青海格尔木哈希牙地区中基性岩墙群地球化学特征与LA-ICP-MS锆石U-Pb年龄

位于东昆仑造山带上的东昆北哈希牙地区发育中基性岩墙群。其岩性主要为辉绿岩、闪斜煌斑岩和闪长玢岩,地球化学数据显示其具有高钾钙碱性玄武岩系列特征。轻、重稀土元素存在较高程度分馏,LREE/HREE值为4.72~8.66,平均值为6.57。δEu值介于0.81~0.98之间,平均值为0.91,显示出微弱的负Eu异常,表明斜长石的分离结晶作用不明显,富集Rb、Ba、Pb、K等大离子亲石元素,贫高场强元素Ta、Nb、Zr、Hf等地球化学特征,主体显示板内玄武岩特征,但有来自俯冲带的部分信息。采用LA-ICP-MS技术对锆石进行了U-Th-Pb同位素测定,结果显示锆石年龄较为分散,其中8颗岩浆锆石给出的206Pb/238U年龄加权平均值为411.5±7.5Ma,代表了格尔木哈希牙地区辉绿岩墙的结晶年龄,反映东昆北地块于晚志留世—早泥盆世已由地体碰撞的挤压状态转为碰撞后伸展状态,标志着该地区加里东期构造旋回的结束。     

Microbiological degradation of phenol using two co-aggregating bacterial strains

Phenol biodegradation in an aerobic batch reactor was investigated using mixed two co-aggregating strains (Flavobacterium sp. and Acetobacter sp.). Response surface methodology by the Box–Behnken model was used to evaluate the optimal cell growth and phenol degradation conditions. The optimum temperature, pH value and inoculum size were found to be 33 °C, 6.06 and 13 %, respectively. In the conditions, phenol degradation rate and biomass were predicted to be 96.97 % and 410.78 mg/L within the range examined, respectively. Less toxic acetaldehyde, ethanol and acetic ether were identified as main intermediate products from the degraded samples using GC–MS. Substrate inhibition was calculated from experimental biomass growth and phenol degradation parameters using the Haldane equation. Kinetic parameters derived from nonlinear regression with correlation factors (R ²) were 0.9682 for phenol degradation and 0.9594 for biomass growth, respectively. The phenol concentration to avoid substrate inhibition was 278.17 mg/L.     

中国萤石矿床分类

通过对中国萤石矿床的成矿作用研究,综合考虑萤石矿床的成因类型和工业类型,将中国萤石矿床划分为沉积改造型、热液充填型和伴生型3种矿床类型。在全面分析萤石矿典型矿床的成矿条件、控矿因素和成矿作用的基础上,总结成矿要素,以相同或相似的二级成矿必要要素组合确定沉积改造型、热液充填型萤石矿床的亚类型,沉积改造型进一步划分出2个矿床式,热液充填型划分出5个矿床式,伴生型按伴生主矿种划分出4个矿床式。文章分析了每一个矿床式的成矿地质背景,成矿条件、矿床特征、控矿因素和成矿作用,总结了每一个矿床式的二级成矿必要要素。     

西藏嘎拉勒金铜矿床40Ar/39Ar同位素年龄及地质意义

西藏嘎拉勒矽卡岩型金(铜)矿床为近几年由西藏自治区第二地质大队发现的具有一定规模和潜力的矿床。本文以嘎拉勒金铜矿床中矽卡岩中金云母为研究对象,通过40Ar/39Ar同位素定年的方法,精确厘定了嘎拉勒矽卡岩型金铜矿床的成矿时代。金云母结晶在石榴子石和透辉石、黄铁矿和黄铜矿形成之间,并与石榴子石、针状透闪石和放射状阳起石密切共生。测试结果表明,嘎拉勒矿区金云母的40Ar/39Ar坪年龄为85.41±0.64 Ma,与相应的等时线年龄85.9±2.4 Ma一致,推测其成矿作用可能与拉萨地块和羌塘地块碰撞后在拉萨地块北侧发生岩石圈拆沉引起地幔物质上涌而诱发的岩浆活动有关。     

