浙闽近海瓯江凹陷新生代地质构造发展特征

瓯江凹陷的上白垩统和下第三系建造序列具体反映了断凹演化。断陷阶段分为初始开裂、强裂裂开、全面裂陷和频繁振荡。凹陷阶段沐现了海浸—沉降—填满全过程,凹陷由数个剖面上呈箕状的菱形次级小断块组成。这种结构及发展特征既与弧后垃开体制有关,也与瓯江凹陷处于中生代地体碰撞带有关。瓯江凹陷是东海陆架弧后裂陷盆地的一部分。     

区域重力地改“测点高程平移法”精度探讨

在讨论测点高程平移法区域重力地改的精度问题基础上，提出了系统差概念，并推荐一种新的计算方法，即把测点高程平移法和节点高程插值法有机地结合起来实现地改，通过理论模型和实例计算，表明该方法计算精度优于节点高程插值法和测点高程平移法。     

一颗罕见的金丝猫眼宝石的鉴定

一颗蛋圆形的猫眼宝石,经采用无损伤鉴定研究,确定为天然顽火辉石——金丝猫眼石。其特征为:重1.38g,呈茶褐色,玻璃光泽,Hv(50)1145kg/mm~2(莫氏硬度7级),具平行细密纹理,猫眼光学效应,明显的多色性及平行消光。电子探针分析(％):SiO_2 61.11,MgO 33.71,FeO 3.78,总量为98.60。化学式为(Mg_(1.72) Fe_(0.11))_(1.83)[Si_(2.08)O_6]。     

大兴安岭中南段中生代成矿物质的深部来源与背景

大兴安岭是我国北方一个重要的多金属成矿带。本文从成矿的物质来源和构造作用两方面讨论大兴安岭的成矿系统。Sr、Nd、O、Pb同位素的研究显示大兴安岭成矿物质的深部来源,大兴安岭晚中生代壳幔混熔花岗质岩石组成及其构造环境的研究,表明它们是在板内非造山的伸展环境下形成的A型花岗岩。与南岭花岗岩及其成矿作用的对比研究,将加深对大兴安岭中生代成矿特征的认识。深部构造特征也进一步印证了大兴安岭的成岩-成矿的背景。     

丹凤地区秦岭岩群片麻岩锆石U-Pb年龄:北秦岭地体中-新元古代岩浆作用和早古生代变质作用的记录

秦岭岩群被认为是出露于北秦岭地体内最古老的前寒武纪基底岩石,记录了北秦岭造山带的地壳形成和演化历史。本文报道丹凤-西峡地区五件秦岭岩群片麻岩锆石U-Pb年龄结果,限定其形成和变质时代,探讨北秦岭地体的构造归属。定年结果表明,岩浆成因锆石颗粒的年龄集中在1400～1600Ma左右和850～950Ma左右,记录两期主要岩浆活动。6粒锆石具有变质成因特征,低Th/U比值(0.03),206Pb/238U年龄变化在510～465Ma之间,加权平均值477±18Ma。这一古生代变质叠加时代与北秦岭地体南北缘高压变质作用时代基本一致,说明秦岭岩群遭受到北秦岭造山带俯冲-碰撞造山过程的变质作用。秦岭岩群主要形成于中元古代晚期至新元古代早期,基底岩石缺乏早元古代和太古代岩浆活动的记录。在岩浆作用时代上,北秦岭地体与广泛发育新元古代中-晚期岩浆作用的扬子陆块北缘有差别,也不同于晚太古代-早元古代的华北陆块南缘,可能是中-新元古代形成的独立微陆块。     

正态分布检验在地下水检测质量控制中的应用

对地下水调查中37种必测组分检测过程的替代物进行筛选,应用D’Agostino法对替代物的测量结果进行正态性检验。利用正态分布函数"3σ"原则,定义了各替代物质量控制指标的有效区间。应用正态函数随机变量的数学期望和方差,计算得到各替代物有效区间内的正态函数分布概率均大于97%,替代物过程能力指数计算结果表明,二溴氟代甲烷、甲苯-d8、对溴氟苯、1,2-二氯苯-d4、氟苯等挥发性有机污染物分析过程选用的替代物质量控制过程处于稳定的监控状态;2,4,5,6-四氯间二甲苯、二丁基氯菌酸酯、p-三联苯、十氯联苯等半挥发性有机污染物分析过程选用的替代物监控指标分析过程能力不足。建议参考美国EPA方法中有关监控指标质量控制区间的要求,适当放宽对半挥发性有机物检测流程中选用的替代物质量控制区间的有效范围。正态分布在地下水检测过程质量控制中的应用,为实验室检测过程的质量管理提供了科学、有效的数学依据。     

