锡铁山石晶体结构中Fe3+的两种亚晶位

对产于青海锡铁山铅锌矿氧化带中的锡铁山石进行了５７Ｆｅ穆斯堡尔谱的研究，在晶体结构分析的基础上进行了谱峰的重新解释，发现由于配位Ｃｌ－离子无序占位引起Ｆｅ３＋离子所占配位八面体的畸变，形成了Ｆｅ３＋的两种亚晶位，并根据结构数据指定了这两种亚晶位各自形成的四极双峰。     

横断山区花岗岩类中角闪石的标型特征及其成因意义

本文研究了横断山区不同成因类型花岗岩中角闪石的化学成分、微量元素、稀土元素、晶胞参数和物理性质等特征。按化学成分对角闪石作了晶体化学成因分类。在三种不同成因类型角闪石中，其M值[M=Mg/(Mg Fe^2 )]各不相同；幔型M＞0．7，壳幔型M＝0．7－0．5，壳型M<0．5。     

Pretreatment of high strength waste emulsions by combined vibratory shear enhanced process with Fenton oxidation

Pretreatment of waste emulsions with high organic content by a combined process of vibratory shear enhanced process and Fenton’s oxidation prior to biological treatment was investigated. Vibrating membrane had shown good performance in chemical oxygen demand and oil removals and the mitigation of concentration polarization. However, the permeate after filtration processing still contained high content of organics. Thus, additional Fenton oxidation was applied to reduce the organic loading, and improve the biodegradability of the wastewater. The optimal molar ratio of ferrous iron to hydrogen peroxide was 0.05 obtained from the jar-test experiments. Removal of organics was enhanced by increasing hydrogen peroxide dosage, while efficiency of hydrogen peroxide reached maximum of 1.11(w/w) at the hydrogen peroxide dosage of 6.8 g/L. Furthermore, the biological experiments indicated that the high concentration of organics could inhibit microbial activity, which decreased the chemical oxygen demand degradation rates. The adaptive period of the microbe was greatly shortened using Fenton’s reagent at the low dosages. The improvement of the biodegradability could be explained by partial mineralization and chemical transformation of parent organic compounds after Fenton oxidation.     

Magma type and genesis of the basic-ultrabasic layered intrusions in Panzhihua-Xichang area,Southwest China

The layered intrusions in the Panzhihua-Xichang area may be grouped into two types: basic rock masses represented by the Panzhihua rockbody and basic-ultrabasic rock masses represented by the Hongge rockbody. Their major difference lies in that the former has poorly developed ultramafic facies, while the latter is characterized by well developed mafic facies and ultramafic facies. There exists apparent rhythmic stratification in the rock masses, which can be basically divided into four grades in terms of superimposition relationship and multicycle characters. Both direct and indirect evidence suggest that the magma responsible for the layered intrusions in this area should be a transition-type alkaline olivine basalt magma derived directly from partial melting of the upper mantle. In rhythmic cycles of various grades, the magmatic evolution is characterized obviously by periodicity and early enrichment of Fe and Ti, which is evidently different from the evolution of the Skaergaard magma in which Fe and Ti are enriched at the late stage. The FCA diagram can be used to describe the unique evolutionary trend of magma in this area. It is demonstrated in this diagram that the enrichment of Fe and Ti is consistent with the increase of basicity. In the upper magmatic chamber, the evolutionary trend of magma is conditioned by the difference in pressure, and this enables magma to form different types of rock assemblage. In the Fo-Di-An system, when the pressure exceeds 5 x 18⁸ Pa, forsterite is incompatible with anorthite, and the rock facies sequence of Hongge type might form; when the pressure is lower than 5 x 10⁸ Pa, forsterite can coexist with anorthite, and the rock facies sequence of Panzhihua type is likely to form if the magma is relatively rich in Mg and Fe components.     

