Mineralized Microbiota: A Possible Indicator of Hydrocarbon Flows in the Rift Zone of Iceland

Relationships of mineralized microbiota with the content of polycyclic aromatic hydrocarbons in hydrothermal systems are considered. It has been established that the mineralized microbiota can serve as an indicator of hydrothermal hydrocarbon flows in present-day and ancient deposits.     

Reliability based risk index for the design of reinforced earth structures

The design methods currently used for earth reinforcement are mostly based on deterministic properties of both the soil and the construction materials used. Nowadays, however, the general trend is designing at a specific degree of reliability. This is even more true where the raw data such as soil properties exhibit significant variation. Deterministic solutions, in this case, may not suffice. Therefore, this paper will attempt to use probabilistic formulations thereby modifying the existing design procedure of reinforced earth retaining walls to account for uncertainties and variabilities. Through a first order Taylor's series expansion about the mean, the mean and variance of the strip reinforcing components, namely width and length, are derived in terms of the variations in the soil properties. Design charts that enable estimation of both mean and variance are developed to avoid extensive partial differentiation involved in the computations. Using appropriate probability distributions along with the mean and variance, the final design outputs are determined for a selected failure probability by introducing what is refered to as 'risk index'. The results indicate that the risk index increases with an increase in the coefficient of variations and a decrease in failure probability. Furthermore, it is shown that in some cases, depending on the variabilities of the soil properties, the classical design technique produced a relatively high failure probability. This revised version was published online in July 2006 with corrections to the Cover Date.     

Smoothing and Change Point Detection for Gamma Ray Count Data

Gamma ray detectors are used to measure the natural radioactivity of rocks. For a number of boreholes drilled at a site the gamma ray detector is lowered into each borehole and counts of gamma ray emissions at different depths are recorded as the instrument is gradually raised to ground level. The profile of gamma counts can be informative about the geology at each location. The raw count data are highly variable, and in this paper we describe the use of adaptive smoothing techniques and change point models in order to identify changes in the geology based on the gamma logs. We formulate all our models for the data in the framework of the class of generalized linear models, and describe computational methods for Bayesian inference and model selection for generalized linear models that improve on existing techniques. Application is made to gamma ray data from the Castelreagh Waste Management Centre which served as a hazardous waste disposal facility for the Sydney region between March 1974 and August 1998. Understanding the geological structure of this site is important for further modelling the transport of pollutants beneath the waste disposal area.     

Geochemistry of the Early Jurassic Messejana-Plasencia dyke (Portugal-Spain); Implications on the Origin of the Central Atlantic Magmatic Province

The Messejana–Plasencia dyke (MPD) is one of the largestdoleritic dykes of the so-called Central Atlantic Magmatic Province(CAMP). Emplaced at     

Contrasting metamorphic evolution of metasedimentary rocks from the Çine and Selimiye nappes in the Anatolide belt, western Turkey

Abstract P–T conditions, mineral isograds, the relation of the latter to foliation planes and kinematic indicators are used to elucidate the tectonic nature and evolution of a shear zone in an orogen exhumed from mid‐crustal depths in western Turkey. Furthermore, we discuss whether simple monometamorphic fabrics of rock units from different nappes result from one single orogeny or are related to different orogenies. Metasedimentary rocks from the Çine and Selimiye nappes at the southern rim of the Anatolide belt of western Turkey record different metamorphic evolutions. The Eocene Selimiye shear zone separates both nappes. Metasedimentary rocks from the Çine nappe underneath the Selimiye shear zone record maximum P–T conditions of about 7 kbar and >550 °C. Metasedimentary rocks from the overlying Selimiye nappe have maximum P–T conditions of 4 kbar and c. 525 °C near the base of the nappe. Kinematic indicators in both nappes are related to movement on the Selimiye shear zone and consistently show a top‐S shear sense. Metamorphic grade in the Selimiye nappe decreases structurally upwards as indicated by mineral isograds defining the garnet‐chlorite zone at the base, the chloritoid‐biotite zone and the biotite‐chlorite zone at the top of the nappe. The mineral isograds in the Selimiye nappe run parallel to the regional S_R foliation, parallel the Selimiye shear zone and indicate that the Selimiye shear zone formed during this prograde greenschist to lower amphibolite facies metamorphic event but remained active after the peak of metamorphism. ⁴⁰Ar/³⁹Ar mica ages and the tectonometamorphic relationship with the Eocene Cyclades–Menderes thrust, which occurs above the Selimiye nappe in the study area, suggests an Eocene age of metamorphism in the Selimiye nappe. Metasedimentary rocks of the Çine nappe 20–30 km north of the Selimiye shear zone record maximum P–T conditions of 8–11 kbar and 600–650 °C. An age of about 550 Ma is indicated for amphibolite facies metamorphism and associated top‐N shear in the orthogneiss of the Çine nappe. Our study shows that simple monophase tectonometamorphic fabrics do not always indicate a simple orogenic development of a nappe stack. Preservation in some areas and complete overprinting of those fabrics in other areas apparently occur very heterogeneously.     

