溴素的有机化学──I．2，4，6－三溴苯甲酸溴代和非溴代芳酯的合成

用ｍ－氨基苯甲酸作原料，经溴代、重氮化、还原脱氨、酰氯化和酯化反应等步骤，合成了六种新型的三溴苯甲酸的溴代和非溴代芳酯，即；双（２，４，６－三溴苯甲酸）－２＇，３＇，５＇，６＇－四溴－１＇，４＇－苯二酯，２，４，６－三溴苯甲酸－２＇，３＇，４＇，５＇，６＇－五溴苯酯，２，４，６－三溴苯甲酸－２＇，４＇，６＇－三溴苯酯，２，４，６－三溴苯甲酸－４＇－溴苯酯，２，４，６－三溴苯甲酸－４＇－甲基苯酯和２，４，６－三溴苯甲酸苯酯．通过对产物中碳、氢、溴元素的定量分析以及红外吸收光谱和氢核磁共振谱的研究，验证了合成产物的结构。     

灵山岛浅海岩礁区底栖生物的群落特点

浅海岩礁环境系高生产力区,在中、高纬度海域中,由大型海藻和大叶藻(Zosteramarina)所构成的初级生产力常为浮游植物初级生产力的数倍(Miller et al.,1971)。同时,此种环境又是以大型藻类或有机碎屑为食物的珍贵海产品鲍鱼(Haliotis)、刺参(Stichopus)、海胆(Strongylocentrotus)等的栖息场所和采捕作业区;还是一些优质鱼类星鳗( Astroconger myriaster)、鲈(Lateolobrax japonicus)等的藏匿场所和游钓渔业的渔场;重要经济藻类石花菜(Gelidium)等也在此环境中定着、生长。所以,浅海岩礁的资源开发前景很好。为了促进上述珍贵海产品的增、养殖生产和发展游钓渔业,有必要对浅海岩礁底栖生物群落的结构、功能进行系统研究,以便为岩礁区的资源开发和海岸带环境保护提供科学依据。为此,中科院海洋研究所在1987年初步调查的基础上,1992年以灵山岛为点,对水下岩礁环境和生物群落进行了系统的调查。本文主要分析浅海岩礁底栖生物的群落特点。     

The algorithms of chlorophyll-a concentration for CMODIS

The algorithms of extracting chlorophyll-a(Chl-a) concentration have been established for Chinese moderate resolution imaging spectrometer(CMODIS) mounted on Shenzhou-3 spaceship launched on 25 March 2002.The CMODIS is an ocean color sensor with 30 visible channels and 4 infrared channels,much different from other ocean color satellites and needs new algorithms to process data.Three models of Chl-a concentration were established based on Chl-a data retrieved from sea-viewing wide field-of-view sensor(SeaWiFS),with the average relative errors of 26.6%,24%.0% and 33.5%,respectively.This practical and economic approach can be used for developing the algorithms of Chinese ocean color and temperature sensor(COCTS) on the satellite Haiyang-1 to derive the Chl-a concentration concentration distribution.The applicability of the algorithms was analyzed using some in situ measurements.Suspended sediment is the main factor influencing the accuracy of the spectral ratio algorithms of Chl-a concentration.The algorithms are suitable to using in the regions where suspended sediment concentrations(SSC) are less than 5 g/m3 under the condition of relative error of Chl-a concentration retrieval within 35%.High concentration of suspended sediment leads to the overestimate remote sensing retrieval of concentration of Chl-a,while low-middle SSCs lead to the low Chl-a concentration values using the spectral ratio algorithms.Since the accuracy of Chl-a concentration by the spectral ratio algorithms is limited to waters of Case 2,it is necessary to develop semi-analytical models to improve the performance of satellite ocean color remote sensing in turbid coastal waters.     

环台湾岛海域半日潮波特征的三维模拟

用1997版POM海洋模式,首次应用于环台湾岛海域的潮波数值研究.得到该海域的半日潮波主要为23°N以南西太平洋传来的胁振潮.影响台湾海峡的半日潮波分别由海峡南北口传入的两支潮波,且北支强于南支.福建沿岸湄州湾-兴化湾为最强潮区,其M₂分潮最大振幅可达240cm.最强潮流区位于澎湖水道,M₂分潮最大潮流达196cm/s.环台湾岛海域潮波潮流水平结构上除海峡北部原有一个圆流点外,还发现另外存在4个新的圆流点.潮流垂直结构上主要为右偏,接近底层处为左偏.     

