Hydraulic Conductivity Tests for Evaluating Compatibility of Lateritic Soil—Fly Ash Mixtures with Municipal Waste Leachate

Long term competent performance of liner systems is a critical issue in the design and construction of waste repositories due to adverse interactions associated with leachate generated by wastes. This study was conducted to verify the efficacy of fly ash stabilization in enhancing compatibility between lateritic soil and municipal waste leachate. Applications investigated include soil mixtures containing 0, 5, 10, 15, and 20% fly ash compacted at approximately 2% wet of optimum moisture content with modified proctor energy. Baseline hydraulic conductivity was first established at every level of fly ash content by permeating soil mixtures with tap water before permeation with leachate in a compaction mould permeameter using the falling head test method. Results show that the trend in hydraulic conductivity of specimen containing 0% fly ash was characterized by a gradual but erratic decrease which may suggests partial entry of the leachate cations into the double layer. Conversely, specimens containing fly ash showed a general trend consisting of an initial drop in k (up to an order of magnitude) that was followed by slight decrease sustained until k stabilized and later terminated. Above 10% fly ash content, the relatively high values of k observed was not connected with the reactivity of the soil mixtures with leachate, rather it may be attributed to excessive fly ash content that altered their textural and hydraulic properties. The result of this study is potentially significant in the assessment of fly ash as a compatibility enhancing agent which can be admixed in barrier materials that are susceptible to adverse reactions with the liquid to be contained.     

Application of a square wave potentiometry technique for electroreductive sulfur removal from a thiophenic model fuel

Thiophene-containing solutions were electroreductively desulfurized by a dynamic method. Initially, cyclic voltammetry was utilized to study thiophene electroadsorption from aqueous solution onto a platinum electrode surface and also to investigate the thiophene electroreductive behavior. Then, the solution was desulfurized via a square wave potentiometry method. The objective of this study was to find the optimal conditions. In this regard, the best adsorption potential, electroreduction potential, and square wave frequency were found to be ?0.54 V, ?0.95 V, and 1 Hz, respectively. Finally, a model fuel (containing 294 part per millions thiophene) was desulfurized by the square wave potentiometry method. Gas chromatography and Fourier transform infrared spectroscopy were used to examine the feed and product solutions. Gas chromatographic measurements revealed that sulfur content decreased to 55 part per millions. Based on the acquired results, electroreductive desulfurization could be designated as an efficient superseded for the commercial hydrodesulfurization process. However, more studies must perform to overcome technical limitations of electroreductive desulfurization technique and to guarantee its reliability.     

Pb isotope composition of granitoids from the Hercynides of the Central Asian orogenic Belt: Evidence for growth of the juvenile crust

Based on study of the Middle Paleozoic (Hercynian) structures of the Central Asian Fold Belt located in Southwest Mongolia, the problem of the sources of juvenile crust growth registered in the Pb isotope composition of postaccretional granitoids is considered. Our study shows that the Pb isotope system of Late Paleozoic granitoids from the Hercynides of the Central Asian Fold Belt provides evidence for the juvenile nature of the continental crust in this region. The evolution of the Pb isotope composition in the Hercynides of Mongolia corresponds to the model parameter μ = 9.25, according to the Stacey–Kramers twostage model. The juvenile source of the Hercynian crust should be characterized by a lower μ value. In addition, according to the Stacey–Kramers two-stage model, the Th/U value in this crust is 3.58.     

Long-Term Changes in the Extreme Significant Wave Heights on the Western North Pacific: Impacts of Tropical Cyclone Activity and ENSO

