秦岭太白山南麓降水中常量无机离子特征及其来源研究

以2011年11月至2014年9月连续采集的74个有效降水样品为研究载体,运用趋势分析法和相关分析法分析太白山南麓黄柏塬地区降水中常量无机离子（NH₄⁺、Ca²⁺、Na⁺、K⁺、Mg²⁺、SO₄^2-、NO₃^-、Cl^-、F^-）的化学特征,并结合富集因子法、端源贡献法及后向气流轨迹模型探究其来源。结果表明：研究区降水中各离子浓度大小顺序为Ca²⁺ > SO₄^2- > NH₄⁺ > NO₃^- > K⁺ > Na⁺ > Mg²⁺ > Cl^- > F^-,主要阳离子是Ca²⁺和NH₄⁺,共占阳离子总量的76.21%,主要阴离子是SO₄^2-和NO₃^-,共占阴离子总量的90.83%。降水总离子年平均浓度为404.64 μeq·L^-1,相对于国内外已研究的其他高山站点偏高,表现出典型的大陆型及人为源干扰的特征。受排放源、气象因子、植被、降水量等因素影响,降水总离子浓度表现出显著的季节差异,依次为冬季 > 春季 > 秋季 > 夏季。源解析结果显示降水中SO₄^2-和NO₃^-95%以上由人为源贡献,Ca²⁺和Mg²⁺主要来源于地壳风化,Na⁺海盐源和非海盐源贡献约各占一半,K⁺主要来自于非海盐贡献,而F^-和NH₄⁺则几乎全部由人为源贡献。不同路径气团影响下的降水离子组分具有明显不同,北方气团途径太原、石家庄、北京、兰州等工业发达城市,工业燃煤交通废气排放量大,降水中SO₄^2-、NO₃^-浓度均偏高,离子总浓度也明显高于南方气团。     

新疆东准噶尔北部荒漠区金属矿床白茎绢蒿植物地球化学异常特征及其找矿意义

东准噶尔北部荒漠区植被属土砾质荒漠植被类型,占优势的植物群落为白茎绢蒿(Seriphidium terrae-albae(Krasch)Poljak),覆盖度为20%~25%。为探讨植物地球化学方法在荒漠区找矿的有效性,本文选择了隐伏于荒漠覆盖下的喀拉通克铜镍矿、希勒库都克铜钼矿和阿克塔斯金铜矿作为实例,研究生长在这些矿床地表的白茎绢蒿植物地球化学异常特征及其与矿化的关系。研究发现:这些矿床上部均发育植物地球化学综合异常,综合异常的宽度略大于矿体或矿化带的宽度,异常元素组合具有套合性和分带性。本文认为:(1)植物异常中强度较高、清晰度及连续性较好、规模较大的主导元素组合及其异常参数可以作为区分不同矿化类型的标志或指标,进而圈定成矿靶区;(2)植物综合异常的空间分布及其套合性和分带性,能大致确定隐伏矿床(体)的位置;(3)植物异常的元素组合、异常规模和异常强度,能大致推测隐伏矿床(体)的埋藏深度和矿化规模。     

稳健总体最小二乘Helmert方差分量估计

对于总体最小二乘而言,经常需要处理不同精度或者不同类型的观测数据,根据先验方差来定权往往不准确,同时观测数据中可能含有粗差。针对这两个问题,提出稳健总体最小二乘Helmert方差分量估计,将稳健估计和Helmert方差分量估计同时应用于总体最小二乘中。最后通过两个实验的计算结果表明,该方法是可行的、有效的。     

