Compressibility of the calcium aluminosilicate, CAS, phase to 44 GPa

In situ X-ray diffraction measurements on a calcium aluminosilicate (CAS) phase have been carried out using a laser-heated diamond anvil cell up to a pressure of 44 GPa, employing a synchrotron radiation source. CAS is the major mineral formed from sediments subducted into the Earth's mantle. The sample was heated using a YAG laser after each pressure increment to relax the deviatoric stress in the sample. X-ray diffraction measurements were carried out at T = 300 K using an angle-dispersive technique. The pressure was calculated using an internal platinum metal pressure calibrant. The Birch–Murnaghan equation of state for the CAS phase obtained from the experimental unit cell parameters showed a density of ρ₀ = 3.888 g/cm³ and a bulk modulus of K₀ = 229 ± 9 GPa for K^′₀ = 4.7 ± 0.7. When the first pressure derivative of the bulk modulus was fixed at K^′₀ = 4, then the value of K₀ = 239 ± 2 GPa. From the experimental compressibility, the density of the CAS phase was observed to be lower than the density of co-existing Al-bearing stishovite, calcium perovskite, calcium ferrite-type phases, and (Fe,Al)-bearing Mg-perovskite in subducted sediments in the lower mantle. Therefore, the density of subducted sediments in the lower mantle decreases with increasing mineral proportion of the CAS phase.     

Reconstructing the evolution of fault zone architecture: Field‐based study of the core region of the Atera Fault,Central Japan

In order to reconstruct the architectural evolution of a fault zone with heterogeneous structures, we studied the Atera Fault in Central Japan, and described the detailed mesoscopic and microscopic features of the zone. The fault zone studied consists of a 1.2‐m wide fault core of fault breccia mixed with fragments derived from welded tuff, granite, and mafic volcanic rocks. The 1.2‐m wide fault core is bordered by a western damage zone characterized by a welded tuff fault breccia and an eastern damage zone characterized by a granite cataclasite. A secondary fault core, a 30‐cm wide granite‐derived fault gouge, cross‐cuts the granite cataclasite. Although welded tuff fault breccia and granite cataclasite are also pervasively fractured and fragmented, the fault cores are significantly affected by fragment size reduction due to intense abrasive wear and comminution. The 1.2‐m wide fault core includes fragments and a sharp dark layer composed of mafic volcanic rocks, which can be correlated with neighboring 1.6 Ma volcanic rocks. This observation places a younger constraint on the age of the fault core formation. Carbonate coating on basalt fragments in the 1.2‐m wide fault core has also been fractured indicating the repetition of intense fragmentation. Bifurcated, black and gray veins near the 1.2‐m wide fault core are likely injection veins, formed by the rapid injection of fine material within fault zones during seismic events. The granite‐derived fault gouge, characterized by hard granite fragments without intense brecciation and microfracturing, in a kaolinite‐rich clay matrix, is interpreted as the most recent slip zone within the exposed fault zone. A preview of published geological and hydrological studies of several fault zones shows that clay‐rich fault cores can exhibit much lower permeability than the adjacent damage zones represented in this present case by the welded tuff fault breccia and granite cataclasite.     

Basin-scale distribution of NH<Subscript>4</Subscript><Superscript>+</Superscript> and NO<Subscript>2</Subscript><Superscript>−</Superscript> in the Pacific Ocean

We used more than 25,000 nutrient samples to elucidate for the first time basin-scale distributions and seasonal changes of surface ammonium (NH₄ ⁺) and nitrite (NO₂ ^?) concentrations in the Pacific Ocean. The highest NH₄ ⁺, NO₂ ^?, and nitrate (NO₃ ^?) concentrations were observed north of 40°N, in the coastal upwelling region off the coast of Mexico, and in the Tasman Sea. NH₄ ⁺ concentrations were elevated during May–October in the western subarctic North Pacific, May–December in the eastern subarctic North Pacific, and June–September in the subtropical South Pacific. NO₂ ^? concentrations were highest in winter in both hemispheres. The seasonal cycle of NH₄ ⁺ was synchronous with NO₂ ^?, NO₃ ^?, and satellite chlorophyll a concentrations in the western subtropical South Pacific, whereas it was synchronous with chlorophyll-a but out of phase with NO₂ ^? and NO₃ ^? in the subarctic regions.     