南岭西段加里东期苗儿山岩体锆石SHRIMPU-Pb年龄、地球化学特征及其构造意义

苗儿山岩体位于南岭西段,主体为加里东期花岗岩,少量印支期和早燕山期花岗岩。加里东期花岗岩具块状构造,由早期黑云母花岗闪长岩、中期斑状黑云母二长花岗岩和晚期细粒黑(二)云母二长花岗岩组成,以斑状黑云母二长花岗岩为主。对中期斑状黑云母二长花岗岩和晚期细粒二云母二长花岗岩各进行了1个样品的锆石SHRIMP U-Pb年龄测试,分别得到428.5±3.8 Ma、409±4 Ma的年龄值,反映出早志留世末、志留纪末-泥盆纪初2期岩浆事件。中期主体花岗岩具有富硅(SiO2=70.09%~76.59%)、中铝(Al2O3=12.71%~14.72%)、高钾(K2O=4.48%~5.73%)、中碱(Na2O+K2O=7.24%~7.91%)、高ASI(平均1.15)的特点,总体属高钾钙碱性系列过铝质花岗岩类。主体花岗岩微量元素中Ba、Nb、Sr、P、Ti表现为明显亏损,Rb、(Th+U+K)、(La+Ce)、Nd、(Zr+Hf+Sm)、(Y+Yb+Lu)等则相对富集,稀土总量中等(179.8×10-6~270.6×10-6),轻稀土富集[(La/Yb)N=5.07~14.33],具明显的负Eu异常(δEu=0.15~0.46)。岩体具有较高的ISr值(0.70660~0.72082)和较低的εNd(t)值(-8.29~-7.94),两阶段Nd模式年龄(t2DM)为1.81~1.84 Ga。C/MF-A/MF图解显示源岩为变质泥质岩和碎屑岩。上述地球化学特征表明花岗岩为S型花岗岩,源岩主要为中、上地壳岩石。花岗岩氧化物和微量元素构造环境判别图解指示岩体形成于后碰撞构造环境。基于岩石成因、构造环境判别以及区域构造演化过程,推断加里东期苗儿山花岗岩的具体形成机制为:在陆内强挤压之后挤压应力相对松弛、压力降低的后碰撞构造环境下,因地壳增厚而升温的中、上地壳岩石减压熔融并向上侵位。结合区域资料分析,苗儿山地区在奥陶纪末-志留纪初北流运动和志留纪后期的广西运动中均产生过强烈的陆内挤压和地壳增厚。     

斑岩铜矿成矿构造背景研究进展

斑岩铜矿是指与具斑状结构的中酸性侵入岩伴生,蚀变与矿化受流体、构造控制且分带明显,矿石以细脉浸染状为主,低品位、大储量的铜矿床,是最重要的铜矿床类型。大地构造背景对斑岩铜矿的形成具有重要意义,经典的斑岩铜矿主要产于岛弧、陆缘弧环境。然而,近年来国内矿床学家发现,国内形成于大陆环境的斑岩铜矿与大洋板块俯冲、板块消减作用无关,斑岩铜矿还可产于碰撞造山带,甚至是在陆内环境。相比之下,不同构造背景下形成的斑岩铜矿床含矿岩浆、成矿物质来源、矿床成因等方面存在一定差异与共性。综述了目前斑岩铜矿研究内容中的关于构造背景的一些重要观点和几个重要进展,对比了不同构造背景下形成的斑岩铜矿床的含矿岩浆、蚀变矿化、成矿流体等方面的共性与差异,以期对斑岩型矿床的成因与找矿提供一定的线索。     

