南极长城站地区现代环境地球化学特征

本文通过环境背景值、风化壳地球化学、对流层(大气气溶胶)地球化学和人为地球化学异常,初步探讨了南极长城站地区的现代环境地球化学特征。分析表明:环境要素固有的地球化学性质、区域环境条件和自然环境演变之间具有深刻的内在联系。     

U-Pb, Hf and O isotope evidence for two episodes of fluid-assisted zircon growth in marble-hosted eclogites from the Dabie orogen

A combined study of internal structure, U-Pb age, and Hf and O isotopes was carried out for metamorphic zircons from ultrahigh-pressure eclogite boudins enclosed in marbles from the Dabie orogen in China. CL imaging identifies two types of zircon that are metamorphically new growth and recrystallized domain, respectively. The metamorphic zircons have low Th and U contents with low Th/U ratios, yielding two groups of ²⁰⁶Pb/²³⁸U age at 245 ± 3 to 240 ± 2 Ma and 226 ± 4 to 223 ± 2 Ma, respectively. Anomalously high δ¹⁸O values were obtained for refractory minerals, with 9.9 to 21.4‰ for garnet and 16.9‰ for zircon. This indicates that eclogite protolith is sedimentary rocks capable of liberating aqueous fluid for zircon growth during continental subduction-zone metamorphism. Most of the zircons are characterized by very low ¹⁷⁶Lu/¹⁷⁷Hf ratios of 0.000001-0.000028, indicating their growth in association with garnet recrystallization. A few of them falling within the older age group have comparatively high ¹⁷⁶Lu/¹⁷⁷Hf ratios of 0.000192-0.000383, suggesting their growth prior to the formation of garnet in the late stage of subduction. The variations in the Lu/Hf ratios for zircons can thus be used to correlate with garnet growth during eclogite-facies metamorphism. In either case, the zircons have variable ε_Hf (t) values for individual samples, suggesting that their protolith is heterogeneous in Hf isotope composition with localized fluid availability in the bulk processes of orogenic cycle. Nevertheless, a positive correlation exists between ²⁰⁶Pb/²³⁸U ages and Lu-Hf isotope ratios for the metamorphically recrystallized zircons, suggesting that eclogite-facies metamorphism in the presence of fluid has the identical effect on zircon Lu-Hf and U-Th-Pb isotopic systems. We conclude that the zircons of the older group grew in the presence of fluid during the subduction prior to the onset of peak ultrahigh-pressure metamorphism, whereas the younger zircons grew in the presence of fluid released during the initial exhumation toward high-pressure eclogite-facies regime.     

Effect of some additives on synthesis of zeolite from coal fly ash

Hydrothermal conversion of fly ash into zeolites was conducted and the effects of the addition of sodium halide and waste solutions produced after zeolitization of fly ash, as well as the adjustment of the Si/Al ratio prior to synthesis process on the formation and cation exchange capacity (CEC) of zeolite product were evaluated. Both the addition of NaCl and NaF ameliorated the crystallinity and CEC of synthesized zeolite, but NaF had a better improvement effect. Na⁺ was considered to enhance the crystallization of zeolite, while F⁻ favored the dissolution of fly ash. The type of zeolite formed depended on the Si/Al ratio of the starting material prior to the nucleation and crystallization of zeolite. The adjustment of the Si/Al ratio of fly ash by addition of Na₂SiO₄ and Al(OH)₃ changed the type and CEC of zeolite. Waste solutions contained large amount of Si and little Al due to the formation of a zeolite named NaP1 in zeolite terminology with the Joint Committee of Powder Diffraction Standard (JCPDS) code of 39-0219. The alkalinity decreased largely. As a result, the CEC value of zeolite products synthesized with waste solution as alkali source decreased. The supplementation of new alkali to adjust the alkalinity of waste solution could enhance the CEC of synthesized product. It was concluded that: (1) addition of sodium halide and adjustment of the Si/Al ratio prior to synthesis can improve the quality of zeolite; (2) waste solutions produced following the zeolitization of fly ash can be reused as an alkali source in the activation of fly ash; zero-emission of waste solution in the synthesis of zeolite from fly ash is possible.     

Are the South and North Liaohe Groups of North China Craton different exotic terranes? Nd isotope constraints

The Liaohe Group is an important Paleoproterozoic stratigraphic unit in the northeastern part of the North China Craton and is traditionally subdivided into the North and South Liaohe Groups. Associated with both the North and South Liaohe Groups are voluminous Paleoproterozoic granitoid rocks, named the Liaoji granitoids. Different tectonic models, including terrane amalgamation, continent–arc collision and rift closure, have been proposed to interpret the tectonic setting and evolution of the North and South Liaohe Groups and associated Liaoji granitoids. At the centre of the controversy between these models is whether or not the North and South Liaohe Groups developed on the same Archean basement. Nd isotopic geochemistry of the Liaoji granitoids provides important constraints on this controversial issue. The Liaoji granitoids associated with the North and South Liaohe Groups display similar ε_Nd values, restricted to a narrow range from 0 to 2, implying that these granitoid rocks were derived from the same or a similar magma source. Moreover, the Liaoji granitoids associated with the North and South Liaohe Groups have similar Nd model ages (T_DM), ranging from 2.4 to 2.6 Ga, suggesting that the protoliths of the Liaoji granitoids associated with both groups may have formed simultaneously, and that the basement rocks underneath the Liaoji granitoids and associated North and South Liaohe Groups belong to the same continental block rather than two different blocks. Combining lithological, structural and geochronological considerations, we interpret the North and South Liaohe Groups as having developed on a single late Archean basement that underwent Paleoproterozoic rifting associated with the intrusion of the Liaoji granitoids and the formation of the Liaohe Group, and closed upon itself in the Paleoproterozoic.     

