镉—5—Br—PADAP—溴化十六烷基三甲基铵—十八醇聚氧乙烯(20)醚显色体系的研究及应用

本文研究了镉-5-Br-PADAP-溴化十六烷基三甲基铵-peregalo显色体系的光谱特征,显色条件,络合物的组成、干扰及其消除。实验证明该法灵敏度高,ε=1.3×10~5l·mol~(-1)·cm~(-1)。选择性较好,显色酸度范围较宽pH=8.0-9.5,络合物最大吸收波长为560nm,镉在0-10μg/25ml的含量范围内服从比尔定律。经标准水样、工业废水及生活用水验证,不经分离可测定水中PPb级的微量镉。     

Predicting TBM penetration rate in hard rock condition: A comparative study among six XGB-based metaheuristic techniques

A reliable and accurate prediction of the tunnel boring machine(TBM) performance can assist in minimizing the relevant risks of high capital costs and in scheduling tunneling projects.This research aims to develop six hybrid models of extreme gradient boosting(XGB) which are optimized by gray wolf optimization(GWO), particle swarm optimization(PSO), social spider optimization(SSO), sine cosine algorithm(SCA), multi verse optimization(MVO) and moth flame optimization(MFO), for estimation of the TBM penetration rate(PR).To do this, a comprehensive database with 1286 data samples was established where seven parameters including the rock quality designation, the rock mass rating, Brazilian tensile strength(BTS), rock mass weathering, the uniaxial compressive strength(UCS), revolution per minute and trust force per cutter(TFC), were set as inputs and TBM PR was selected as model output.Together with the mentioned six hybrid models, four single models i.e., artificial neural network, random forest regression, XGB and support vector regression were also built to estimate TBM PR for comparison purposes.These models were designed conducting several parametric studies on their most important parameters and then, their performance capacities were assessed through the use of root mean square error, coefficient of determination, mean absolute percentage error, and a10-index.Results of this study confirmed that the best predictive model of PR goes to the PSO-XGB technique with system error of(0.1453, and 0.1325), R~2 of(0.951, and 0.951), mean absolute percentage error(4.0689, and 3.8115), and a10-index of(0.9348, and 0.9496) in training and testing phases, respectively.The developed hybrid PSO-XGB can be introduced as an accurate, powerful and applicable technique in the field of TBM performance prediction.By conducting sensitivity analysis, it was found that UCS, BTS and TFC have the deepest impacts on the TBM PR.     

胶莱盆地蛇窝泊地区白垩纪林寺山组沉积时代与物源特征:来自碎屑锆石U-Pb测年与稀土元素组成的新证据

林寺山组是胶莱盆地莱阳群底部重要的地层单元之一.准确限定其沉积时代与物源性质对于客观重建华北陆块东部晚中生代大地构造格局以及周缘造山带/前寒武纪变质基底晚中生代的折返过程具有重要的制约作用.以莱阳盆地蛇窝泊地区莱阳群林寺山组细砾岩为研究对象,对其开展了野外地质调查、岩相学观察、锆石U-Pb测年与锆石稀土元素分析等综合研...     

