month^?1 on average). Haze and fog were very rare (81 h and one event per year, respectively on average). Light fog with a visibility less than 2 km usually was detected together with rain or drizzle. Low visibility was observed more frequently at night and during the rainy season. Applications of the Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model for light fog forecast were tested. Thermodynamic processes were studied by vertical profile, elaborated by: (1) National Centers for Environmental Prediction (NCEP) reanalysis data for Maceio (because of some radiosonde absence) and (2) forecast vertical temperature and humidity profiles were produced, using Air Parcels Trajectories of the HYSPLIT model at the pattern levels. The synoptic situations before and during low visibility phenomena were analyzed using different products of NCEP reanalysis, the high resolution (10 km) ETA model and infrared satellite images. Wave disturbance in the trade winds field, localized on the northwest periphery of the South Atlantic subtropical High, usually accompanied the phenomena. A humidity advection, weak ascendant movement and thermal inversion absence at the low levels were created by these waves. The middle level’s descendent movement provoked the humidity accumulation at levels below. Satisfactory results of the HYSPLIT model applications for light fog forecast were obtained with 12 h antecedence. In particular, stable level forecast by the ETA model was forecast satisfactorily with 12 h antecedence; vertical movements were predicted better with up to 48 h antecedence. The PSU/NCAR mesoscale model (MM5) and PAFOG models were tested for analysis and forecast of an intensive fog event. Intensive fog provoked a fatal accident of a small airplane near the Maceio Airport in 2007. These fog formation processes were studied by NCEP reanalysis data, the high resolution regional model MM5, and satellite and radar data. Fog formation was simulated by PAFOG model and satisfactory results were obtained with 10 h antecedence.     

Local disappearance of bivalves in the Azores during the last glaciation

The Pleistocene (Eemian) outcrops of Lagoinhas and Prainha, located at Santa Maria Island (Azores), were investigated and their fossil mollusc content reported. These studies revealed that the last glaciation affected two groups of molluscs: the ‘warm‐guest’ gastropods with West African or Caribbean affinities (e.g. Conus spp., Cantharus variegatus, Bulla amygdala, Trachypollia nodulosa) and shallow bivalve species mainly associated with sandy habitats (Ensis minor, Lucinella divaricata, and probably Laevicardium crassum). In this paper we focus on this group of bivalves, which has since locally disappeared from the Azores. We relate the local disappearance of these bivalves in the Azores with the lack of sand in the shelf. The specific characteristics of the Santa Maria shelf combined with the sea‐level drop during the Weichselian prevented deposition of the lowstand deposits and permitted erosion of the previous ones, leaving the shelf without a sediment cover. Copyright © 2008 John Wiley & Sons, Ltd.