厦门港真刺唇角水蚤的生长率

本文以实验室培养为主,结合自然种群调查,观测厦门港真刺唇角水蚤各发育阶段体长、体重的增长状况,并研究了其生长率与温度、发育期的关系。     

海州湾淤泥质海滩剖面堆积过程的计算模式

分别于1986年12月和1985年3月1日—1987年3月1日在海州湾进行了波浪和含沙量观测，运用所获资料以及本区长期水文、地形资料，采用流体力学、沉积学和泥沙运动力学相结合的研究方法，建立了海州湾淤泥质海滩剖面堆积过程的二维计算模式。结果表明，在堆积型淤泥质海滩，由于浮泥的经常性存在，使波浪急剧衰减，其对岸滩的作用甚为微弱，潮流成为塑造淤泥质海滩的主要动力，岸滩在淤涨过程中，在平均高潮位厂沿和平均低潮位附近出现两个凸点，上一个凸点外推速率大于下一个凸点，潮下带变化缓慢。     

Contributions to atmospheric methane by natural seepages on the U.K. continental shelf [Mar. Geol. 137 (1997) 165–189]

Natural gas seepages occur on the United Kingdom's continental shelf and although published reports suggest that they are very rare, the petroleum industry has identified, but not publicly reported, many more. There is also very little data on the flux of gas from seabed seepages, and even less on the contribution of seepages to atmospheric concentrations of gases such as methane.

Potential gas source rocks include Quaternary and Tertiary peats as well as petroliferous source rocks such as the Carboniferous Coal Measures and the Upper Jurassic Kimmeridge Clays. There are also other organic-rich sediments which are potential source rocks. Together these cover a considerable part of the U.K. continental shelf.

Analogue seismic reflection (pinger) profiles acquired during the British Geological Survey's regional mapping programme have been reviewed to identify water column targets including fish and plumes of gas bubbles. The ability to distinguish targets is critical to an assessment of the distribution of gas seepages. Both theoretical predictions of target identity and the habits of shoaling fish have been investigated in order to identify a method of distinction.

Data from seabed seepages and measurements of seepage rates have been used to establish likely ranges of gas flux rates and the sizes of gas bubbles. The likelihood that a rising bubble will survive and escape into the atmosphere is determined primarily by bubble size and water depth; methane, the principal constituent of seepage gas, is relatively unreactive and sparingly soluble.

The studies have enabled a new estimate of the distribution of gas seepages on the U.K. continental shelf, and of the contribution to atmospheric methane levels. The results suggest that natural gas seepages are significantly more important as a source of methane than had hitherto been established. It is estimated that between 120,000 and 3.5 mtonnes of methane per year come from a continental shelf area of about 600,000 km². This represents between 2% and 40% of the total United Kingdom methane emission. It is suggested that similar contributions arise from other continental shelf areas worldwide, and that geological sources of atmospheric methane are more significant than is generally acknowledged.     

厦门港岩相潮间带多毛类的生态

本文根据１９８７年２、５、８、１１月调查资料，研究了厦门港岩相潮间带多毛类的种类组成、种类与数量的垂直分布、季节变化，并与大亚湾多毛类生态进行比较。结果表明，调查区域有多毛类４７种。平均栖息密度６０个／ｍ＾２，平均生物量１．７８ｇ／ｍ＾２，潮汐作用影响多毛类的种数、密度、生物量的垂直分布。多毛类数量的季节变化不甚明显，但冬季的栖息密度和春季的生物量较高。     

黄海北部降水中氟的浓度变化

1988～1992年连续采集了黄海西北部的大气降水,分析样品中的氟而得到的80多个数据显示出大气降水中氟的平均浓度低于中国北方主要河流的氟平均浓度。在冬季,氟的浓度较其他季节高,这可能和降雨量减少以及人为因素等密切相关。目前还难以估算出人为因素对氟在降水中化学行为的影响程度,但数据显示出人口密集地区降水中氟的浓度明显高于人口稀疏的自然地带。     

科氏力对河口分汊的影响

以长江口、黄河口、珠江口、闽江口等几个分汊河口为例,分析了科氏力在河口分汊中的作用。结果表明,涨落潮流路分歧主要通过形成涨落潮冲刷槽和中央缓流区浅滩而逐渐使河口产生分汊;水面横比降则以横向环流和横向切滩两种形式,或堆积或冲刷,导致河口分汊。