华北克拉通东缘金岭杂岩体岩浆源区及构造背景:来自岩相学、岩石地球化学及年代学的证据

金岭杂岩体由细粒黑云角闪闪长岩、中细粒黑云角闪闪长岩、中细粒黑云角闪二长闪长岩和细粒角闪二长闪长岩组成,是鲁西地区典型矽卡岩型富铁矿(金岭铁矿)控矿岩体。本次研究对细粒黑云角闪闪长岩和细粒角闪二长闪长岩进行了锆石LA‐ICP‐MS U‐Pb定年,其结果分别为129.2±3.2 Ma和132.8±1.2 Ma,表明该杂岩体的侵位时代为早白垩世。样品SiO2、K2O和Na2O含量分别介于54.17%~63.73%、1.92%~4.76%和3.10%~5.41%之间,K2O/Na2O为0.58~0.94,A/CNK为0.60~0.93,具有轻稀土富集,重稀土亏损的右倾型稀土配分模式,轻、重稀土分馏程度中等((La/Yb)N=9.94~23.49),Eu异常不明显(δEu=0.84~1.10),具中—弱负Ce异常(δCe=0.56~0.92)。样品以富集大离子亲石元素(Ba、K、U、Pb等)、亏损高场强元素(Nb、Ta、Ti)以及高Sr/Y为特征。金岭杂岩体为燕山晚期岩浆活动产物,属准铝质高钾钙碱性系列,岩浆主要来源于富集岩石圈地幔的部分熔融,并在岩浆上升侵位的过程中有地壳物质的同化混染。燕山晚期华北克拉通在古太平洋板块俯冲后后撤引起的板内伸展环境下,增厚陆壳减薄阶段,岩浆上侵就位形成金岭杂岩体。     

库车坳陷侏罗系煤成气动力学模拟研究

应用黄金管—高压釜封闭体系热模拟实验与GC、GC-IRMS分析技术,结合KINETICS专用软件,对库车坳陷侏罗系煤成气进行了动力学模拟研究。库车坳陷侏罗系煤具有高的产气性,在高演化阶段主要产甲烷气;侏罗系煤热解气甲烷碳同位素为-36‰～-25‰,乙烷碳同位素为-28‰～-16‰;甲烷、C2-C5气态烃的生成活化能分别为(47～64k)calm/ol、(55～72k)calm/ol,频率因子各为5.265×1013s-1、5.388×1018s-1。在此基础上,进一步探讨了克拉2气田天然气的成因。研究认为,克拉2气田天然气属阶段捕获的煤成气,主要聚集了5～1Ma时期的天然气,其成熟度Ro分布范围为1.3%～2.5%。     

Late Triassic granites from the northwestern margin of the Tibetan Plateau,the Dahongliutan example: petrogenesis and tectonic implications for the evolution of the Kangxiwa Palaeo-Tethys

The Dahongliutan granitic pluton consists of two-mica granites and is located in the eastern part of the Western Kunlun Orogen, northwestern Tibetan Plateau. Zircon separates from the pluton yield a SIMS U–Pb age of 217.5 ± 2.8 Ma. Rocks from the pluton contain relatively high and uniform SiO₂ (72.32–73.48 wt%) and total alkalis (Na₂O + K₂O = 8.07–8.67 wt%) and are peraluminous and high-K calc-alkaline to shoshonitic in composition. The Dahongliutan granites are relatively depleted in the high-field-strength elements and the heavy rare earth elements (HREEs) and have relatively high Rb, and low Ba and Sr concentrations. They contain low total rare earth element (REE) concentrations. The light REEs are strongly enriched relative to the HREEs, with (La/Yb)_N values of 28.56–37.01. The ε_Nd(t) values range from ?10.6 to ?8.8, and (⁸⁷Sr/⁸⁶Sr)_i = 0.7142–0.7210. Zircons from the pluton yield ε_Hf(t) values of ?13.8 to ?1.6, and δ¹⁸O = 10.5–11.6‰. Petrographic and geochemical features of the pluton indicate that the granites are S-type and were derived from parting melting of a mixture of metasedimentary and minor metaigneous sources in the middle–lower crust. Magmatic differentiation was dominated by the fractional crystallization of plagioclase, K-feldspar, muscovite, biotite, and accessory monazite, allanite, and Fe–Ti oxides. Regional granitoids were emplaced in the Early-to-Middle Triassic. Other younger granitoids, with ages of 240–200 Ma, are mostly I-type in character and were likely derived from multiple types of source rock, suggesting the source was heterogeneous Triassic crust. Such a scenario is consistent with their formation in a post-collisional setting. Our new data, combined with other geological evidence, suggest that the collision between the Tianshuihai and southern Kunlun terranes occurred between ca. 250 and 240 Ma, resulting in the closure of the Palaeo-Tethys. Post-collisional tectono-magmatic events may have occurred between 240 and 200 Ma.     

