Considerations for conducting incubations to study the mechanisms of As release in reducing groundwater aquifers

Microbial Fe reduction is widely believed to be the primary mechanism of As release from aquifer sands in Bangladesh, but alternative explanations have been proposed. Long-term incubation studies using natural aquifer material are one way to address such divergent views. This study addresses two issues related to this approach: (1) the need for suitable abiotic controls and (2) the spatial variability of the composition of aquifer sands. Four sterilization techniques were examined using orange-colored Pleistocene sediment from Bangladesh and artificial groundwater over 8 months. Acetate (10 mM) was added to sacrificial vials before sterilization using either (1) 25 kGy of gamma irradiation, (2) three 1-h autoclave cycles, (3) a single addition of an antibiotic mixture at 1× or (4) 10× the typical dose, and (5) a 10 mM addition of azide. The effectiveness of sterilization was evaluated using two indicators of microbial Fe reduction, changes in diffuse spectral reflectance and leachable Fe(II)/Fe ratios, as well as changes in P-extractable As concentrations in the solid phase. A low dose of antibiotics was ineffective after 70 days, whereas autoclaving significantly altered groundwater composition. Gamma irradiation, a high dose of antibiotics, and azide were effective for the duration of the experiment.     

Defect properties of albite

Knowledge of the defect properties of Lunar and Mercurian minerals has recently become important, with the advent of models which attempt to explain the formation of the thin exosphere of these celestial bodies. Here, we have calculated the formation energies of sodium and oxygen vacancies in the mineral albite (NaAlSi₃O₈), as well as the Schottky defect energy for the removal of a Na₂O unit. We have employed both the supercell and Mott–Littleton approaches, using Kohn–Sham density functional theory and classical interatomic potential methods. As well as reporting the defect energies and structures, we comment upon the relative merits of the methods used.     

四川大陆槽稀土矿床碳酸岩-英碱正长岩锆石U-Pb年代学和Hf同位素性质及其地质意义

川西冕宁-德昌稀土成矿带是中国最重要的稀土成矿带之一,所有稀土矿床均与碳酸岩-正长岩杂岩体有关.前人研究表明,牦牛坪、木落寨和里庄碳酸岩-碱性杂岩体成岩年龄与其相应矿床的成矿年龄基本一致,而大陆槽正长岩年龄与REE矿床的成矿年龄相差甚远.本文对大陆槽碳酸岩、英碱正长岩进行了SHRIMP U-Pb锆石年代学和LA-MC-ICPMS锆石Hf同位素原位测量,它们的形成年龄分别为12.99±0.94Ma、14.53±0.31Ma,表明两者是同时形成的,且与其成矿年龄基本一致.碳酸岩和正长岩的εHf(t)值、Hf模式年龄与它们的εNd(t)值、Nd模式年龄所展现出来的特征一致,说明在其形成过程中有地壳物质的加入.     

海拉尔盆地贝尔凹陷兴安岭群储层粘土矿物组成及成因研究

油田注水开发是保持地层能量,提高采收率的有效手段.海拉尔地区由于粘土矿物含量高,在开发过程中储层遇水易泥化、坍塌,严重影响油气的有效开采.通过X射线衍射、偏光显微镜观察和扫描电镜分析,确定了海拉尔盆地贝16断块兴安岭群储层自上而下存在三种粘土矿物组合:蒙脱石 高岭石 (绿泥石)→高岭石 伊/蒙间层 伊利石 (绿泥石)→伊利石 绿泥石 绿/蒙间层 伊/蒙间层.粘土总量在9.1%～69.1%之间,由地层浅部到深部呈现由高到低的变化规律.详细研究了水敏性极强的钠蒙脱石及其间层矿物,认为凝灰物质的水解蚀变以及长石和中、酸性岩屑在成岩过程中的次生变化是造成海拉尔地区粘土含量高的主要因素.     

烟台港和邻近锚地及其入境船舶压舱水中的浮游植物

本文根据2003年5月到2004年4月间烟台港和邻近锚地水域及其船舶压舱水中的浮游植物调查资料,对浮游植物的群落结构和压舱水对其影响进行了初步研究。结果表明,烟台港和临近锚地的浮游植物群落主要由温带沿岸性物种组成,以硅藻为主,还有少量甲藻和金藻;对比船舶压舱水中浮游植物群落发现:压舱水中浮游植物群落和本地群落的结构有很大差异,有害物种在压舱水中出现的频率较高。     

3厘米扫描成像微波辐射计在海洋感感中的初次应用

所有物体都不断地发出电磁辐射,在微波谱段内黑体的辐射量B_bb可用瑞利—金斯公式表示:B_bb=2KT/λ2。     

南极冰退与深圳湾北岸海平面变化的地质记录

南极冰层的冰量为２４．５×１０６ｋｍ３，占地球总冰量的９０％以上，南极冰川进退控制着全球海平面变化和气候波动。酉部南极乔治王岛第四纪冰碛与湖积剖面记录了近１２０００ａ来南极曾于距今１１０００ａ，９０００ａ和６１００ａ出现过３次快速的冰消过程，近６０００ａ来是一小幅度冷暖交替的气候波动过程。深圳湾北岸潮间带堆积是在近６０００ａ以来发育的，堆积物的环境记录表明，海平面呈周期性升降变化，波动周期平均为６７０ａ，低海面时期发生于距今５５００—４９００ａ，３９００—３６００ａ，２４００—２２００ａ和１３００—１２００ａ。相邻低海面间则是海面上升时期，每一升降周期的海平面变化幅度为８０ｃｍ左右，近１００ａ的现代增温，海平面处于上升阶段，上升速率为２—３ｍｍ·ａ（－１）。     

Studies on the distribution and antibacterial properties of Streptomyces in the intertidal zone of Southern Fujian

The oceans have rich resources of microbes. In recent years, searching for antibiotic of new structure and special biological activity from marine microbes has received great attention. This paper reports the results of the studies on the distribution and the antibacterial properties of Streptomyces in the intertidal zone of Southern Fujian. These studies have important significance to further investigate     

厦门市海域功能区划实践中若干问题的探讨

1997年，厦门市制定了中国第一部市级海洋功能区划，率先实行了海洋功能区划制度，几年来在科学指导海洋开发活动、建立良好的海洋开发和管理秩序、合理地利用海洋资源和调整海洋产业布局、实施海洋经济的可持续发展等方面取得了良好的效果。但是，海洋功能区划实施后，厦门市的海域使用仍然存在一些问题。中国范围内的市、县级海洋功能区划刚刚完成，都还处于起步实施阶段，对于功能区划的管理和实践中出现的问题进行总结，分析探讨其原因，