Relationship between garnet skarn and W mineralization: A case study from the Tongshankou Cu-Mo-W deposit,Daye, Hubei.SCIEI北大核心CSCD

石榴子石是矽卡岩型矿床的标志性矿物之一,其结构和成分特征被广泛用来示踪早期成矿流体性质的变化,但其生长过程与金属元素富集过程的关系还不清楚。本文对长江中下游成矿带最西端鄂东矿集区内的铜山口铜钼钨矿床中的石榴子石开展了显微结构和电子探针主量元素、LA-ICP-MS微量元素点分析和面扫描分析。结果显示,铜山口矿床中的石榴子石端元成分以钙铁榴石-钙铝榴石为主,普遍含有一定量的W,特别是在钙铁榴石端元比例高的石榴子石中(可达3898×10-6),且W与Mo、As、Sn存在明显的正相关关系、与Ti存在一定的负相关关系,指示W以类质同象的方式进入石榴子石晶格。石榴子石可包裹结构简单的白钨矿或被具复杂结构的白钨矿交代,指示石榴子石记录了白钨矿形成前和形成过程中流体性质(氧逸度和W含量等)的变化。铜山口矿床中钙铁榴石的大量结晶,导致成矿早期W的大量分散,不利于高品位和大规模钨矿的形成,仅在这些钙铁榴石遭受强烈的退化蚀变时,释放的W在一定程度能够提高矿石的品位,这可能是氧化性矽卡岩型钨矿通常比还原性矽卡岩型钨矿品位低、规模小的重要原因。石榴子石的成分特征(如W、Sn等元素含量和W/Sn、W/Mo和W/As等比值)可以作为判断矽卡岩的氧化还原性和钨矿床的品位及规模的依据,并具有成为W、Mo和Sn等矿床的找矿勘查指示矿物的潜力。     

Calibration of Infrared Absorption Coefficients for Structural Hydroxyl in Garnet by a Combined Study of Isotope Ratio Spectrometry and Vibrational Spectroscopy

An accurate determination of water content in garnet is critical to quantify the transport of water to the deep mantle by the subducted oceanic crust beyond the breakdown of hydrous phases. Fourier transform infrared spectroscopy (FTIR) is the most widely used approach to determine the species and contents of water in garnet. Accurate quantification of OH in garnet requires independent calibration using an external method, as OH absorbance is mineral and composition specific. To obtain the infrared absorption coefficients of structural hydroxyl in garnet, a combined study of spectrometric analyses by FTIR and a method combining a thermal conversion elemental analyser with isotope ratio mass spectrometry (TC/EA-MS) was carried out for fourteen gem-quality natural garnet crystals with variable compositions. The obtained molar absorption coefficients were 9322 ± 338 and 240 ± 26 l mol⁻¹ cm⁻² for grossular- and spessartine-rich garnet and pyrope-almandine garnet, respectively. These results are within the range of previous studies. A new molar absorption coefficient of 689 ± 177 l mol⁻¹ cm⁻² was obtained for pyrope-spessartine garnet. The large variation in the absorption coefficient indicates it is controlled by both garnet composition and OH-absorption bands. The obtained absorption coefficients are only appropriate for certain types of eclogitic garnet, and more studies should be carried out on eclogitic garnets.     

Concentrations and contamination trends of heavy metals in the sediment cores of Taihu Lake,East China,and their relationship with historical eutrophication

To assess the contamination trends and potential bio-availability of sediment-bound heavy metals, concentrations of heavy metals in acid-leaching fraction and in bulk sediments from the two typical bays (the Meiliang Bay and Xuhu Bay) of the Taihu Lake, East China, were studied. Pb and Zn showed elevated concentrations in the sediments from both areas, although sedimentation history and degree of pollution are different between the two bays. In the Meiliang Bay, both Pb and Zn pollutions started in the late 1970’s, the same time as the beginning of eutrophication of the lake, while the in the Xuhu Bay the metal contamination started since recent 10 years. The concentrations of acid-leachable Pb in the sediments from the Meiliang Bay are correlated with the historical eutrophication process. Before the eutrophication and heavy metal pollution, the chemical properties of the lake sediments were the same as the source compositions of the Xiashu loess. Both Pb and Zn in the sediments mainly occur in leachable forms by nitric or hydrochloric acid, whilst most of Cu is in residual fraction. The results indicate that both Pb and Zn may have higher mobility and bioavailability in water and biology than Cu.     

钻石颜色分级条件浅析

颜色是钻石4C评估中的一个重要指标,也是决定钻石档次和价格的一个重要依据。作者结合实践体会对颜色分级条件进行了分析,并提出了注意要点。