Seasonal extreme wave statistics were reproduced by using the 25-km-grid global wave model of WAVEWATCH-III. The results showed that the simulated wave dataset for the present climate (1979-2009) was similar to Climate Forecast System Reanalysis (CFSR) wave data. Statistics such as the root mean squared error (RMSE) and correlation coefficient (CC) over the western North Pacific (WNP) basin were 0.5 m and 0.69 over the analysis domain. The largest trends and standard deviation were around the southern coast of Japan and western edge of the WNP. Linear regression analysis was employed to identify the relationship between the leading principal components (PCs) of significant wave heights (SWHs) in the peak season of July to September and sea surface temperature (SST) anomalies in the equatorial Pacific. The results indicated that the inter-annual variability of SWH can be associated with the El Niño-Southern Oscillation in the peak season. The CC between the first PC of the SWH and anomalies in the Nino 3.4 SST index was also significant at a 99% confidence level. Significant variations in the SWH are affected by tropical cyclones (TCs) caused by increased SST anomalies. The genesis and development of simulated TCs can be important to the variation in SWHs for the WNP in the peak season. Therefore, we can project the variability of SWHs through TC activity based on changes in SST conditions for the equatorial Pacific in the future.     

湘江中下游农田土壤和蔬菜的重金属污染

A total of 219 agricultural soil and 48 vegetable samples were collected from the midstream and downstream of the Xiangjiang River（the Hengyang-Changsha section）in Hunan Province.The accumulation characteristics,spatial distribution and potential risk of heavy metals in the agricultural soils and vegetables were depicted.There are higher accumulations of heavy metals such as As,Cd,Cu,Ni,Pb and Zn in agricultural soils,and the contents of Cd（2.44 mg kg^-1 ）,Pb（65.00 mg kg^-1 ）and Zn（144.13 mg kg^-1 ）are 7.97,3.69 and 1.63 times the corresponding background contents in soils of Hunan Province,respectively. 13.2%of As,68.5%of Cd,2.7%of Cu,2.7%of Ni,8.7%of Pb and 15.1%of Zn in soil samples from the investigated sites exceeded the maximum allowable heavy metal contents in the China Environmental Quality Standard for Soils（GB15618-1995,Grade Ⅱ）.The pollution characteristics of multi-metals in soils are mainly due to Cd.The contents of As,Cd,Cu,Pb and Zn in vegetable soils are significantly higher than the contents in paddy soils.95.8%, 68.8%,10.4%and 95.8%of vegetable samples exceeded the Maximum Levels of Contaminants in Foods（GB2762-2005）for As,Cd,Ni and Pb concentrations,respectively.There are significantly positive correlations between the concentrations of Cd,Pb and Zn in vegetables and the concentrations in the corresponding vegetable soils（p〈0.01）.It is very necessary to focus on the potential risk of heavy metals for food safety and human health in agricultural soils and vegetables in the midstream and downstream of the Xiangjiang River,Hunan Province of China.     

Spatial distribution of solar flares in 23rd solar cycle

H-alpha flares accompanied by the X-radiation f ?? 10^?6 wm^?2 in power are examined; 2331 flares were registered during the first half of the 23rd solar cycle (1997?C2000). The specific power of the X-radiation of the flares monotonically doubles from the minimum to the maximum of the sunspot. An increase in the number of flares in each solar rotation is nonmonotonic and disproportional to the relative number of sunspots. Several longitudinal intervals with increased flare activity can be distinguished in the entire time interval of five to ten rotations. The longitudinal distributions of flares and boundaries of the sector structures of a large-scale magnetic field differ considerably. This confirms the existence of two types of zero lines; the first type is determined by active regions, and the second one is determined by large-scale structures with weak magnetic fields. The flares concentrate near Hale??s zero lines of the first type.     

The assessment of landslide susceptibility mapping using random forest and decision tree methods in the Three Gorges Reservoir area,China