Metamorphic petrology and zircon geochronology of high-grade rocks from the central Mozambique Belt of Tanzania: crustal recycling of Archean and Palaeoproterozoic material during the Pan-African orogeny

New data on the metamorphic petrology and zircon geochronology of high‐grade rocks in the central Mozambique Belt (MB) of Tanzania show that this part of the orogen consists of Archean and Palaeoproterozoic material that was structurally reworked during the Pan‐African event. The metamorphic rocks are characterized by a clockwise P–T path, followed by strong decompression, and the time of peak granulite facies metamorphism is similar to other granulite terranes in Tanzania. The predominant rock types are mafic to intermediate granulites, migmatites, granitoid orthogneisses and kyanite/sillimanite‐bearing metapelites. The meta‐granitoid rocks are of calc‐alkaline composition, range in age from late Archean to Neoproterozoic, and their protoliths were probably derived from magmatic arcs during collisional processes. Mafic to intermediate granulites consist of the mineral assemblage garnet–clinopyroxene–plagioclase–quartz–biotite–amphibole ± K‐feldspar ± orthopyroxene ± oxides. Metapelites are composed of garnet‐biotite‐plagioclase ± K‐feldspar ± kyanite/sillimanite ± oxides. Estimated values for peak granulite facies metamorphism are 12–13 kbar and 750–800 °C. Pressures of 5–8 kbar and temperatures of 550–700 °C characterize subsequent retrogression to amphibolite facies conditions. Evidence for a clockwise P–T path is provided by late growth of sillimanite after kyanite in metapelites. Zircon ages indicate that most of the central part of the MB in Tanzania consists of reworked ancient crust as shown by Archean (c. 2970–2500 Ma) and Palaeoproterozoic (c. 2124–1837 Ma) protolith ages. Metamorphic zircon from metapelites and granitoid orthogneisses yielded ages of c. 640 Ma which are considered to date peak regional granulite facies metamorphism during the Pan‐African orogenic event. However, the available zircon ages for the entire MB in East Africa and Madagascar also document that peak metamorphic conditions were reached at different times in different places. Large parts of the MB in central Tanzania consist of Archean and Palaeoproterozoic material that was reworked during the Pan‐African event and that may have been part of the Tanzania Craton and Usagaran domain farther to the west.     

Deformation at Stromboli volcano (Italy) revealed by rock mechanics and structural geology

We approach the reconstruction of the recent structural evolution of Stromboli volcano (Italy) and the analysis of the interplay between tectonics, gravity and volcanic deformation. By tying together structural, lithostratigraphic and rock mechanics data, we establish that since 100 ka BP, the edifice has faulted and jointed mainly along NE-striking planes. Faults mostly dip to the NW with normal displacement. Taking also into account the presence of a NW-trending regional least principal stress and of tectonic earthquake hypocenters inside the cone, we suggest that this fracturing can be related to the transmission of tectonic forces from the basement to the cone. Dyking concentrated along a main NE-trending weakness zone (NEZ) across the volcano summit, resembling a volcanic rift, whose geometry is governed by the tectonic field. In the past 13 ka, Stromboli experienced a reorganisation of the strain field, which was linked with the development of four sector collapses affecting the NW flank, alternating with growth phases. The tectonic strain field interplayed with dyking and fracturing related to unbuttressing along the collapse shoulders. We propose that tectonics control the geometry of dykes inside the cone and that these, in turn, contribute to destabilise the cone flanks.     

