Influence of basin characteristics on baseflow and stormflow chemistry in the Great Smoky Mountains National Park,USA

Relationships between stream chemistry and elevation, area, Anakeesta geology, soil properties, and dominant vegetation were evaluated to identify the influence of basin characteristics on baseflow and stormflow chemistry in eight streams of the Great Smoky Mountains National Park. Statistical analyses were employed to determine differences between baseflow and stormflow chemistry, and relate basin‐scale factors governing local chemical processes to stream chemistry. Following precipitation events, stream pH was reduced and aluminium concentrations increased, while the response of acid neutralizing capacity (ANC), nitrate, sulfate, and base cations varied. Several basin characteristics were highly correlated with each other, demonstrating the interrelatedness of topographical, geological, soil, and vegetative parameters. These interrelated basin factors uniquely influenced acidification response in these streams. Streams in higher‐elevation basins (>975 m) had significantly lower pH, ANC, sodium, and silicon and higher nitrate concentrations (p < 0.05). Streams in smaller basins (<10 km²) had significantly lower nitrate, sodium, magnesium, silicon, and base cation concentrations. In stormflow, streams in basins with Anakeesta geology (>10%) had significantly lower pH and sodium concentrations, and higher aluminium concentrations. Chemical and physical soil characteristics and dominant overstory vegetation in basins were more strongly correlated with baseflow and stormflow chemical constituents than topographical and geological basin factors. Saturated hydraulic conductivity, of all the soil parameters, was most related to concentrations of stormflow constituents. Basins with higher average hydraulic conductivities were associated with lower stream pH, ANC, and base cation concentrations, and higher nitrate and sulfate concentrations. These results emphasize the importance of soil and geological properties influencing stream chemistry and promote the prioritization of management strategies for aquatic resources. Copyright © 2012 John Wiley & Sons, Ltd.     

Physical Controls on Spatial Variability in Decomposition of Organic Matter in Lake Kinneret,Israel

High resolution chemical data collected during summer 2003 indicate that the lower water mass (LWM) of the thermally stratified Lake Kinneret (LK) can be subdivided into three layers: a benthic boundary layer (BBL), overlain by the hypolimnion (HYP), and on top, the lower part of the metalimnion (ME-L). After onset of thermal stratification, the BBL is the first layer that turns anoxic, followed shortly afterward by the ME-L, while the HYP remains oxic and has relatively higher pH until later in summer. Thus, during the early summer, the HYP forms an oxygen-containing layer in-between two DO-deficient layers. Somewhat later, the HYP is characterized by still having significant levels of nitrate NO₃, while in both adjacent layers nitrate is already removed through denitrification. The mechanisms controlling the gradual decline of dissolved oxygen (DO) in the HYP during the summer were studied. The seasonal mean lake-wide vertical eddy diffusion coefficient in this layer, evaluated from heat flux measurements, is approximately 4 × 10⁻⁶ m² s⁻¹. The vertical oxygen flux due to diffusion from within the HYP toward its oxygen-deficient upper and lower boundaries accounts for most of the slow summer decline in DO in this layer. A smaller portion of this decline can be attributed to in-layer respiratory processes. The low turbidity, relatively high pH, and slow accumulation rate of NH₄ in the HYP support the notion that the slower mineralization processes occurring in this layer result from relatively low ambient concentrations of biodegradable organic matter, most probably due to the short residence time of the particles settling through this layer.     

Rhessi and Trace Observations of the 21 April 2002 x1.5 Flare

Solar Physics - Observations of the X1.5 flare on 21 April 2002 are reviewed using the Reuven Ramaty High-Energy Solar Spectroscopic Imager (RHESSI) and the Transition Region and Coronal Explorer...     

Modeling Images and Spectra of a Solar Flare Observed by RHESSI on 20 February 2002

We have analyzed a C7.5 limb flare observed by RHESSI on 20 February 2002. The RHESSI images appear to show two footpoints and a loop-top source. Our goal was to determine if the data are consistent with a simple steady-state model in which high-energy electrons are continuously injected at the top of a semicircular flare loop. A comparison of the RHESSI images with simulated images from the model has made it possible for us to identify spurious sources and fluxes in the RHESSI images. We find that the RHESSI results are in many aspects consistent with the model if a thermal source is included between the loop footpoints, but there is a problem with the spectral index of the loop-top source. The thermal source between the footpoints is likely to be a low-lying loop interacting with the northern footpoint of a higher loop containing the loop-top source.     