Mesozoic tectonic evolution of the Southeast China Block: New insights from basin analysis

In order to better understand the Mesozoic tectonic evolution of Southeast China Block (SECB in short), this paper describes geological features of Mesozoic basins that are widely distributed in the SECB. The analyzed data are derived from a regional geological investigation on various Mesozoic basins and a recently compiled 1:1,500,000 geological map of Mesozoic–Cenozoic basins. Two types of basin are distinguished according to their tectonic settings, namely, the post-orogenic basin (Type I) and the intracontinental extensional basin (Type II); the latter includes the graben and the half-graben or faulted-depression basins. Our studies suggest that the formation of these basins connects with the evolution of geotectonics of the SECB. The post-orogenic basin (Type I) was formed in areas from the piedmont to the intraland during the interval from Late Triassic to Early Jurassic; and the formation of the intracontinental extensional basin (Type II) connects with an intracontinental crustal thinning setting in the Late Mesozoic. The graben basin was generated during the Middle Jurassic and is associated with a bimodal volcanic eruption; and the half-graben or faulted-depression basin, filled mainly by the rhyolite, tuff and sedimentary rocks during Early Cretaceous, is occupied by the Late Cretaceous–Paleogene red-colored terrestrial clastic rocks. We noticed that the modern outcrops of numerous granites and basins occur in a similar level, and the Mesozoic granitic bodies contact with the adjacent basins by large normal faults, suggesting that the modern landforms between granites and basins were yielded by the late crustal movement. The modern basin and range framework was settled down in the Cretaceous. Abundant sedimentary structures are found in the various basins, from that the deposited environments and paleo-currents are concluded; during the Late Triassic–Early Jurassic time, the source areas were situated to the north and northeast sides of the outcrop region. In this paper, we present the study results on one geological and geographical separating unit and two separating fault zones. The Wuyi orogenic belt is a Late Mesozoic paleo-geographically separating unit, the Ganjiang fault zone behaves as the western boundary of Early Cretaceous volcanic rocks, and the Zhenghe–Dapu fault zone separates the SE-China Coastal Late Mesozoic volcanic-sedimentary basins and the Wuyi orogenic belt. Finally, we discuss the geodynamic mechanisms forming various basins, proposing a three-stage model of the Mesozoic sedimentary evolution.     

南海上层海洋热结构的年循环与半年循环

根据南海季风试验(SCSMEX)期间南海内区的三个ATLAS(Autonomous Temperature Line Acquisition System)锚碇浮标资料(1998年4月～1999年4月),采用谐波分析方法对南海上层海洋水温年循环、半年循环加以分离,发现无论在年循环还是在半年循环尺度上,18°N附近SCS1站与13°N附近SCS3站的水温变化次表层与表层呈反位相;15°20′N附近SCS2站水温变化基本上次表层与表层同位相.这说明不同区域上层海洋热变化受不同的正压与斜压模态控制.其次,SCS2、SCS3两点水温年循环振幅均在次表层达到极值;而SCS1在表层达到极大值,在100 m深度达到次极大值.3个站位水温半年循环振幅极值均出现在次表层内,这说明该层内的水温半年循环在温度变化趋势中所占的权重比在表层的权重大.     

Optimal Doppler-aided smoothing strategy for GNSS navigation

GPS Solutions - Carrier-phase-smoothed code (CPSC), i.e., smoothing of the code using carrier phases, has widely been used to reduce the code noise in GNSS applications. However, the efficiency of...     

固体潮潮汐因子的特征频谱及其应用

本文应用非线性谱分析中的最大熵谱分析方法（ＭＥＭ）、和一般线性功率谱的分析方法，对固体潮潮汐因子的时间序列进行了综合研究，指出固体潮潮汐因子的时间序列中普遍存在明显的半月左右周期的特征频谱；将其应用于地震前兆的分析与探索，对固体潮潮汐因子特征频谱中的前兆变化特征进行了解释，得出结论：半月左右周期的频率域，是固体潮观测中前兆响应的一个重要主频域。