Palaeomagnetic results from the ca. 1130 Ma Borgmassivet intrusions in the Ahlmannryggen region of Dronning Maud Land, Antarctica, and tectonic implications

Detailed palaeomagnetic and rock magnetic analyses provide improved palaeomagnetic results from 23 sites in the Borgmassivet intrusions in the Ahlmannryggen region of Dronning Maud Land, East Antarctica. These intrusions are of similar age to their host, the ca. 1130 Ma Ritscherflya Supergroup (RSG). A mean direction of D=235.4°, I=−7.6° with k=45.9 and α₉₅=4.5° was obtained from this study. When combined with previously reported results from 11 sites in the same region, including sites from the Ritscherflya Supergroup, it gives an overall mean direction for 34 sites from the igneous suite with D=236.5°, I=−3.6°, k=27.9 and α₉₅=4.8°. Isothermal remanent magnetization (IRM) experiments on several specimens suggest magnetite or titanomagnetite as the primary remanence carrier, while high temperature magnetic susceptibility experiments indicate the presence of single domain particles. These observations, together with field evidence and the high coercivities and unblocking temperatures, support a primary origin for the observed characteristic remanence. The Borgmassivet palaeomagnetic pole lies at 54.5°E, 8.3°N with A₉₅=3.3°. If Antarctica is moved to its Gondwanan position adjacent to southeast Africa, the Borgmassivet pole (BM) coincides with that of the African well-established, well-dated (1100 Ma) Umkondo Large Igneous Province pole, supporting the hypothesis that the Grunehogna craton of Dronning Maud Land was part of the Kalahari craton of southern Africa at ca. 1100 Ma.     

From geometry to dynamics of microstructure: using boundary lengths to quantify boundary misorientations and anisotropy

The microstructure of a quartzite experimentally deformed and partially recrystallised at 900 °C, 1.2 GPa confining pressure and strain rate 10⁻⁶/s was investigated using orientation contrast and electron backscatter diffraction (EBSD). Boundaries between misoriented domains (grains or subgrains) were determined by image analysis of orientation contrast images. In each domain, EBSD measurements gave the complete quartz lattice orientation and enabled calculation of misorientation angles across every domain boundary. Results are analysed in terms of the boundary density, which for any range of misorientations is the boundary length for that range divided by image area. This allows a more direct comparison of misorientation statistics between different parts of a sample than does a treatment in terms of boundary number.The strain in the quartzite sample is heterogeneous. A 100×150 μm low-strain partially recrystallised subarea C was compared with a high-strain completely recrystallised subarea E. The density of high-angle (>10°) boundaries in E is roughly double that in C, reflecting the greater degree of recrystallisation. Low-angle boundaries in C and E are produced by subgrain rotation. In the low-angle range 0–10° boundary densities in both C and E show an exponential decrease with increasing misorientation. The densities scale with exp(−θ/λ) where λ is approximately 2° in C and 1° in E; in other words, E has a comparative dearth of boundaries in the 8–10° range. We explain this dearth in terms of mobile high-angle boundaries sweeping through and consuming low-angle boundaries as the latter increase misorientation through time. In E, the density of high-angle boundaries is larger than in C, so this sweeping would have been more efficient and could explain the relative paucity of 8–10° boundaries.The boundary density can be generalised to a directional property that gives the degree of anisotropy of the boundary network and its preferred orientation. Despite the imposed strain, the analysed samples show that boundaries are not, on average, strongly aligned. This is a function of the strong sinuosity of high-angle boundaries, caused by grain boundary migration. Low-angle boundaries might be expected, on average, to be aligned in relation to imposed strain but this is not found.Boundary densities and their generalisation in terms of directional properties provide objective measures of microstructure. In this study the patterns they show are interpreted in terms of combined subgrain rotation and migration recrystallisation, but it may be that other microstructural processes give distinctive patterns when analysed in this fashion.