Weathering and climate change since l820 AD in Hoh Xil, Qinghai-Xizang Plateau, China——Evidence from element geochemistry of lake sediments of Gulug Co Lake

Element geochemistry of lake sediments has been widely used to detect climate change because element composition and ratios can reflect the weathering degree in the source area. Given the dement composition of lake sediments from Gulug Co Lake, Hoh Xil, Qing- hai-Xizang Plateau, chemical index of alteration （CIA）, index of composition variability （ICV） and other element ratios have been used to establish the weathering sequence of this area since 1820 AD. The weathering is so weak that the element composition change is more sensitive to climate change and autochthonous processes. From 1820 to 1984 AD, there were two drier periods with a wetter interval from 1870 to 1945 AD. After 1984 the weather showed a tendency of becoming wet.     

3-D seismic structure of the source area of the 1993 Latur, India, earthquake and its implications for rupture nucleations

The Latur earthquake (M_w 6.1) of 29 September 1993 is a rare stable continental region (SCR) earthquake that occurred on a previously unknown blind fault. In this study, we determined detailed three-dimensional (3-D) P- and S-wave velocity (V_p, V_s) and Poisson's ratio (σ) structures by inverting the first P- and S-wave high-quality arrival time data from 142 aftershocks that were recorded by a network of temporary seismic stations. The source zone of the Latur earthquake shows strong lateral heterogeneities in V_p, V_s and σ structures, extending in a volume of about 90 × 90 × 15 km³. The mainshock occurred within, but near the boundary, of a low-V_p, high-V_s and low-σ zone. This suggests that the structural asperities at the mainshock hypocenter are associated with a partially fluid-saturated fractured rock in a previously unknown source zone with intersecting fault surfaces. This might have triggered the 1993 Latur mainshock and its aftershock sequence. Our results are in good agreement with other geophysical studies that suggest high conductivity and high concentration of radiogenic helium gas beneath the source zone of the Latur earthquake. Our study provides an additional evidence for the presence of fluid related anomaly at the hidden source zone of the Latur earthquake in the SCR and helps us understand the genesis of damaging earthquakes in the SCR of the world.     

Modeling the seismic response of basin-edge structure by a sequential waveform method

A sequential waveform method is developed to simulate the seismic response of basin-edge structure excited by a plane incident P-wave. The full procedure involves: (a) a previous parameterization of the investigated model using the seismic wave velocities and depths of the sedimentary stratifications; (b) an input motion determined from the records at stations installed on hard rock; (c) forward computation of the P-SV elastic wave field by means of a two-dimensional finite difference (FD) method; (d) the optimization of the model vector using simulated annealing technique and comparing the simulated seismic response of the tested structure with the observed wave field; (e) the correction of the initial model by trial-and-error by testing the differences between synthetics and observed data, and (f) the final solution obtained by iteration using the conjugate gradient algorithm. The search of an optimal basin-edge model has been parallel processed by varying the shapes and velocities of strata on the basis of the fitting of relative timing, amplitude and phase between the output and the observed data. The input motion and sensitivity have been checked and the validity of the method has been demonstrated by numeric analysis. Using the teleseismic records generated by 7 earthquakes recorded at 26 broadband seismic stations, we have studied the seismic velocity structure of the southern edge of the Jiyang depression located in the Bohai Bay basin, northern China. Two cross sections show an agreement between the velocity results and the geological sections available in the region. In addition, we obtain evidence of three hidden faults under the sections and features that suggest major extensions at the Paleogene.     

Characterization of water bursting and discharge into underground mines with multilayered groundwater flow systems in the North China coal basin

A conceptual framework for characterization of water bursting and discharge into underground mines with multilayered groundwater flow systems is presented, based on the features of the site conditions and analyses of the water bursting and mine inundation events of the North China coal basin. Comprehensive analyses of the hydrogeological conditions for establishment of the three-dimensional groundwater flow systems of the North China coal basin revealed different vertical hydraulic connection paths or channels. These connections include karst collapse columns, fault or fracture zones, buried weathering zones, and fracture networks in aquitards, within the multilayered groundwater flow systems. Also examined, was the effect of the primary features of the flow system and those different connection paths on water bursting and discharge into the underground coal mines. It was demonstrated that appropriately identifying and adequately understanding the three-dimensional multilayered groundwater flow systems and those various vertical hydraulic connection mechanisms are critical for appropriately preventing water bursting hazards and predicting water discharge into underground mines. A valuable guideline is presented on characterization of water bursting and discharge into underground mines with multilayered groundwater flow systems.