Landslide susceptibility mapping is an indispensable prerequisite for landslide prevention and reduction. At present, research into landslide susceptibility mapping has begun to combine machine learning with remote sensing and geographic information system (GIS) techniques. The random forest model is a new integrated classification method, but its application to landslide susceptibility mapping remains limited. Landslides represent a serious threat to the lives and property of people living in the Zigui–Badong area in the Three Gorges region of China, as well as to the operation of the Three Gorges Reservoir. However, the geological structure of this region is complex, involving steep mountains and deep valleys. The purpose of the current study is to produce a landslide susceptibility map of the Zigui–Badong area using a random forest model, multisource data, GIS, and remote sensing data. In total, 300 pre-existing landslide locations were obtained from a landslide inventory map. These landslides were identified using visual interpretation of high-resolution remote sensing images, topographic and geologic data, and extensive field surveys. The occurrence of landslides is closely related to a series of environmental parameters. Topographic, geologic, Landsat-8 image, raining data, and seismic data were used as the primary data sources to extract the geo-environmental factors influencing landslides. Thirty-four layers of causative factors were prepared as predictor variables, which can mainly be categorized as topographic, geological, hydrological, land cover, and environmental trigger parameters. The random forest method is an ensemble classification technique that extends diversity among the classification trees by resampling the data with replacement and randomly changing the predictive variable sets during the different tree induction processes. A random forest model was adopted to calculate the quantitative relationships between the landslide-conditioning factors and the landslide inventory map and then generate a landslide susceptibility map. The analytical results were compared with known landslide locations in terms of area under the receiver operating characteristic curve. The random forest model has an area ratio of 86.10%. In contrast to the random forest (whole factors, WF), random forest (12 major factors, 12F), decision tree (WF), decision tree (12F), the final result shows that random forest (12F) has a higher prediction accuracy. Meanwhile, the random forest models have higher prediction accuracy than the decision tree model. Subsequently, the landslide susceptibility map was classified into five classes (very low, low, moderate, high, and very high). The results demonstrate that the random forest model achieved a reasonable accuracy in landslide susceptibility mapping. The landslide hazard zone information will be useful for general development planning and landslide risk management.     

Impact of satellite observed microwave SST on the simulation of tropical cyclones

The impact of realistic representation of sea surface temperature (SST) on the numerical simulation of track and intensity of tropical cyclones formed over the north Indian Ocean is studied using the Weather Research and Forecast (WRF) model. We have selected two intense tropical cyclones formed over the Bay of Bengal for studying the SST impact. Two different sets of SSTs were used in this study: one from TRMM Microwave Imager (TMI) satellite and other is the weekly averaged Reynold’s SST analysis from National Center for Environmental Prediction (NCEP). WRF simulations were conducted using the Reynold’s and TMI SST as model boundary condition for the two cyclone cases selected. The TMI SST which has a better temporal and spatial resolution showed sharper gradient when compared to the Reynold’s SST. The use of TMI SST improved the WRF cyclone intensity prediction when compared to that using Reynold’s SST for both the cases studied. The improvements in intensity were mainly due to the improved prediction of surface latent and sensible heat fluxes. The use of TMI SST in place of Reynold’s SST improved cyclone track prediction for Orissa super cyclone but slightly degraded track prediction for cyclone Mala. The present modeling study supports the well established notion that the horizontal SST gradient is one of the major driving forces for the intensification and movement of tropical cyclones over the Indian Ocean.     

Analysis of decade-long time series of GPS-based polar motion estimates at 15-min temporal resolution

We present results from the generation of 10-year-long continuous time series of the Earth’s polar motion at 15-min temporal resolution using Global Positioning System ground data. From our results, we infer an overall noise level in our high-rate polar motion time series of 60 \(\upmu \hbox {as}\) (RMS). However, a spectral decomposition of our estimates indicates a noise floor of 4 \(\upmu \hbox {as}\) at periods shorter than 2 days, which enables recovery of diurnal and semidiurnal tidally induced polar motion. We deliberately place no constraints on retrograde diurnal polar motion despite its inherent ambiguity with long-period nutation. With this approach, we are able to resolve damped manifestations of the effects of the diurnal ocean tides on retrograde polar motion. As such, our approach is at least capable of discriminating between a historical background nutation model that excludes the effects of the diurnal ocean tides and modern models that include those effects. To assess the quality of our polar motion solution outside of the retrograde diurnal frequency band, we focus on its capability to recover tidally driven and non-tidal variations manifesting at the ultra-rapid (intra-daily) and rapid (characterized by periods ranging from 2 to 20 days) periods. We find that our best estimates of diurnal and semidiurnal tidally induced polar motion result from an approach that adopts, at the observation level, a reasonable background model of these effects. We also demonstrate that our high-rate polar motion estimates yield similar results to daily-resolved polar motion estimates, and therefore do not compromise the ability to resolve polar motion at periods of 2–20 days.