Development of a Multi-Layer Urban Canopy Model for the Analysis of Energy Consumption in a Big City: Structure of the Urban Canopy Model and its Basic Performance

A multilayer one-dimensional canopy model was developed to analyze the relationship between urban warming and the increase in energy consumption in a big city. The canopy model, which consists of one-dimensional diffusion equations with a drag force, has three major parameters: building width, distance between buildings, and vertical floor density distribution, which is the distribution of a ratio of the number of the buildings that are taller than some level to all the buildings in the area under consideration. In addition, a simplified radiative process in the canopy is introduced. Both the drag force of the buildings and the radiative process depend on the floor density distribution. The thermal characteristics of an urban canopy including the effects of anthropogenic heat are very complicated. Therefore, the focus of this research is mainly on the basic performance of an urban canopy without anthropogenic heat. First, the basic thermal characteristics of the urban canopy alone were investigated. The canopy model was then connected with a three-dimensional mesoscale meteorological model, and on-line calculations were performed for 10 and 11 August, 2002 in Tokyo, Japan. The temperature near the ground surface at the bottom of the canopy was considerably improved by the calculation with the canopy model. However, a small difference remained between the calculation and the observation for minimum temperature. Deceleration of the wind was well reproduced for the velocity at the top of the building by the calculation with the canopy model, in which the floor density distribution was considered.     

Reaction of forsterite with hydrogen molecules at high pressure and temperature

High pressure and temperature reactions of a mixture of forsterite and hydrogen molecules have been carried out using a laser heated diamond anvil cell at 9.8–13.2 GPa and ~1,000 K. In situ X-ray diffraction measurements showed no sign of decomposition or phase transitions of the forsterite under these experimental conditions, indicating that the olivine structure was maintained throughout all runs. However, a substantial expansion of the unit cell volume of the forsterite was observed for samples down to ~3 GPa upon quenching to ambient pressure at room temperature. The Raman spectroscopy measurements under pressure showed significant shifts of the Raman peaks of the Si–O vibration modes for forsterite and of the intramolecular vibration mode for H₂ molecules toward a lower frequency after heating. Additionally, no OH vibration modes were observed by Raman and FT-IR spectroscopic measurements. These lines of evidence show that the observed volume expansion in forsterite is not explained by the incorporation of hydrogen atoms as hydroxyl, but suggest the presence of hydrogen as molecules in the forsterite structure under these high pressure and temperature conditions.     

Implications for the low latitude cloud formations from solar activity and the quasi-biennial oscillation

We examined the effect of the 11-year solar cycle and quasi-biennial oscillation (QBO) on the ～27-day solar rotational period detected in tropical convective cloud activity. We analyzed the data of outgoing longwave radiation (OLR) for AD1979–2004, dividing into four different cases by the combination of high and low solar activities in terms of the 11-year variation, and easterly and westerly stratospheric winds associated with QBO. As a result, ～27-day variation has been most significantly detected in high solar activity period around the Indo-Pacific Warm Pool. Based on correlation analysis, we find that solar rotation signal can explain 10–20% of OLR variability around the tropical warm pool region during the high solar activity period. The spatial distribution has been, however, apparently different according to the phases of QBO. It is suggested that the 11-year solar cycle and stratospheric QBO have a possibility to cause large-scale oceanic dipole phenomena.     

