利用GPS拖体在万山区域测量平均海面技术研究

Wanshan area has been chosen to be the specified field to calibrate and validate(Cal/Val) the HY-2 altimeter and its follow-on satellites. In March 2018, an experiment has been conducted to determine the sea surface height(SSH) under the HY-2 A ground track(Pass No. 203). A GPS towing-body(GPS-TB) was designed to measure the SSH covering an area of about 6 km×28 km wide centered on the HY-2 A altimeter satellite ground track. Three GPS reference stations, one tide gauge and a GPS buoy were placed in the research area, in order to process and resolve the kinematic solution and check the precision of the GPS-TB respectively. All the GPS data were calculated by the GAMIT/GLOBK software and TRACK module. The sea surface was determined by the GPS-TB solution and the tide gauge placed on Zhiwan Island. Then the sea surface of this area was interpolated by Arc GIS10.2 with ordinary Kriging method. The results showed that the precision of the GPS-TB is about 1.10 cm compared with the tide gauge placed nearby, which has an equivalent precision with the GPS buoy. The interpolated sea surface has a bias of –1.5–4.0 cm with standard deviation of 0.2–2.4 cm compared with the checking line. The gradient of the measured sea surface is about 1.62 cm/km along the HY-2 orbit which shows a good agreement compared with the CLS11 mean sea surface(MSS). In the Cal/Val of satellites, the sea surface between the tide gauge/GPS buoy and the footprint of altimeter can be improved by this work.     

Prediction of polar motion

Based on an analysis of polar motion behavior, we found the possibility of predicting polar motion up to one year in advance. Comparing these predicted polar coordinates with the observed ones (smoothed), the rms of the differences is about 0".02. The differences of the relative polar motion are much smaller. For any time interval of 20–30 days throughout the whole year, the rms of the relative polar motion differences is about 0".01. It appears that 80–90% of the polar motion is composed of the stable, predictable Chandler and annual terms.     

Characterization,dissolution and solubility of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb<Subscript>x</Subscript>Ca<Subscript>1−x</Subscript>)<Subscript>5</Subscript>(PO<Subscript>4</Subscript>)<Subscript>3</Subscript>OH] at 25 °C and pH 2–9

Background

The interaction between Ca-HAP and Pb²⁺ solution can result in the formation of a hydroxyapatite–hydroxypyromorphite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)], which can greatly affect the transport and distribution of toxic Pb in water, rock and soil. Therefore, it’s necessary to know the physicochemical properties of (Pb_xCa_1?x)₅(PO₄)₃(OH), predominantly its thermodynamic solubility and stability in aqueous solution. Nevertheless, no experiment on the dissolution and related thermodynamic data has been reported.

Results

Dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)] in aqueous solution at 25 °C was experimentally studied. The aqueous concentrations were greatly affected by the Pb/(Pb + Ca) molar ratios (X_Pb) of the solids. For the solids with high X_Pb [(Pb_0.89Ca_0.11)₅(PO₄)₃OH], the aqueous Pb²⁺ concentrations increased rapidly with time and reached a peak value after 240–720 h dissolution, and then decreased gradually and reached a stable state after 5040 h dissolution. For the solids with low X_Pb (0.00–0.80), the aqueous Pb²⁺ concentrations increased quickly with time and reached a peak value after 1–12 h dissolution, and then decreased gradually and attained a stable state after 720–2160 h dissolution.

Conclusions

The dissolution process of the solids with high X_Pb (0.89–1.00) was different from that of the solids with low X_Pb (0.00–0.80). The average K _sp values were estimated to be 10^?80.77±0.20 (10^?80.57–10^?80.96) for hydroxypyromorphite [Pb₅(PO₄)₃OH] and 10^?58.38±0.07 (10^?58.31–10^?58.46) for calcium hydroxyapatite [Ca₅(PO₄)₃OH]. The Gibbs free energies of formation (ΔG _f ^o ) were determined to be ?3796.71 and ?6314.63 kJ/mol, respectively. The solubility decreased with the increasing Pb/(Pb + Ca) molar ratios (X_Pb) of (Pb_xCa_1?x)₅(PO₄)₃(OH). For the dissolution at 25 °C with an initial pH of 2.00, the experimental data plotted on the Lippmann diagram showed that the solid solution (Pb_xCa_1?x)₅(PO₄)₃(OH) dissolved stoichiometrically at the early stage of dissolution and moved gradually up to the Lippmann solutus curve and the saturation curve for Pb₅(PO₄)₃OH, and then the data points moved along the Lippmann solutus curve from right to left. The Pb-rich (Pb_xCa_1?x)₅(PO₄)₃(OH) was in equilibrium with the Ca-rich aqueous solution.

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Graphical abstractLippmann diagrams for dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃OH] at 25??C and an initial pH of 2.00.

