淤泥质海岸入海河口闸下港道河相关系

以江苏沿海北部的射阳河闸下港道为原型,建立二维水动力及泥沙输运概化数学模型,模拟了淤泥质海岸闸下港道淤积过程。分别在不考虑径流年内分配变化和考虑径流年内分配变化的情况下,研究了入海径流对港道内水沙动力和冲淤演变的影响。参考前人研究成果,结合量纲和谐准则,根据模型的计算结果,建立了淤泥质海岸闸下港道年均平衡流量与汛期排水比例、河床断面积、外海潮差、潮波变形、港道长度等因素间的河相关系式,对在实际情况中达到动态冲淤平衡的某条特定港道,可简化为港道年均流量与河床断面积间关系式的简化形式,并通过分析实测资料,对公式的简化形式加以佐证。     

深海嗜热异化铁还原菌Caloranaerobacter ferrireducens DY22619T对不同铁氧化物的铁还原特性

异化铁还原微生物在铁元素的地球化学循环中具有重要意义。深海热液活动是大洋铁元素的重要来源,目前深海热液环境中铁代谢相关微生物研究很少。本文对一株分离自深海热液区的嗜热异化铁还原菌新种Caloranaerobacter ferrireducens DY22619T的铁还原特性进行分析,比较了该菌对无定形羟基氧化铁、无定形铁氧化物和针铁矿3种不同铁氧化物的铁还原速率;并利用透射电镜对矿化产物进行矿物形貌、组成元素和晶型的分析。研究发现该菌生长在指数期至稳定期时,铁还原速率最快,其中对无定形羟基氧化铁和无定形铁氧化物的还原速率较高,达2.82 μmol/h和2.15 μmol/h;透射电镜结果表明,该菌可将3种不同胞外铁氧化物均还原矿化形成颗粒状磁铁矿,由针铁矿矿化形成的磁铁矿少但粒径最大,而由无定形铁氧化物形成的磁铁矿晶面不同于另外两种铁氧化物。结果表明,该菌有很强的铁还原和矿化能力,能厌氧呼吸还原三价铁氧化物,但是铁氧化物的性质对该菌胞外铁还原能力和矿化形成的磁铁矿的性质有重要影响。本研究为认识深海热液环境中异化铁还原菌在铁元素的地球化学循环和生物成矿过程提供了参考。     

Hydrothermal Fluid Sources of the Fengjia Barite–fluorite Deposit in Southeast Sichuan,China: Evidence from Fluid Inclusions and Hydrogen and Oxygen Isotopes

The Fengjia barite–fluorite deposit in southeast Sichuan is a stratabound ore deposit which occurs mainly in Lower Ordovician carbonate rocks. Here we present results from fluid inclusion and oxygen and hydrogen isotope studies to determine the nature and origin of the hydrothermal fluids that generated the deposit. The temperature of the ore‐forming fluid shows a range of 86 to 302 °C. Our detailed microthermometric data show that the temperature during mineralization of the fluorite and barite in the early ore‐forming stage was higher than that during the formation of the calcite in the late ore‐forming stage. The salinity varied substantially from 0.18% to 21.19% NaCl eqv., whereas the density was around 1.00 g/cm³. The fluid composition was mainly H₂O (>91.33%), followed by CO₂, CH₄ and traces of C₂H₆, CO, Ar, and H₂S. The dominant cation was Na⁺ and the dominant anion Cl^‐, followed by Ca²⁺, SO₄^2‐, K⁺, and Mg²⁺, indicating a mid–low‐temperature, mid‐low‐salinity, low‐density NaCl–H₂O system. Our results demonstrate that the temperature decreased during the ore‐forming process and the fluid system changed from a closed reducing environment to an open oxidizing environment. The hydrogen and oxygen isotope data demonstrate that the hydrothermal fluids in the study area had multiple sources, primarily formation water, as well as meteoric water and metamorphic water. Combined with the geological setting and mineralization features we infer that the stratabound barite–fluorite deposits originated from mid–low‐temperature hydrothermal fluids and formed vein filling in the fault zone.     

Curvedness feature constrained map matching for low-frequency probe vehicle data

Map matching method is a fundamental preprocessing technique for massive probe vehicle data. Various transportation applications need map matching methods to provide highly accurate and stable results. However, most current map matching approaches employ elementary geometric or topological measures, which may not be sufficient to encode the characteristic of realistic driving paths, leading to inefficiency and inaccuracy, especially in complex road networks. To address these issues, this article presents a novel map matching method, based on the measure of curvedness of Global Positioning System (GPS) trajectories. The curvature integral, which measures the curvedness feature of GPS trajectories, is considered to be one of the major matching characteristics that constrain pairwise matching between the two adjacent GPS track points. In this article, we propose the definition of the curvature integral in the context of map matching, and develop a novel accurate map matching algorithm based on the curvedness feature. Using real-world probe vehicles data, we show that the curvedness feature (CURF) constrained map matching method outperforms two classical methods for accuracy and stability under complicated road environments.     