Iron isotopic analyses of geological reference materials on MC-ICP-MS with instrumental mass bias corrected by three independent methods

Here we report iron (Fe) isotopic data of three pure Fe solution standards (IRMM-014, GSB Fe, and NIST 3126a) and five widely used geological reference materials (RMs) from the United States Geological Survey and Geological Survey of Japan obtained on a Neptune Plus multi-collector–inductively coupled plasma–mass spectrometer (MC-ICP-MS) in our laboratory over the past 3 years. The instrumental mass bias was corrected by three independent methods: sample-standard bracketing (SSB), Ni doping?+?SSB, and ⁵⁷Fe–⁵⁸Fe double spike?+?SSB. Measurements reveal that both the Ni doping and double spike methods helped calibrate short-term fluctuations in mass bias. Collectively, almost all measurements of RMs yielded δ⁵⁶Fe within?±?0.05 of recommended values, provided that each sample was measured four times on MC-ICP-MS. For the first time, new recommended values for NIST SRM3126a are reported (δ⁵⁶Fe?=?0.363?±?0.006, 2SE, 95% CI; and δ⁵⁷Fe?=?0.534?±?0.010, 2SE).     

Magnetic properties,characteristic spectra and colors of turquoise

The unique bright bluish-green color of turquoise as a high-grade jade has long received wide attention. The relationship between the color of turquoise and its composition and structure is described in this paper on the basis of chemical data, EPR, magnetic susceptibility, absorption and Mössbauer spectra. The results show that the basic color of turquoise (bright blue) is related to the existence of octahedrally on the amount of iron. EPR, magnetic susceblue through green to earth-yellow is dependentcoordinated Cu²⁺ and the shade variation from ptibility, and crystal-field spectra of Cu²⁺ have been analyzed and compared with the theoretical calculations. A preliminary discussion is also made of the color change as a function of temperature.     

西藏自治区昂仁县朱诺铜矿地质特征及找矿潜力远景评价

通过典型斑岩型铜矿模式对比,朱诺铜矿含矿斑岩体剥蚀程度为钾化带和黄铁绢英岩化上部,向深部及西部,具有较大的找矿潜力。     

Geochemical Features of Ophiolite in Mianxian Lueyang Suture Zone，Qinling Orogenic Belt

ＧｅｏｃｈｅｍｉｃａｌＦｅａｔｕｒｅｓｏｆＯｐｈｉｏｌｉｔｅｉｎＭｉａｎｘｉａｎＬｕｅｙａｎｇＳｕｔｕｒｅＺｏｎｅ，ＱｉｎｌｉｎｇＯｒｏｇｅｎｉｃＢｅｌｔＬａｉＳｈａｏｃｏｎｇ；ＺｈａｎｇＧｕｏｗｅｉ（ＤｅｐａｒｔｍｅｎｔｏｆＧｅｏｌｏｇｙ，Ｎｏｒｔ...     

东亚季风“2.8ka”事件高分辨率的石笋记录

据湖北省神农架永兴洞一支石笋的8个230Th年龄、648个δ18O数据,建立了晚全新世4.40～ 1.75ka B.P.时段平均分辨率为4a的东亚夏季风演化序列,其中在2.92～ 2.74ka B.P.期间,δ18O发生显著正偏,幅度达2.5‰,指示一个显著的弱季风事件(这里称之“2.8ka”事件).该事件以夏季风缓慢减弱开始,迅速增强结束,事件内部有两个次一级的振荡旋回(两峰三谷结构),在内部细节与转型特征上类似湖北和尚洞石笋δ18O记录的“8.2ka”事件,暗示发生在全新世这两个冷事件的驱动机制基本一致.这两个弱季风事件都发生在太阳活动明显减弱时期,并分别与北大西洋Bond 2和Bond 5冰漂碎屑事件同步,表明百年尺度的东亚季风环流的演化由太阳活动和北高纬气候共同驱动.     

矿区公路平面坐标计算方法

根据公路测量中几种基本的平面线型——直线、园曲线、缓和曲线和卯型曲线的特点,直接给出各线型的中桩坐标和切线方位角的计算公式,根据中桩坐标的计算结果及边线桩至道路中线的水平距离,计算边线桩的坐标。这4种线型的计算公式非常适宜于极坐标法放样矿区公路的中桩和边桩计算。对于较长矿区公路的测量,可以把它分解成多个直线、园曲线和缓和曲线等图元对象,再运用其相应公式进行计算。