Anaerobic digestion of residual liquid effluent (brown juice) from a green biorefinery

This work studied the anaerobic digestion of brown juice, a liquid residual stream generated from biomass fractionation in a green biorefinery. Biomethane potential batch tests and inhibition studies of brown juice were performed during continuous processing in an upflow anaerobic sludge blanket reactor. Prolongation of the lag phase in the batch tests with increasing substrate/inoculum ratio suggested initial inhibition, which was, however, overcome by adaptation. This was indicated by high final methane yields, which were close to the theoretical maximum of up to 500 L-CH₄ kg-VS^?1, achieved after 15 days for most of the set-ups. Reactor operation at the organic loading rate of 13.9 g-COD L^?1 day^?1 and hydraulic retention time of 3 days revealed methane yields of 202 L-CH₄ kg-COD^?1 (307 L-CH₄ kg-VS^?1). Particle size analysis of the granules used in the reactor showed disintegration of the larger granules.     

High-performing antifouling bacterial consortium for submerged membrane bioreactor treating synthetic wastewater

Biofouling, associated with membranes, is considered as a major operational challenge in membrane bioreactor (MBR) technology. Interrupting the process for the formation of biofilm by the action of interspecies quorum quenching (QQ) has received a significant attention since recent years. An antifouling bacterial consortium was identified to improve biofouling inhibition performance during MBR operation. For this purpose, various QQ bacteria were isolated from laboratory-scale MBR using enrichment culture method and identified via 16S rRNA. Potential quenching strains including Enterobacter cloaca, Delftia sp., and Pseudomonas sp. were utilized to control biofouling in the MBR operated in the continuous mode for 38 days. Three laboratory-scale MBRs, including two MBRs with different anti fouling consortium and a control, were operated in parallel under similar operating conditions. Biofouling control by QQ bacteria was compared based on the membrane permeability and EPS secretion from biofilm on the membrane. Both MBRs with antifouling consortium (AC-MBRs) experienced around three times less biofouling as compared to conventional MBR leading to significant decrease in acyl homoserine lactones (AHLs) concentration in the biocake. More than 90, 45, and 49% of COD, NH₄–N, and PO₄ ^3?–P removal efficiencies elucidate that QQ bacterial consortium could effectively reduce membrane biofouling without compromising the MBR efficiency. Comparatively lower concentration of bound EPS in AC-MBRs restricted the bacterial adhesion to membrane resulting in enhanced membrane permeability depicting that a broader range of signal molecules could be hydrolyzed using antifouling consortium than single or no QQ strain in the submerged MBR.     

Interactive effect of cadmium and zinc on chromium uptake in spinach grown in Vertisol of Central India

A pot culture experiment was conducted to study impact and interaction of multi-metals on growth, yield and metals uptake by spinach (variety All Green). Three levels of each chromium (0, 50 and 100 mg/kg), cadmium (0, 1 and 2 mg/kg) and zinc (0, 10 and 20 mg/kg) in combinations (total treatments 3 × 3 × 3 = 27) were applied in a Vertisol (5 kg). The results showed that increasing the concentration of chromium, cadmium and zinc in soil enhanced the respective metal concentrations in spinach root and shoot. When cadmium at 2 mg/kg along with chromium at 100 mg/kg soil was applied, chromium concentration and uptake were decreased in root and shoot. Meanwhile, zinc application had no significant effect on chromium uptake and concentration in spinach biomass. From the results, it was concluded that cadmium at higher dose had an antagonistic effect over chromium. On the other hand, in chromium, cadmium and zinc combinations particularly at their higher levels, a competition among each other was found. Therefore, the findings could be used as guidelines for controlling and management of heavy metals pollution in farmland.     

Investigation of metal pollution in Moryayla (Erzurum) and surrounding stream sediments,Turkey

The enrichment factor (EF), geochemical index (Igeo), pollution factor (Cf), and pollutant load index (PLI) were calculated using average shale metal concentration values to determine metal pollution in Moryayla and surrounding stream sediments. It was determined that the average concentration values are above the world average shale values. According to the results obtained, the mean accumulation levels of heavy metals in the study area were Mn > Zn > Cu > Pb > As > Cr > Ni > Sb. Considerable degree of enrichment was observed because the elements As, Cu, and Pb are at EF > 5 at locations 47, 53, 70, and 71. The values obtained from the Igeo, Cf, and PLI are a wide range of pollutants (from unpolluted to moderately polluted to extremely polluted to) for the various elements studied.     

A novel continuous magnetic nano-Fe<Subscript>3</Subscript>O<Subscript>4</Subscript>/perlite fixed bed reactor for catalytic wet peroxide oxidation of dyes: reactor structure

In the present work, a continuous catalytic wet peroxide oxidation fixed bed reactor was employed to treat a simulated wastewater sample with malachite green dye, as a contaminant. Natural perlite particle-supported nano-Fe₃O₄ catalyst was used as a fixed bed inside a reactor, and it was immobilized by a persistent magnetic field. The range of (perlite) particle sizes was from 100 to 1000 nm. The effects of various operating parameters, including temperature of the reactor, pH, initial hydrogen peroxide concentration and initial dye concentration, were investigated on the percentage removal of malachite green dye. Load of catalyst of 2 g and volumetric flow rate of 1 L/h were selected for all the tests. Maximum malachite green degradation was 99.5 ± 0.3%. This removal percentage was attained at temperature of 80 °C, pH = 6, initial dye concentration of 6 mg/L and initial hydrogen peroxide concentration of 100 mg/L. The process was isotherm, and the catalyst showed high catalytic activity in the steady-state condition. The loss of catalyst was less than 0.3%.     