Eigenrays in 3D heterogeneous anisotropic media,Part I: Kinematics

We present a new ray bending approach, referred to as the Eigenray method, for solving two‐point boundary‐value kinematic and dynamic ray tracing problems in 3D smooth heterogeneous general anisotropic elastic media. The proposed Eigenray method is aimed to provide reliable stationary ray path solutions and their dynamic characteristics, in cases where conventional initial‐value ray shooting methods, followed by numerical convergence techniques, become challenging. The kinematic ray bending solution corresponds to the vanishing first traveltime variation, leading to a stationary path between two fixed endpoints (Fermat's principle), and is governed by the nonlinear second‐order Euler–Lagrange equation. The solution is based on a finite‐element approach, applying the weak formulation that reduces the Euler–Lagrange second‐order ordinary differential equation to the first‐order weighted‐residual nonlinear algebraic equation set. For the kinematic finite‐element problem, the degrees of freedom are discretized nodal locations and directions along the ray trajectory, where the values between the nodes are accurately and naturally defined with the Hermite polynomial interpolation. The target function to be minimized includes two essential penalty (constraint) terms, related to the distribution of the nodes along the path and to the normalization of the ray direction. We distinguish between two target functions triggered by the two possible types of stationary rays: a minimum traveltime and a saddle‐point solution (due to caustics). The minimization process involves the computation of the global (all‐node) traveltime gradient vector and the traveltime Hessian matrix. The traveltime Hessian is used for the minimization process, analysing the type of the stationary ray, and for computing the geometric spreading of the entire resolved stationary ray path. The latter, however, is not a replacement for the dynamic ray tracing solution, since it does not deliver the geometric spreading for intermediate points along the ray, nor the analysis of caustics. Finally, we demonstrate the efficiency and accuracy of the proposed method along three canonical examples.     

The Low Compaction Grading Technique on Steep Reclaimed Slopes: Soil Characterization and Static Slope Stability

Since the Surface Mining and Control Reclamation Act of 1977, US coal mining companies have been required by law to restore the approximate ground contours that existed prior to mining. To ensure mass stability and limit erosion, the reclaimed materials have traditionally been placed with significant compaction energy. The Forest Reclamation Approach (FRA) is a relatively new approach that has been successfully used to facilitate the fast establishment of native healthy forests. The FRA method specifies the use of low compaction energy in the top 1.2–1.5 m of the contour, which may be in conflict with general considerations for mechanical slope stability. Although successful for reforestation, the stability of FRA slopes has not been fully investigated and a rational stability method has not been identified. Further, a mechanics-based analysis is limited due to the significant amount of oversize particles which makes the sampling and measurement of soil strength properties difficult. To investigate the stability of steep FRA slopes (steeper than 20°), three reclaimed coal mining sites in the Appalachian region of East Tennessee were investigated. The stability was evaluated by several methods to identify the predominant failure modes. The infinite slope method, coupled with the estimation of the shear strength from field observations, was shown to provide a rational means to evaluate the stability of FRA slopes. The analysis results suggest that the low compaction of the surface materials may not compromise the long-term stability for the sites and material properties investigated.     

ASSESSING THE ONSET OF SPRING: A CLIMATOLOGICAL PERSPECTIVE

This study is part of a program to examine spring plant-climate interactions in the major agricultural regions of eastern North America. The project's objectives were to: (1) document the yearly onset of the spring green wave and associated phenomena from 1908 to 1987 using phenological models, and (2) analyze regional dynamics and recent changes. Examining past variations in the green wave provides a context within which present and future variations can be assessed. Spring index dates, last -2.2°C (28°F) frost dates, and the difference between these two dates (termed the damage index) were generated for selected United States Daily Historical Climatology Network (HCN) stations between 1908 and 1987. The results show considerable geographic and temporal variations over the study period, and suggest that the threat of late spring frost damage may have decreased slightly from about 1960 to 1987. In future research, an improved version of the spring index (and associated surface phenological data) will be compared with satellite-derived vegetation condition data, in order to facilitate many kinds of atmosphere-biosphere interaction studies. [Key words: phenology, spring, “green wave” climatology.]     

Increasing temperature and flow management alter mercury dynamics in East Fork Poplar Creek

East Fork Poplar Creek (EFPC) is a mercury (Hg) contaminated creek in east Tennessee, USA. Stream restoration activities included the initiation of a flow management programme in 1996 in which water from a nearby lake was pumped to the head of the creek. We conducted regular water sampling for 2 years along the length of EFPC during active flow management and for 5 years after flow management stopped. Total Hg and total monomethylmercury (MMHg) concentration and flux decreased in the uppermost reaches of EFPC that were closest to the point of water addition. Most water quality parameters, including DOC concentration, remained unchanged after flow management termination. Nevertheless, SUVA₂₅₄, a measure of dissolved organic matter (DOM) composition, increased and coincided with increased dissolved Hg (Hg_D) concentration and flux and decreased Hg solid-water partitioning coefficients throughout EFPC. Higher SUVA₂₅₄ and Hg_D concentration have potential implications for bioavailability and MMHg production. Total and dissolved MMHg concentrations increased in lower reaches of EFPC after the end of flow management and these increases were most pronounced during spring and early summer when biota are more susceptible to exposure and uptake. A general warming trend in the creek after active flow management ended likely acted in concert with higher Hg_D concentration to promote higher MMHg concentration. Total and dissolved MMHg concentrations were positively correlated with water temperature above a threshold value of 10°C. Concentration changes for Hg and MMHg could not be accounted for by changes in creek discharge that accompanied the cessation of flow management. In addition to the changing DOM composition in-stream, other watershed-scale factors likely contributed to the observed patterns, as these changes occurred over months rather than instantaneously after flow management stopped. Nevertheless, similar changes in MMHg have not been observed in a tributary to EFPC.