     

山东郯城麦坡中更新世地震事件记录*

山东郯城麦坡被命名为典型地震活动断层遗址,其最醒目的标志是郯庐断裂带主干断层(F₂)东盘的紫灰色下白垩统逆冲到断层西盘的红棕色第四系之上且界线截然。野外调查和试验分析表明,郯城麦坡第四系于泉组中发育液化砂涌管、液化砂脉、震裂缝充填构造和同沉积断层等地震引发的软沉积物变形构造——地震事件记录。根据软沉积物变形构造的砂质黏土光释光测年分析,推断这些软沉积物变形构造所记录的地震事件属郯庐断裂带主干断层F₂在中更新世晚期发生的强构造与地震活动。这些地震事件记录为研究郯庐断裂带新构造运动与地震活动提供了新资料,也丰富了该地震活动断层遗址的内涵。     

Elemental characteristics of lacustrine oil shale and its controlling factors of palaeo-sedimentary environment on oil yield: a case from Chang 7 oil layer of Triassic Yanchang Formation in southern Ordos Basin

As an important unconventional resource, oil shale has received widespread attention. The oil shale of the Chang 7 oil layer from Triassic Yanchang Formation in Ordos Basin represents the typical lacustrine oil shale in China. Based on analyzing trace elements and oil yield from boreholes samples, characteristics and paleo-sedimentary environments of oil shale and relationship between paleo-sedimentary environment and oil yield were studied. With favorable quality, oil yield of oil shale varies from 1.4% to 9.1%. Geochemical data indicate that the paleo-redox condition of oil shale’s reducing condition from analyses of V/Cr, V/(V + Ni), U/Th, δU, and authigenic uranium. Equivalent Boron, Sp, and Sr/Ba illustrate that paleosalinity of oil shale is dominated by fresh water. The paleoclimate of oil shale is warm and humid by calculating the chemical index of alteration and Sr/Cu. Fe/Ti and (Fe + Mn)/Ti all explain that there were hot water activities during the sedimentary period of oil shale. In terms of Zr/Rb, paleohydrodynamics of oil shale is weak. By means of Co abundance and U/Th, paleo-water-depth of oil shale is from 17.30 to 157.26 m, reflecting sedimentary environment which is mainly in semi deep–deep lake facies. Correlation analyses between oil yield and six paleoenvironmental factors show that the oil yield of oil shale is mainly controlled by paleo-redox conditions, paleoclimate, hot water activities, and depth of water. Paleosalinity and paleohydrodynamics have an inconspicuous influence on oil yield.     

The roles of different mechanisms related to the tide-induced fronts in the Yellow Sea in summer

In summer, the Yellow Sea Cold Water Mass （YSCWM） is a stable water mass of low temperature lying at the bottom of the central Yellow Sea （YS）. It is fringed by some typical tidal fronts, which separate deep, stratified water on the offshore side from the well-mixed, shallow water on the inshore side. Three striking fronts--Subei Bank Front （SBF）, Shandong Peninsula Front （SPF）, and Mokpo Front （MKF; a front off the southwestern tip of the Korean Peninsula）--have been iden- tified by various studies from both satellite observations and model results. Tide plays an important role in the formation and maintenance of these fronts. However, it is still a matter of debate as to the roles these two kinds of mechanisms of upwelling and tidal mixing play, and how importance they are in the maintenance processes of the above three fronts. Basing a nested high-resolution model HYCOM （the Hybrid Coordinate Ocean Model）, this study focuses on the different mechanisms of tidal effects on the thermal fronts in the YS in summertime. Through comparative experiments with and without tidal forcing, the results indicate that the MKF is mainly driven by tide-induced upwelling. For the SPF, tidal mixing is the dominant factor, when lower cold water is stirred upwards along the sloping topography of the western YS. Meanwhile, the combined effect of upwelling and tidal mixing is the main cause of the formation of the SBF. Diagnostic analysis of thermal balance shows that horizontal nonlinear advection induced by strong tidal currents also contributes to the thermal balance of frontal areas.     

城市化进程对重庆都市圈降水空间分布的影响

基于小时分辨率降水过程辨识和评估方法,利用1980—2019年逐小时降水气象观测资料,分析了京津冀、长三角、珠三角、成渝、长江中游、中原、关中平原等七个城市群在城市不同发展阶段降水过程的年变化和月变化布特征。结果表明,城市快速发展期（2000—2019年）,七个城市群降水过程次数呈增多趋势,尤其是2010年之后明显增加;冬季降水过程次数出现从无到有,从少到多的变化趋势;年平均降水时数增长,但过程平均时数缩短;降水过程持续时间3、4月增加,5、6、7月有减少趋势,8、9月为增加趋势;极端+特强+强降水过程逐年累计次数呈增加趋势;极端和特强降水过程次数8、9月份有明显增加趋势,强降水过程3—6月为增加趋势,冬季较强和中等强度降水过程增多。

     

气溶胶粒子谱的观测分析

本文对我国北京附近三个地方的气溶胶粒子浓度的观测资料进行了分析研究,并分别用Junge分布和Deirmendjian分布分段进行拟合,这样拟合精度较高且能反映不同半径范围内气溶胶粒子的分布特征。     

类星体的成线排列

以Savage-Bolton的两个5°×5°天区的光学类星体巡天为样品,本文系统地分析了成线排列的类星体数目,并与由Monte Carlo方法产生的随机样品进行了比较。统计结果表明,类星体成线排列现象至少在这组样品中不明显。     

地勘单位经济运行中关键环节管理与执行力问题探讨

对地勘单位经济运行中的资金管理、成本管理、制度管理等三个关键环节的作用及运行状况进行分析,指出其运行过程中存在的三个共性问题,即制度不健全,经营机制不完善;成本管理滞后,经济效益不明显;资金管理不规范,经济运行质量不高。地勘单位经济运行执行力就是地勘单位实现经济运行目标的能力。提高地勘单位经济运行执行力的关键是解决经济运行中存在的问题,为此提出了建立健全制度、完善经营机制,强化资金管理、确保生产经营正常进行,加强成本管理、提高经济运行质量等对策和措施。探索地勘单位提升管理水平,增强管理执行力,推动煤田地质经济健康持续发展。