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Resumen Un cadre de travail conceptuel pour la caractérisation du jaillissement et de la vidange des eaux dans les mines à plusieurs niveaux d'écoulement est présenté, basé sur les conditions et l'analyse sur site du jaillissement des eaux et des inondations dans les bassins charbonneux du Nord de la Chine. L'analyse compréhensive des conditions hydrogéologiques des systèmes d'écoulement tridimensionnel de ces bassins, révèle des trajets ou des chenaux qui sont autant de connections hydrauliques verticales. Ces connections comprennent des effondrement karstiques en colonne, des zones de fractures et de failles, des zones d'altération, des réseaux de fractures dans les aquitards, dans le système hydrogéologique multicouche. L'influence des caractéristiques primaires du système d'écoulement et de ces différentes connections sur le jaillissement et la vidange dans les mines, est également examiné. Il a été démontré que l'identification appropriée et la compréhension adéquate du système d'écoulement souterrain multicouche et tridimensionnel, et des mécanismes variés de connection hydraulique verticale est critiquée pour prévenir de manière appropriée les risques de jaillissement et de vidange dans les mines. Des guidelines valorisables sont présentées, pour la caractérisation du jaillissement et de la vidange dans de tels systèmes.

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Résumé Se presenta un marco conceptual para la de caracterización de la despresurización y descarga de agua a minas subterráneas con sistemas de acuíferos de múltiples niveles, el cual se basa en las condiciones del sitio, análisis de la despresurización de agua e inundaciones de minas en la cuenca de carbón del norte de la China.Un análisis comprehensivo de las condiciones hidrogeológicas para el establecimiento de los sistemas de flujo de agua de tri-dimensionales en la cuenca de carbón del norte de la China ha revelado diferentes canales hidráulicos verticales. Estas conexiones incluyen columnas de karst colapsadas, fallas o zonas de fracturas, zonas de regalita hundida y redes de fracturas en zonas de poca permeabilidad dentro de los sistemas de flujo de múltiples niveles.También se investigó el efecto de los rasgos primarios del sistema de flujo y los diferentes canales conectivos sobre la despresurización y descarga de agua a minas subterráneas. Se demostró que el entendimiento e identificación adecuada de los sistemas de acuíferos de múltiples niveles en tres dimensiones es crítico para prevenir apropiadamente la despresurización y descarga de agua a minas subterráneas. Se presentan lineamientos valiosos en relación con la despresurización y descarga de agua a minas subterráneas en sistemas de flujo de múltiple nivel.

     

Detection of spectral variability of the optical component of the IR source IRAS 20508+2011

Our high-resolution spectral observations have revealed variability of the optical spectrum of the cool star identified with the IR source IRAS 20508+2011. We measured the equivalent widths of numerous absorption lines of neutral atoms and ions at wavelengths 4300–7930 Å, along with the corresponding radial velocities. Over the four years of our observations, the radial velocity derived from photospheric absorption lines varied in the interval V _r⊙ = 15–30 km/s. In the same period, the Hα profile varied from being an intense bell-shaped emission line with a small amount of core absorption to displaying two-peaked emission with a central absorption feature below the continuum level. At all but one epoch, the positions of the metallic photospheric lines were systematically shifted relative to the Hα emission: ΔV _r = V _r(met) ? V _r(Hα, emis) ≈ ?23 km/s. The Na D doublet displayed a complex profile with broad (half-width ≈ 120 km/s) emission and photospheric absorption, as well as an interstellar component. We used model atmospheres to determine the physical parameters and chemical composition of the star’s atmosphere: T _eff = 4800 K, log g = 1.5, ξ_t = 4.0 km/s. The metallicity of the star differs little from the solar value: [Fe/H]_⊙ = ?0.36. We detected overabundances of oxygen [O/Fe]_⊙ = +1.79 (with the ratio [C/O] ≈ ?0.9), and α-process elements, as well as a deficit of heavy metals. The entire set of the star’s parameters suggests that the optical component of IRAS 20508+2011 is an “O-rich” AGB star with luminosity M _v ≈ ?3^m that is close to its evolutionary transition to the post-AGB stage.     

Impact of Flood Disasters on Taiwan in the Last Quarter Century

The increasing natural disasters, especially floods during the last quarter century, are raising the economic losses in Taiwan. The most severe hazard in Taiwan is flooding induced by typhoons and storms in summer and autumn. By comparing the rivers around the world, the ones in Taiwan have the steepest slopes, the largest discharge per unit drainage area, and the shortest time of concentrations. Rapid urbanization without proper land uses managements usually worsen the flood problems. Consequently, flood hazards mitigation has become the most essential task for Taiwan to deal with. Although the government keeps improving flood defense structures, the flood damage grows continuously. In this article, possible flood mitigation strategies are identified for coping with complex environmental and social decisions with flood risk involved.