Observed and simulated sensitivities of summertime urban surface air temperatures to anthropogenic heat in downtown areas of two Japanese Major Cities,Tokyo and Osaka

In this study, the sensitivities of surface air temperatures to anthropogenic heat (AH) were investigated in downtowns of the two Japanese major cities, Tokyo and Osaka. First, meteorological measurements were made with the simultaneous monitoring of electricity demand in a contrastive couple of a downtown commercial area (C-area) and a residential area (R-area) within each city in summer 2007. From the measurements, the areal-mean surface air temperatures were obtained as \( {\overline{T}}_{\mathrm{C}} \) and \( {\overline{T}}_{\mathrm{R}} \) for each of the C-area and R-area, respectively. Using the actual electricity demand and the estimated motor fuels consumption, their areal total was evaluated as the energy-consumption-basis AH. The estimated C-areas' AH indicated greater values up to 220 W/m² on weekdays and remarkable decrease about by half on weekends, whereas that in the R-areas showed less values of 10–20 W/m² stably. Then, \( {\overline{T}}_{\mathrm{C}}-{\overline{T}}_{\mathrm{R}} \) on calm and fine days were found to be systematically decreased from weekdays to weekends in both cities roughly indicating a proportional relationship with the reductions in the C-areas' AH on weekends. The result suggested a common afternoon sensitivity for both C-areas of around 1.0°C/100 W/m², which indicated an intensity of the AH impact on surface air temperature there. Next, to simulate the observed AH impact, the authors' CM-BEM (a multilayer urban canopy model coupled with a building energy model) was newly implemented in the mesoscale Weather Research and Forecasting (WMF) model. This new system, WRF-CM-BEM, was applied to Tokyo and almost reasonably validated from the aspects of the reproducibility of urban surface air temperature and electricity demand in the observation areas. The simulations also suggested that WRF-CM-BEM underestimated the observed air temperature sensitivity to AH in the Tokyo C-area roughly by half but still in the same order of magnitude.     

Scavenging of Insoluble Particles from the Marine Atmosphere over the Sub-Arctic North Pacific

Direct deposition measurements ofatmospheric insoluble particles over the sub-ArcticNorth Pacific indicate that the number of particles(6.4 ± 3.8) × 10⁴ cm^-2 per rain eventwas fairly constant compared with the large variationof the precipitation rate, which ranged from 0.16 to18 mm per event for 43 rain days during the period ofMarch–September (total 109 days) 1996. Thissuggests that insoluble particles larger than 0.4 min area equivalent diameter are primarilyremoved at the margin of the rainfall area by wetscavenging processes below clouds in the marineatmosphere in sub-Arctic regions. The frequency ofrain events controls the fate of the troposphericaerosols larger than sub-micrometer in diameter. Reflecting the seasonal long-range transport of Asiandust, mineral particles were dominant as insolubleparticles in the spring rains, but carbonaceousparticles were dominant in the summer rains. Theatmospheric deposition of insoluble particles could besignificant as a source of sediment particles over thesub-Arctic North Pacific.     

The stability and compressibility of MgAl2O4 high-pressure polymorphs

High-pressure and high-temperature experiments using a laser-heated diamond anvil cell (LHDAC) and synchrotron X-ray diffraction have revealed a phase transition in MgAl₂O₄. CaTi₂O₄-type MgAl₂O₄ was found to be stable at pressures between 45 and at least 117 GPa. The transition pressure of CaTi₂O₄-type phase in MgAl₂O₄ is much lower than that in the natural N-type mid-oceanic ridge basalt composition. The Birch–Murnaghan equation of state for CaTi₂O₄-type MgAl₂O₄ was determined from the experimental unit cell parameters with K ₀=219(±6) GPa, K ₀′=4(constrained value), and V ₀=238.9(±9) ų. The observed compressibility was in agreement with the theoretical compressibility calculated in a previous study. ε-MgAl₂O₄ was observed at pressures between 40 and 45 GPa, which has not been reported in natural rock compositions. The gradient (dP/dT slope) of the transition from the ε-type to CaTi₂O₄-type MgAl₂O₄ had a positive value. These results should resolve the dispute regarding the stable high-pressure phase of MgAl₂O₄, which has been reported in earlier studies using both the multi-anvil press and the diamond anvil cell.