Color-change processes of a plinian pumice and experimental constraints of color-change kinetics in air of an obsidian

Colors of plinian pumices were measured by spectrocolorimetry, and their quantitative color parameters in the L*a*b* color space were determined. A series of heating experiments of obsidian was conducted to simulate the color-change processes of rhyolitic glasses. In these experiments, following three stages of color-change processes were observed. Stage I showed a rapid b* (yellowishness) increase associated with fast dehydration controlled by water diffusivity (D _water). In stage II, a* (reddishness) increase was accompanied by Fe²⁺ decrease. Both a* increase and Fe²⁺ decrease can be simulated by a diffusion model. Obtained diffusivity D _oxidation were about two orders of magnitude smaller than D _water . The a*-value increase after the oxidation in stage III appeared to be quasi-linear with time, indicating the zeroth order reaction corresponding to the formation of hematite-like structures in rhyolitic glasses. The diffusion-limited a* increase model in stage II was applied to a natural plinian pumice fall unit to evaluate time periods of color-change processes through oxidation by air of fragmented rhyolitic materials.     

Simultaneous Analysis of Natural Free Estrogens and Their Conjugates in Wastewater by GC‐MS

A solid‐phase extraction (SPE)‐gas chromatography (GC)‐mass spectrometry (MS) analytical method was developed for the simultaneous analysis of natural free estrogens and their conjugates in wastewater samples. Natural free estrogens and their conjugates in wastewater were successfully separated by the oasis hydrophilic‐lipophilic balance solid phase extraction (Oasis HLB SPE) method, and the conjugates were initially enzyme hydrolyzed by β‐glucuronidase or arylsulfatase from Helix pomatia prior to derivatization. N‐methyl‐N‐(tert‐butyldimethylsilyl)trifluoroacetamide (MTBSTFA) plus 1% tert‐butyldimetheylchlorosilane (TBDMCS) was chosen as the derivatization reagent, and the most appropriate conditions of derivatization were determined to be at 95°C for 90 min. The recovery ratios of nine target chemicals were determined by spiking them in 1 L of ultra‐purified water or the influent of a wastewater treatment plant (WWTP). The recovery ratios of six out of nine for the analytes ranged from 73.3–114.9% with relative standard deviations (RSD) from 1.6–19.9%. The established method was successfully applied to environmental wastewater samples which were collected from one municipal wastewater treatment plant (WWTP) in Osaka, Japan, for the determination of natural free estrogens and their conjugates. In the influent sample, E1, E2, E1‐3S, E3‐3S, and E1‐3G were detected at concentrations of 16.6, 9.6, 8.2, 21.9, and 3.2 ng L^–1, respectively. However, only E1 was detected at a high concentration of 44 ng L^–1 in the effluent sample, suggesting that it is the dominant natural free estrogen in the effluent.     

A method for tsunami risk assessment: a case study for Kamakura,Japan

This paper presents a methodology for tsunami risk assessment, which was applied to a case study in Kamakura, Japan. This methodology was developed in order to evaluate the effectiveness of a risk-reducing system against such hazards, also aiming to demonstrate that a risk assessment is possible for these episodic events. The tsunami risk assessment follows these general steps: (1) determination of the probability of flooding, (2) calculation of flood scenarios, (3) assessment of the consequences and (4) integration into a risk number or graph. The probability of flooding was approximated based on the data provided by local institutes, and the flood scenarios were modeled in 1D using the Simulating WAves till SHore model. Results showed that a tsunami in Kamakura can result in thousands of casualties. Interventions such as improvements in evacuation systems, which would directly reduce the number of casualties, would have a large influence in risk reduction. Although this method has its limits and constraints, it illustrates the value it can add to existing tsunami risk management in Japan.     

Effect of seismic retrofit of bridges on transportation networks

The objective of this research is to determine the effect earthquakes have on the performance of transportation network systems. To do this, bridge fragility curves, expressed as a function of peak ground acceleration (PGA) and peak ground velocity (PGV), were developed. Network damage was evaluated under the 1994 Northridge earthquake and scenario earthquakes. A probabilistic model was developed to determine the effect of repair of bridge damage on the improvement of the network performance as days passed after the event. As an example, the system performance degradation measured in terms of an index, “Drivers Delay,“ is calculated for the Los Angeles area transportation system, and losses due to Drivers Delay with and without retrofit were estimated.     

Compact Two-Dimensional Array of Stressed GE:GA Detectors

We have developed a 4 × 8 array of stressed Ge:Ga detectors. This array detector has a high density format ofentrance pupils so that we can minimize the size of the cameraoptics. The cutoff wavelength of the detector is about 170 m, and the detector's NEP is better than 10¹⁶ WHz^-1/2. We are going apply this array detector toballoon-borne astronomical observations. Furthermore, we aredeveloping this detector into a 5 × 15 array detector that will be placed onboard the IRIS satellite to be launched in 2003.     