南水北调中线核心区土地利用变化及其生态环境响应研究

本文以南水北调中线工程核心水源区淅川县为例,选取2004年TM、2014年GF1号影像等数据,解译获取了淅川县土地利用数据,对2004-2014年淅川县土地利用变化进行定量分析。通过选用区域生态环境质量模型,对研究期内淅川县土地利用变化的生态环境效应进行评估,并采用灰色关联法对导致淅川县生态环境质量变化的驱动因素进行分析。研究结果表明：① 2004-2014年,林地、建设用地和水域面积增加,耕地面积减少。在林地资源演化趋势上,有林地、疏林地、灌木林地和苗圃地与林地资源的整体演化格局一致,而宜林地和无立木林地、未成林造林地呈减少的趋势;② 在空间分布上,林地主要分布在海拔高、坡度较陡的北部山区,耕地和建设用地密集分布于海拔低、相对平缓的东南部地区;③ 2004年和2014年2期生态环境质量均在县域内表现出明显的空间差异,呈现出北高南低的分布趋势。研究期内淅川县区域生态环境质量指数从0.5443上升至0.6039,生态环境质量提高,其中宜林地和无立木林地转化为有林地、退耕还林对区域生态环境改善贡献最大;④ 局部地区生态环境呈负向发展,其中对森林资源采取掠夺式开采和粗放型管理、毁林开地对县域生态环境产生的负面影响最为深刻。⑤ 2004-2014年县域生态环境质量变化主要由政策和居民追求利益最大化的行为所驱动。     

Site classification of Turkish national strong-motion stations

Since 1973, the General Directorate of Disaster Affairs of Turkey has deployed several strong-motion accelerographs at selected sites. Within the framework of the project entitled Compilation of National Strong Ground Motion Database in Accordance with International Standards, site conditions were investigated within the upper 30-m depth by surface seismic and standard penetration tests. Preliminary characterization of the sites is made by making use of both geophysical and geotechnical criteria of NEHRP Provisions and Eurocode-8 site classification systems. The liquefaction susceptibility of those sites which comprise saturated cohesionless deposits is also determined. Mean shear-wave velocity, mean penetration resistance, site class, and liquefaction susceptibility of each site are tabulated. The Turkish strong-motion database supplemented by detailed information on site conditions is a valuable source of information particularly for those studies that put emphasis on the relationship between site conditions and strong-motion parameters.     

陕西高陵4．4级地震期间形变异常分析

2009年11月5日,陕西省高陵县发生了Ms4．4级地震,震前1周陕西形变资料出现多台项的短临异常。对异常特征和震源机制展开分析,结果显示：①异常幅度与震中距成反比;②异常方向和台项分布与震源机制相吻合。     

全数字摄影测量方法在地理信息数据更新中的应用

社会的飞速发展对测绘工作提出了新的要求,数据的现势性、数据采集的快速性矛盾逐渐突出,传统的数据更新方法生产成本高,更新周期长,已不能满足社会高速发展的需要。探索一条快速、高效的数据更新方法迫在眉睫。该文全面介绍了利用全数字摄影测量方法对已有1：1万3D数字产品进行更新的方法和技巧,在很大程度上缩短了数据更新周期,降低了数据更新的成本,提高了工作效率。     

Basin-wide Holocene environmental changes in the marginal area of the Asian monsoon,northwest China

In arid regions, because of spatial variability, using single climate records is difficult to reconstruct the past climate change for the drainage basins. Holocene environmental records were collected from the upper, middle and lower regions of the Shiyang River drainage basin in the marginal area of the Asian monsoon (northwest China). The main objective of this paper was to compare the records from the terminal lake and the middle and upper reaches of the basin to study the basin-wide environmental changes. During the early Holocene the vegetation was sparse, and the effective moisture was relatively low in the basin. The Holocene Climatic Optimum started between 7.0 and 8.0 cal ka BP, during which the lake level reached the highest level in the terminal lake; the vegetation density and the effective moisture reached the highest level during the Holocene in the drainage basin. From 4.7 cal ka BP the terminal lake began to shrink, while the vegetation density decreased dramatically. In the middle and upper regions of the drainage, the effective moisture began to decrease since 3.5 cal ka BP, and the arid tendency was earlier in the terminal lake than it was in the middle and upper regions of the drainage basin. During the early Holocene the relatively arid environment was affected by the gradually intensifying East Asian monsoon and the dry westerly winds. The mid-Holocene Optimum benefited from the intensive East Asian monsoon and the humid westerly winds. Then, the East Asian monsoon retreated since the late-Holocene. In the basin the arid tendency may be related to the retracting of the East Asian monsoon. However, the intensifying acidification after 1.5 cal ka BP may be correlated to the increasing dryness of the westerly winds.     

