一种新的流动注射在线共沉淀技术的研究及应用

建立了应用流动注射在线共沉淀分离富集火焰原子吸收法测定天然水样中痕量铬的价态分析方法。利用铬（Ⅲ）在碱性条件下与氢氧化镧形成共沉淀而与共存离子分离并得到富集，沉淀不需过滤，直接用稀盐酸从编织反应器（ＫＲ）中溶解并洗脱下来，用原子吸收测定。本体系的浓集倍率２２，检出限（３σ）０．８μｇ／Ｌ，相对标准偏差（ｎ＝１１）２．７２％，用水标样考察，分析结果与推荐值相符。该方法成功地用于天然水中铬的快速测定。     

Correcting for crystal tilt in HRTEM images of minerals: the case of orthopyroxene

High-resolution transmission electron microscopy (HRTEM) is a powerful technique for crystal structure imaging and real structure analysis. It is theoretically possible to resolve inter-atomic distances with modern high resolution microscopes. In practice, however, the effects of sample and lens parameters such as crystal tilt and phase contrast transfer function (CTF) distort the images, reduce the resolution offered, and make image interpretation difficult. We have analyzed to what extent it is possible to reconstruct interpretable images of a tilted mineral by image processing.HRTEM images of orthopyroxene were simulated for a series of crystal tilts and thicknesses under Scherzer defocus condition using the parameters of a 400 kV microscope. The tilted images were reconstructed by crystallographic image processing. After correcting for crystal tilt, the images were as good as electron density maps calculated from X-ray diffraction structure factors.     

激光钻进煤岩技术的研究进展

激光钻进技术是一种极具潜力的创新技术,也是钻探领域的研究热点。作为一种非接触式钻进技术,对破碎松软岩层扰动破坏小,将激光钻进应用于煤层气定向钻进中可发挥出非常明显的优势。梳理和总结了激光用于煤岩钻进的成孔机制、钻进效果的影响因素。在激光钻进过程中,激光与煤岩相互作用伴随着复杂的理化作用,指出激光钻进煤岩主要的成孔机制是烧蚀成孔。从激光参数、岩石性质、外部环境等方面阐述了影响激光钻进煤岩效果的因素,论述了激光钻进用于煤岩这一特定钻进对象的特殊现象和问题,指出煤岩在激光照射下,组分的挥发、热解、升华、烧结和氧化构成了煤岩在高温下主要的热烧蚀机制。从钻进机理、工艺、装置等方面着手,建议加强激光钻进煤岩的多物理场耦合作用机制、钻进工艺、钻进装置研制等适应性研究,为激光用于煤岩的高质高效钻进研究提供参考。     

An improved ionosphere interpolation algorithm for network RTK in low-latitude regions

A traditional interpolation algorithm with the linear interpolation method (LIM) using a fixed number of reference stations is widely used in network RTK to obtain the ionospheric delays for the users. In low-latitude regions, where the ionosphere is relatively active, however, large interpolation errors exist, especially for satellites at low elevation angles. Considering the characteristics of “coinciding ionospheric pierce points (CIPPs)” with a similar nature of ionospheric delays, an improved interpolation algorithm is proposed. In this algorithm, all stations with CIPPs are used to establish the interpolation model; thus, more precise interpolation model is achieved. To validate the performance of the proposed algorithm, data from some reference stations in Guangdong Province of China were used, and the results are compared with those with the traditional interpolation algorithm. Numerical analysis shows that the interpolation accuracy of the proposed algorithm increases by 10–30% compared with the traditional one. Since the number of reference stations is flexible, the proposed algorithm can also balance the model accuracy with the computation burdens. In addition, the proposed algorithm is less affected by the selection of master reference station. In terms of network RTK on-the-fly positioning, the time-to-first-fix is reduced when replacing the traditional interpolation algorithm with the proposed one.     

Distribution of water vapor content (WVC) and its seasonal variation over the mainland of China

Based on the meteorological data of 105 aerological stations during the period of 1960－1969, the monthly average water vapor content (WVC) in air column over the mainland of China is calculated. Charts showing the distribution of mean WVC for January and July and its seasonal variation associated with the atmos-pheric circulation in the lower troposphere over East Asia are also presented. Results obtained from this anal-ysis will contribute to the assessment of water resources, as well as the studies of the formation of rainfall and climate.     

THE EFFECT OF ASPECT RATIO ON THE BIFURCATION PROPERTIES OF A DOUBLE PARALLEL-CONNECTION LORENZ SYSTEM

A double parallel-connection (DPC) Lorenz system is developed by performing spectrum truncation of the Galerkin series expansion of the two-dimensional Rayleigh-Benard convection equation. Analyses of the equilibrium states indicate that a convective roll stems from a flow with a given wavenumber first losing its stability for a particular aspect ratio β after a stable laminar flow gets unstable; when β has the value βc able to deprive synchronously two flows with different wavenumbers of stability, occurrences of convective rolls with different wavenumbers depend entirely on the initial conditions, in good agreement with the relevant experimental results. The calculations of the unstablized rolls show that, with a smaller β (as compared with βc), the DPC Lorenz system has the same bifurcation properties as the ordinary Lorenz system; for a moderate β, the system has very complicated periodic, quasi-periodic and phase-locking motions; for a larger β, it results in intermittent chaos and causes mean flows with different numbers of vortices to occur alternately with time. All these indicate that β has substantial effect on the two Lorenz systems coupled through parallel connection in their interaction and the results.     

我国可能最大暴雨洪水研究的进展

我国的暴雨洪水大、人口众、土坝多。为了保障人民生命财产和工农业的安全,许多大型、重要的中小型水库多采用可能最大暴雨洪水作为设计、校核的标准。在水文与气象人员的协作下,我国近十年来的可能最大暴雨与洪水计算方法得到一定的发展,提出了具有中国特色的方法、论文和一些专著,并开始了国际交流。本文综述这方面的进展并提出了几点看法。     

Three-dimensional variational data assimilation of WindSat ocean surface winds for the genesis and forecasting of tropical storm Henri

With available high-resolution ocean surface wind vectors retrieved from the U.S. Naval Research Laboratorys WindSat on Coriolis, the impact of these data on genesis and forecasting of tropical storm Henri is examined using the non-hydrostatic, fifth-generation mesoscale model (MM5) of Pennsylvania State University-National Center for Atmospheric Research plus its newly released three-dimensional variational data assimilation (3DVAR) system. It is shown that the assimilation of the WindSat-retrieved ocean surface wind vectors in the 3DVAR system improves the model initialization fields by introducing a stronger vortex in the lower troposphere. As a result, the model reproduces the storm formation and track reasonably close to the observations. Compared to the experiment without the WindSat surface winds, the WindSat assimilation reduced an error between the model simulated track and observations of more than 80 km and also improved the storm intensity by nearly 2 hPa. It suggests that these data could provide early detection and prediction of tropical storms or hurricanes.     

Lead isotopic exploration intersecting mineralization zones for the depth forecast of concealed deposits

Pb isotopic geochemical exploration intersecting mineralization zones have been well developed in the light of the eigenvaluesV ₁ andV ₂ of three-dimensional topological projection of Pb isotopic data. The newly developed theoretical model forecasting concealed deposits has been verified in the evaluation of Longbohe copper deposit in Jinping, Yunnan Province, which is consistent with the observed law of depth variation for Pb isotopes. The forecasting results show that the depth of buried major orebody should occur at about -50 to -400 m and deeper within the eastern and western mineralization belts of Longbohe copper deposit.