Development of a global flood risk index based on natural and socio-economic factors

Abstract

A global flood risk index (FRI) is established, based on both natural and social factors. The advanced flood risk index (AFRI) is the expectation of damage in the case of a single flood occurrence, estimated by a linear regression-based approach as a function of hazard and vulnerability metrics. The resulting equations are used to predict potential flood damage given gridded global data for independent variables. It is new in the aspect that it targets floods by units of events, instead of a long-term trend. Moreover, the value of the AFRI is that it can express relative potential flood risk with the process of flood damage occurrence considered. The significance of this study is that not only the hazard parameters which contribute directly to flood occurrence, but vulnerability parameters which reflect the conditions of the region where flood occurred, including its residential and social characteristics, were shown quantitatively to affect flood damage.

Citation Okazawa, Y., Yeh, P., Kanae, S. & Oki, T. (2011) Development of a global flood risk index based on natural and socioeconomic factors. Hydrol. Sci. J. 56(5), 789–804.     

Experimental constraints on permeable gas transport in crystalline silicic magmas

The gas and fluid transport in magmas via permeable flow through interconnected bubble networks controls the rate of outgassing from magmas ascending in volcanic conduits and the fluid transport in the mushy boundary layer of magma reservoirs. Hence, clarifying its mechanism and rate is crucial to understanding the explosivity of volcanic eruptions and the evolution and dynamics of a magma reservoir. Recent experimental studies have determined the gas permeabilities in crystal-free rhyolite and basalt. However, no experimental study has investigated the effect of the crystal contents on the permeable gas transport in magmas. In this study, we performed decompression experiments for hydrous rhyolitic melts having crystallinities of 30 and 50 vol% to examine the effect of crystals on the bubble microstructure and gas permeability during magma vesiculation. Size-controlled (100-meshed) corundum crystals were used as an analog of the phenocrysts in silicic magmas. Microstructural analyses using X-ray CT showed that bubbles coalesce and their connectivity increases with a decrease in the final pressure after the decompression, that is, an increase in the vesicularity. As long as the vesicularities of melt part in the crystal-free basis (melt vesicularity) were similar, no clear effect of the crystallinity on the degree of bubble coalescence and connectivity was observed at melt vesicularities <68 vol%. The corundum showed a large contact angle with aqueous fluid as well as plagioclase and alkaline feldspar; this failed to induce the efficient heterogeneous nucleation and coalescence of bubbles on its surface. The gas permeabilities of all the run products were lower than the detection limits of the present analysis (the order of 10⁻¹⁶ m²) at melt vesicularities <68 vol%. These results show that silicic magmas containing 30 and 50 vol% phenocrysts with a large contact angle have low gas permeabilities until the vesicularity becomes large (at least >68 vol%). This result indicates that the permeable fluid transport through a deep volcanic conduit, which has been proposed on the basis of the observations of volcanic gases and natural products, is so slow that other processes, like shear deformation or magma convection, may be needed to explain the observations.     

The Herschel PACS photometer calibration

We present a flux calibration scheme for the PACS chopped point-source photometry observing mode based on the photometry of five stellar standard sources. This mode was used for science observations only early in the mission. Later, it was only used for pointing and flux calibration measurements. Its calibration turns this type of observation into fully validated data products in the Herschel Science Archive. Systematic differences in calibration with regard to the principal photometer observation mode, the scan map, are derived and amount to 5 ? 6 %. An empirical method to calibrate out an apparent response drift during the first 300 Operational Days is presented. The relative photometric calibration accuracy (repeatability) is as good as 1 % in the blue and green band and up to 5 % in the red band. Like for the scan map mode, inconsistencies among the stellar calibration models become visible and amount to 2 % for the five standard stars used. The absolute calibration accuracy is therefore mainly limited by the model uncertainty, which is 5 % for all three bands.     

Photometric observations of 107P/Wilson-Harrington

We present lightcurve observations and multiband photometry for 107P/Wilson-Harrington using five small- and medium-sized telescopes. The lightcurve has shown a periodicity of 0.2979 day (7.15 h) and 0.0993 day (2.38 h), which has a commensurability of 3:1. The physical properties of the lightcurve indicate two models: (1) 107P/Wilson-Harrington is a tumbling object with a sidereal rotation period of 0.2979 day and a precession period of 0.0993 day. The shape has a long axis mode (LAM) of L₁:L₂:L₃ = 1.0:1.0:1.6. The direction of the total rotational angular momentum is around λ = 310°, β = −10°, or λ = 132°, β = −17°. The nutation angle is approximately constant at 65°. (2) 107P/Wilson-Harrington is not a tumbler. The sidereal rotation period is 0.2979 day. The shape is nearly spherical but slightly hexagonal with a short axis mode (SAM) of L₁:L₂:L₃ = 1.5:1.5:1.0. The pole orientation is around λ = 330°, β = −27°. In addition, the model includes the possibility of binary hosting. For both models, the sense of rotation is retrograde. Furthermore, multiband photometry indicates that the taxonomy class of 107P/Wilson-Harrington is C-type. No clear rotational color variations are confirmed on the surface.     

老年人居住迁移的地理学研究进展

20世纪70年代以来,国内外有关老年人居住迁移的地理学研究在理论化、研究方法和实证研究方面取得了较大的进展。文章按照时间顺序和研究内容的逻辑关系提出了老年人居住迁移的研究框架,回顾了欧美、日本和中国地理学界对老年人居住迁移研究的成果和进程,以期为未来中国地理学的相关研究提供借鉴。