时空约束下的地铁可达性研究：以北京为例

以北京市为例,基于340个站点的时刻表构建地铁组织网络,采用网络分析法和累积机会法,对比在“工作日”和“双休日”“高峰期”和“非高峰期”等时空约束下的可达性动态。研究发现：① 由于起始地空间区位特征及沿线土地利用功能结构的多样性,不同线路的时刻组织模式各异。② 基于运营组织网络的地铁可达性存在时刻上的动态变化,一日内早晚高峰可达性最优,双休日可达性略低于平时。③ 基于运营组织网络的地铁可达性与基于设施网络的可达性存在明显空间差异,且距市中心15~20 km处的站点工作日和双休日的可达性差异最大,与地铁网络结构特征有关。综上,基于时刻组织时空约束下的可达性分析有利于了解地铁系统的精细化管理,并有助于进一步剖析居民出行规律和城市空间结构。     

黄河流域煤炭富集区煤炭水足迹演变及驱动效应研究

煤炭与水资源相互影响和制约,如何评价煤炭耗水的演变趋势及其影响机制对煤炭和水资源进行协同管理具有重要意义。基于国际标准的煤炭水足迹测算模型,分析2000—2017年黄河流域煤炭富集区——晋陕蒙煤炭水足迹的时空演变趋势,构建煤炭水足迹压力指数评价区域煤炭和水资源的匹配关系,并运用LMDI模型定量分析煤炭水足迹的驱动效应。结论如下：① 煤炭水足迹总量在研究期内呈增长趋势,主要以原煤和火力发电水足迹为主,山西和内蒙古煤炭水足迹最高,陕西最低。② 研究区整体煤炭水足迹压力指数逐渐增大,由煤–水关系缓和型逐渐演变为煤–水关系制约型,从空间分异来看,山西最大,研究期内均属于煤–水紧张型,陕西次之,内蒙古最小,均由煤–水关系缓和型演变为煤–水关系制约型。③ 影响煤炭水足迹的主要驱动因素是经济效应和技术效应,前者对煤炭水足迹的影响逐渐增强,后者对煤炭水足迹压力的影响先增强后减弱,各驱动效应空间分异明显。研究结果可为煤炭富集区煤炭和水资源可持续利用提供决策参考,为黄河流域生态保护和高质量发展的资源管理提供决策支持。     

Relation between the “Double-Hump” Behavior in the Radio Band and the Broad-Line Luminosity for Blazars

The physics behind the spectral energy distribution (SED) of blazars remains open. We assembled 36 blazars to tackle the factors that control their SED. Now, many blazar spec- tra have the "double hump" feature in the radio and far-IR frequencies. For these a parameter, , is created to characterize the behavior of the SED. We found a significant correlation be- tween the broad-line luminosity (LBLR) and . Because LBLR is an indicator of the accreting power of the source in blazars, we derived a linear correlation, ∝ M˙1/3.18, which suggests that the SED of blazars may depend on the accretion rate, like that of BL Lac objects. We also found a significant correlation between ■ and for a sample of 11 blazars (out of one of 36) with available black hole masses. This implies the Eddington accretion ratio may influence the shape of the SED of blazars.     

Using modified state surface approach to select parameter values in the Barcelona basic model

The Barcelona basic model (BBM) successfully explained many key features of unsaturated soils and received extensive acceptance. It is also one of the few elastoplastic constitutive models for unsaturated soils that have been implemented within finite element codes and applied to the analysis of real boundary value problems. The BBM was proposed in incremental forms according to theories of soil plasticity in which individual aspects of the isotropic virgin behavior are controlled by multiple parameters, whereas at the same time, a single parameter controls more than one aspect of soil behavior. Although a variety of methods have been recently developed for calibrating model parameters for elastoplastic soil models, at present, there are no well‐established, simple, and objective methods for selecting parameter values in the BBM from laboratory tests. This has been one of the major obstacles to the dissemination of this constitutive model beyond the research context. This article presents an optimization approach especially developed for simple and objective identification of material parameters in the BBM. This is achieved by combining a modified state surface approach, recently proposed to model the elastoplastic behavior of unsaturated soils under isotropic stress conditions, with the Newton or quasi‐Newton method to simultaneously determine the five parameters governing isotropic virgin behavior in the BBM. The comparison between results using the proposed method and an existing method for the same laboratory tests was discussed from which the simplicity and objectivity of the proposed method were evaluated. Copyright © 2012 John Wiley & Sons, Ltd.