从怀来4井水化学异常变化分析流体在孕震过程中的作用

20世纪60年代，流体在地震孕育与发生过程中的作用就已受到研究者关注。如Evans(1966)发现美国洛基山兵工厂周围地震活动与深井注入废液有关。在我国的地壳流体活动与诱发地震关系的研究方面，也取得了很多成果。针对上地壳流体与地震活动的关系，前人在辽东半岛、东南沿海、红河断裂带、京津地区进行了系统研究。结果表明，地壳热流体活动区的地震活动多，但多为中小地震；而地壳热流体活动弱的地区地震活动数量相对少，但以大震活动为主。近年来，地下流体在孕震过程与构造活动中的作用的研究已有了一些进展。     

中国大陆地区中强地震前加卸载响应比异常时间尺度的统计研究

加卸载响应比理论是近年来提出的地震预测方法。本文进行了加卸载响应比异常时间尺度的统计研究，其中包括中国大陆地区5．0～8．1级的部分中强地震共30个震例，并得出加卸载响应比异常的时间尺度与未来地震震级之间的拟合函数。结果表明，地震前加卸载响应比异常的时间尺度与未来地震的震级具有正变关系，即震级越高，地震前加卸载响应比异常的时间尺度越长。根据加卸载响应比异常的时间尺度与震级之间的关系可以估计未来地震的发震时间，同时，可以确定加卸载响应比时空扫描过程中时问长度的大小。     

用MATLAB对倾斜观测资料进行预处理

用MATLAB语言分析了龙岩地震台地倾斜垂直摆数字观测仪NS向观测数据的频率成分,然后分别调用完全的设计函数butter、cheby1、cheby2,设计了低通、带通、高通滤波程序,对龙岩台地倾斜垂直摆数字观测仪NS向观测数据进行了滤波,得到了相关频率的滤波曲线图。本文只对观测数据进行一个月的数据处理,若将一年或几年的观测数据进行滤波处理,并进一步进行波形分析或处理,也许能找出某些与地震有关的信息,为地震分析预报提供服务。     

2-D crustal Poisson’s ratio from seismic travel time inversion in Changbaishan Tianchi volcanic region

Based on the inversion method of 2D velocity structure and interface, the crustal velocity structures of P-wave and S-wave along the profile L ₁ are determined simultaneously with deep seismic sounding data in Changbaishan Tianchi volcanic region, and then its Poisson’s ratio is obtained. Calculated results show that this technique overcomes some defects of traditional forward calculation method, and it is also very effective to determine Poisson’s ratio distribution of deep seismic sounding profile, especially useful for study on volcanic magma and crustal fault zone. Study result indicates that there is an abnormally high Poisson’s ratio body that is about 30 km wide and 12 km high in the low velocity region under Tianchi crater. Its value of Poisson’s ratio is 8% higher than that of surrounding medium and it should be the magma chamber formed from melted rock with high temperature. There is a high Poisson’s ratio zone ranging from magma chamber to the top of crust, which may be the uprise passage of hot substance. The lower part with high Poisson’s ratio, which stretches downward to Moho, is possibly the extrusion way of hot substance from the uppermost mantle. The conclusions above are consistent with the study results of both tomographic determination of 3D crustal structure and magnetotelluric survey in this region. Foundation item: Key Project from China Earthquake Administration and the Project (95-11-02-01) from Ministry of Science and Technology (2001DIA10003). Contribution No. RCEG200401, Geophysical Exploration Center, China Earthquake Administration.     

致密砂岩的形成机制及其地质意义——以塔里木盆地英南2井为例

砂质岩的孔隙和喉道被网格状粘土矿物和次生加大矿物充填成微细孔喉状结构时,形成具有较高毛细管压力的致密砂岩。它与地层水发生水锁效应,可大大降低渗透率,成为致密砂岩盖层。当含水饱和度在50%以下时,束缚水饱和度比较低,致密砂岩储层可以产气;当含水饱和度在50%～90%区间时,具有较高的束缚水饱和度,相对渗透率非常低,它既不能产气也不能产水,反映为渗透率瓶颈区(具有盖层性质);当含水饱和度大于90%以上时,致密砂岩储层仅微量产水。塔里木盆地英南2井侏罗系气藏盖层由致密砂岩构成,不含水时的气体渗透率在(0.027～0.081)×10-3μm2,不能构成封堵;当含水饱和度达到60%以上时,相对渗透率几乎为零,构成有效盖层。     

深基坑支护方案的分析与优化

针对武汉市南湖岸边复杂的地质条件及周边环境,在某高层建筑的深基坑支护结构设计中,结合实际因地制宜地对基坑的支护方法进行了分析比较。支护效果及实测数据表明,该工程所采用的混合式支护实施方案技术安全可靠,经济合理,可为同类型基坑工程设计提供借鉴。     

Ruthenium-ion-catalyzed oxidation of asphaltenes and oil-source correlation of heavy oils from the Lunnan and Tahe oilfields in the Tarim Basin, NW China

The identification of marine source rocks in the Tarim Basin is debated vigorously. The intention of this paper is to investigate the asphahenes in heavy oils from the Lunnan and Tabe oilfields and Well TD2 with ruthenium-ions-catalyzed oxidation technique (RICO), in order to explore its role in oil-oil and oil-source correlations, The RICO products included n-alkanoic acids, α,ω-di-n-alkanoic acids, branched alkanoic acids, tricyclic terpanoic acids, hopanoic acids, gammacerane carboxylic acid , regular sterane carboxylic acids and 4-methylsterane carboxylic acids. The n-alkyl chains and biomarkers bounded on the asphaltenes were of unsusceptibility to biodegradation. The distribution and absolute concentrations of n-alkanoic acids in the RICO products of heavy oils from the Lunnan and Tabe oilfields are different from those of Well TD2. The biomarkers bounded on the asphahenes, especially steranes, have a distribution trend similar to that of the counterparts in saturates. The sterane carboxylic acids and 4-methylsterane carboxylic acids in the RICO products of heavy oils from the Lunnan and Tahe oilfields, dominated by C30 sterane and C31 4-methylsterane carboxylic acids, respectively, are significantly different from those of the heavy oils of Well TD2, whose dominating sterane and 4-methylsterane carboxylic acids are C28 sterane and C29 4-methylsterane acids, respectively. The RICO products of the asphaltenes further indicate that the Middle-Upper Ordovician may be the main source rocks for heavy oils from the Lunnan and Tabe oilfields.     

An invariance in the carbazoles of petroleum

A remarkable invariance in the ratio of 1,3-dimethylcarbazole （DMC） to 1,6-DMC was discovered in crude oils from the Pearl River Mouth Basin, South China Sea. The remarkably invariant ratio is kept at a constant of about unity regardless of their concentrations, sources or maturities for the sampies. In combination with the molecular structures of 1,3- and 1,6-DMCs, the invariance might indicate that the nitrogen compounds share a common precursor with a skeleton of 1-methylcarbazole and are formed through methylation at C3 and C6 with an essentially identical rate.