An approach to determination of phenolic compounds in seawater using SPME-GC-MS based on SWCNTs coating

Phenolic compounds have become one kind of the important pollutants of the marine environment. Single-walled Carbon nanotubes, as one-dimensional nano materials, have light weight and perfect hexagonal structure of connections, with many unusual mechanical, chemical and electrical properties. In recent years, with the research of carbon nanotubes and other nano materials, the application prospect is also constantly discussed. In this paper, homemade single-walled carbon nanotubes(SWCNTs) coating was used for establishing an analytical approach to the determination of five kinds of phenolic compounds in seawater using SPME-GC-MS. Optimal conditions: After saturation was conducted with Na Cl, and p H was adjusted to 2.0 with H_2SO_4, the extract was immersed in a water bath at 40 for GC℃-MS determination through 40-min agitating extraction at 500 rmin~(-1) and 3-min desorption at 280℃. The liniearities ranged between 0.01-100 μg L~(-1), and the determination limits ranged between 1.5-10 ngL~(-1). The relative standard deviation(RSD, n = 5) was less than 6.5%. For the phenolic compounds obtained from the spiked recovery test for actual seawater samples, the rates of recovery were 87.5%-101.7%, and the RSDs were less than 8.8%, which met the requirements of determination. Due to its simplicity, high efficiency and low consumption, this approach is suitable for the analysis of trace amounts of phenolic compounds in marine waters.     

上海中心城就业中心体系测度————基于手机信令数据的研究

利用手机信令数据识别上海市域内手机用户的工作地和居住地,获取就业者的通勤数据,测度上海中心城的就业中心体系.首先用就业者工作地数据生成就业密度分布图,基于中心城的就业密度识别就业中心.随后,用就业者工作地和居住地数据分别从就业密度和通勤联系两方面测度各中心的能级,分析各中心的腹地和势力范围.研究发现:① 上海中心城的就业中心呈主中心强大的弱多中心体系;② 就业密度越高的中心与其他地区的通勤联系一般也越强,但通勤联系在各中心间的差异更显著;③ 能级越高的中心腹地面积越大,但势力范围不一定越大;④ 相比于能级,职住功能混合度对职住平衡的影响更大;⑤缺少就业中心的地区势力范围呈交替状.本研究一定程度上能有助于解决既往就业中心体系研究因空间单元较大,缺少通勤数据在中心识别,通勤联系测度等方面受到的局限,希望能为构建上海中心城就业多中心体系提供帮助.     

玲珑金矿西山幔源脉岩地球化学特征

玲珑西山幔源脉岩主微量元素的变化暗示了源岩很可能经历过类似俯冲带流体的交代作用,矿化流体中含有较高含量的金属矿物,具有Eu的正异常,指示了源区是深源的。脉岩中的CO2来源可能是花岗岩岩浆热液的混入,石英来源于陆壳碎屑物质部分熔融形成的S型花岗岩,硫的来源与幔源脉岩岩浆同源,或来自地幔,或来自地壳深部。     

胶东埠上金矿煌斑岩地球化学特征及成因

大量的研究资料表明煌斑岩与金矿在空间上、时间上具明显的对应关系。埠上金矿位于胶东玲珑金矿田西南方向的金岭金矿田的中北部;有关该矿区煌斑岩的研究资料较少。该文结合岩石学、矿物学、大地构造学等特征,对区内煌斑岩的地球化学进行了研究,揭示其内在成因,认为区内煌斑岩是因该区受到古太平洋板块的俯冲、华北板块与杨子板块碰撞造山及郯庐断裂带等构造岩浆活动的影响,俯冲洋壳析出的流体交代地幔形成的具氧化性的EM1型富集型地幔岩浆于造山拉张期在大陆活动边缘浅成侵入而成的。     

Characteristics of groundwater flow field after land creation engineering in the hilly and gully area of the Loess Plateau

In order to study the degree of influence and control mechanism to groundwater flow field caused by land creation engineering in the hilly and gully area of the Loess Plateau, based on the geological and engineering conditions of the first stage project of Yan’an new district in China, numerical simulation of groundwater flow is carried out by the Feflow and GIS technologies. From the simulation, punning measure relatively reduces infiltration recharge and artificial gravel drain increases groundwater seepage. The basic characteristics of groundwater flow field is controlled by the old and new topographies in the whole study area, and artificial gravel drain plays an auxiliary role in accelerating groundwater drawdown upstream and promotes groundwater rise downstream. According to differences of groundwater level and declining percentages of hydraulic gradient in the main and secondary gullies, dewatering of artificial gravel drain in the secondary gully is more effective than that in the main gully, which will yet play an important role in the future. The study results will make contributions to understand groundwater response to land creation engineering and will be beneficial to take necessary measures to prevent collapse of loess and failure of building foundation in the hilly and gully area of the Loess Plateau.