Ingestion of marine debris by loggerhead sea turtles, Caretta caretta, in the Adriatic Sea

We examined the occurrence of marine debris in the gastrointestinal tract of 54 loggerhead sea turtles (Caretta caretta) found stranded or incidentally captured dead by fisheries in the Adriatic Sea, with a curved carapace length of 25.0-79.2 cm. Marine debris was present in 35.2% of turtles and included soft plastic, ropes, Styrofoam and monofilament lines found in 68.4%, 42.1%, 15.8% and 5.3% of loggerheads that have ingested debris, respectively. The dry mass of debris per turtle was low, ranging from <0.01 to 0.71 g, and the ingestion was not significantly affected by sex or body size (all p > 0.05). Marine debris averaged 2.2 ± 8.0% of dry mass of gut content, with a maximum of 35% found in a juvenile turtle that most likely died due to debris ingestion. Considering the relatively high occurrence of debris intake and possible sub-lethal effects of even small quantities of marine debris, this can be an additional factor of concern for loggerheads in the Adriatic Sea.     

Identification of C24 and C25 lanostanes in Tertiary sulfur rich crude oils from the Jinxian Sag, Bohai Bay Basin, Northern China

Unusual short chain lanostanes (C₂₄ and C₂₅) and C₃₀ lanostane were identified in sulfur rich crude oils from the Jinxian Sag, Bohai Bay Basin, northern China. Besides the regular steranes (C_27-30), a series of 4-methyl steranes (C₂₂₋₂₃, C₂₇₋₃₀), 4,4-dimethyl steranes (C₂₂₋₂₄, C₂₈₋₃₀), short chain steranes (C₂₃₋₂₆), abundant pregnanes (C₂₁₋₂₂) and androstanes (C₁₉₋₂₀), together with sulfur containing steroids (20-thienylpregnanes and thienylandrostanes) were detected in the aliphatic and branched-cyclic hydrocarbon fraction of these crude oils. A literature survey of some long chain sterane analogues (e.g., A-nor-steranes, norcholestanes, C₃₀ steranes, lanostanes) and pregnanes seems to point to a sponge and/or dinoflagellate source. 4-Methyl, 4,4-dimethyl steroids and lanosterols (4,4,14-trimethyl steroids as the basic skeleton of lanostanes) can be derived from methanotrophic bacteria. Thus, a biological origin from a prokaryotic methylotroph can be used to explain the common source of abundant short chain steranes (C_23-26), 4-methyl (C_22-23) and 4,4-dimethyl steranes (C_22-24), as well as lanostanes (C_24-25 and C₃₀ analogues) in our oil samples. Generally, the steroids appear to have been extensively sulfurized with sulfur substitution at the C-22 position in the side chain during the early stage of diagenesis, which was readily subject to attack by bacterial degradation (enzymatic cleavage) and/or abiotic oxidation. As a consequence, short chain sterane analogues (e.g., abundant pregnanes and androstanes in this study) and short chain lanostanes (C₂₄−C₂₅) might later be released through cleavage of weak C-S bonds at the C-22 carbon in the sulfurized steroids and lanostane sulfides. Finally, the formation of the short chain C₂₄−C₂₅ lanostanes and distinctive occurrence of short chain steranes in this study can be well explained by microbial biodegradation of sulfurized lanostanoids and steroids in the reservoir.