Potency of constructed wetlands for deportation of pathogens index from rural,urban and industrial wastewater

Pathogen removal is essential for wastewater treatment and its potential reuse in agriculture. Three field-scale wastewater treatment systems consisting of free surface flow were operated around 1.5 years receiving water from urban domestic, rural domestic and industrial sources. The study was conducted to evaluate seasonal performance of constructed wetland systems in removing Escherichia coli, Enterococci and total coliforms under continuous hydraulic flow. Results displayed that all three wetlands gain recognition in removing pathogen load with high removal efficacy till water reaches output ports. Removal efficiencies were even higher, 66–93, 78–92 and 80–94% for E. coli, Enterococci and total coliforms, respectively, within constructed wetlands. Remarkably at shorter temporal scales in CW-A, greater homogeneity of pathogen concentrations was assessed at wetland outlet sites. In outlet ports, results displayed a highly effective removal of E. coli concentration 80–90% (June 2015), 86–92% (October 2015) and 79–92% (February 2016), Enterococci 80–94% (June 2015), 83–94% (October 2015) and 80–94% (February 2016) and total coliforms 85–93% (June 2015), 87–95% (October 2015) and 88–96% (February 2016). Positive correlation was observed between bacterial indicators (E. coli–Enterococci, r = 0.038; p < 0.01 and E. coli–total coliforms, r = 0.142; p < 0.01). Removal of bacterial indicators in constructed wetland was also displayed by PCA in which three-component analysis of variance was 98.39% and showed a clear decrease in measured parameter gradients toward samples from outlet ports. Constructed wetlands provide cost-effective treatment systems for reducing the pathogen load in wastewater in variable agro-climatic conditions and thus improve water quality.     

Comparison of different models of water quality index in the assessment of surface water quality

The method of water quality index is widely used in evaluation of the surface water quality because of its capability to summarize a number of water quality parameters into one numeric value, along with defined scale of water quality range. The current investigation includes application of modified model for calculating water quality index values, generated using experimental data and literary models. Software was created using modular design. Fourteen physical, chemical and biological parameters representing water quality state along with the assigned weights were elected. Comparison between models generated based on Serbian and American models of water quality index was done. Selected parameters differ mutually in number of parameters used in calculation of index, as well as in values of the weighting factors. In order to enable an efficient water quality analysis and to reconcile the requirements of both Serbian and American model, two software solutions were generated and processed on the example of the water quality of the Danube River in Serbia. Danube water quality was assessed at seventeen measuring locations along the river flow. Index values obtained from the two generated software applications were compared with the results of the official Serbian online calculator. Water quality determined using new generated models shows stricter approach and one class lower water quality compared to the existing Serbian model. Therefore, modular and open-generated simulation software is of great significance for the comparison and testing of different water quality models, not just those two shown in this study.     

Heavy metal exposure from co-processing of hazardous wastes for cement production and associated human risk assessment

This study was carried out to determine the concentration of heavy metals (Cd, Ni, Pb, Cr, Ni and Zn) in ordinary Portland cement (OPC) produced from the co-processing with hazardous waste in comparison with OPC produced using natural raw materials. The results showed that the concentration of heavy metals in cement produced from natural raw material was in the order of Zn > Pb > Cr > Ni > Cu > Cd. Zn and Cd were the highest and the lowest concentrations, respectively, in cements produced from the co-processing activity. The difference between heavy metals concentrations in OPC produced with and without co-processing was found to be statistically significant. The concentration of heavy metals in the cement produced is generally factory dependent. The human risk assessment associated with the heavy metals for non-carcinogenic and carcinogenic risks has been evaluated. The calculated hazard index (HI) and total lifetime cancer risks (LCR) were lower than the acceptable threshold reference values, HI < 1 and LCR < 1 × 10^?4, respectively. Thus, it is anticipated that there is no potential of non-carcinogenic and carcinogenic risks for both adult and children. However, the findings indicated that there is a need for regulatory monitoring. The exposure pathway for both non-carcinogenic and carcinogenic risks are both in the order of ingestion > dermal > inhalation.     

Management of shock loads wastewater produced from water heaters industry

Water heater manufacturing represents one sector of household electrical appliance industry. It includes several batch processes which resulted in a highly polluted wastewater as shock loads. The objective of this study was to manage the shock loads wastewater with a simple and cost-effective approach prior to final discharge into municipality. To achieve this objective, two approaches were studied. The first approach was the chemical treatment of the accumulated shock loads wastewater using alum and an anionic polymer. Although this approach produced a very high-quality effluent, it was economically and technically infeasible. The second approach was a controlled release of the shock loads to the normal daily discharge in a way that guarantees the compliance of the end-off-pipe with the National Regulatory Standards. This solution required establishment of an equalization tank for normal daily flow and a holding tank for controlled release of the shock loads. Mathematical calculations were carried out to determine the most violating parameters in order to calculate the mixing ratio the of shock loads with the normal daily flow. Full engineering design of the proposed solution was carried out. This approach was implemented and proved to be simple, easy to operate, cost-effective and can be replicated in similar batch processing manufacturing plants.     

Improving the indoor air quality using the individual air supply system

Indoor air quality attracts great interest. Many dwellings are ventilated naturally. The article presents the gravity system conversion into individual air supply system, which can be equipped with air fan. This solution’s impact on the interior microclimate was analyzed. The proposed solution uses the lower natural ventilation ducts sections, which are not normally used as air supply channels to bring air to the housing. Exhaust grilles were located in the adjacent rooms. Individual air supply system with switched off fan improves indoor air quality insufficiently; however, switching on the device causes a very significant change. A large carbon dioxide concentration reduction (which was used as an air quality indicator) has been confirmed by rigorous statistical analysis, the results of which were presented in the article.