A modified analytical method for the shipboard determination of nanomolar concentrations of orthophosphate in seawater

A method for the determination of nanomolar concentrations of orthophosphate in oligotrophic seawater developed by Liang et al. (2007) has been modified to make it fully feasible for shipboard application and for faster sample throughput with minimized sample volume. The technique is based on the flow injection method with solid phase extraction on a Sep-Pak C18 cartridge and colorimetric detector. The Schlieren effect was minimized by rinsing the cartridge sequentially with 5 mL water and 2 mL 95% ethanol solution. With three micro pumps in parallel, savings of up to 80% in amount of reagents and 25% volume of seawater samples could be achieved in comparison to the previous method. Variation of stopped flow time and sample loading time gave 3 different standard curves, which corresponded to 3 linear ranges within 3.4 and 515 nM. The modified method permits the analysis of samples over a wide range of concentrations, and has been successfully applied to shipboard determination of trace orthophosphate in more than 200 seawater samples during a one-month cruise in the South China Sea. For seawater at concentrations of 20.6, 82.5, 206.2 nM orthophosphate, the relative standard deviations (RSD) (n = 6), determined daily for 6 days on board ship were 4.45%, 4.73% and 6.75%, respectively. Five seawater samples collected in the Station SEATS (South East Asia Time Series Station at 18°N, 116°E) were analyzed using the present method both on board and in a land-based laboratory, as well as with the magnesium hydroxide-induced coprecipitation (MAGIC) method, and showed no significant difference according to the statistical t-test.     

抽水和建筑荷载双重作用下的地面沉降模型

依据含水层质量守恒原理,推导了非固结地层在建筑荷载作用下的地面沉降机理模型,并将其与Jacob假定下抽水引起的地面沉降弹性模型相比较,结果发现两种模型的机理表达式完全一致,仅区别于水动力原因或实质的不同.在同一坐标系中,根据线性叠加原理,抽水沉降漏斗和荷载沉降漏斗可能都落在地下水位降落漏斗内.假定两者为相互独立事件,给出了抽水和建筑荷载双重作用下的地面沉降模型,表明其如果以水位降深为制约因子,则可以对水动力实质完全不同的两种沉降过程进行线性叠加计算.     

基于数字高程模型不规则三角网的土方计算方法的实现

本文介绍一种基于数字高程模型(DEM)不规则三角网的土方量计算方法,其利用地形碎部点快速、方便的构建三维实体模型,计算土方精度高.     

JSCORS RTK GPS技术在土方测量中的应用

本文介绍了当今城市GPS应用的发展热点CORS系统的优势,并结合实例介绍了JSCORS RTK技术在某土方测量项目中的应用情况、作业流程,分析了测量时应该注意的问题。     

社区生活圈公共服务设施配置的空间分异分析——以大连市沙河口区为例

城市公共服务设施的配置水平直接影响到居民的生活品质。论文基于高德地图获取的地图数据,使用城市网络分析工具(Urban Network Analysis Toolbox, UNA)对大连市沙河口区内的6类公共服务设施分布进行空间分异分析,并对区内90个社区的居民出行可达设施的数量及类别进行测度,最后对各个社区进行总体评价。结果表明：① 大连市沙河口区公共服务设施空间分布不均,北多南少,呈现出“一主多次”的“廾”字形的结构,主要分布在西安路商业区周边和各个街道的次级商业区;② 居民可达设施数量空间差异大,北多南少,各街道均有1或2个区域可达设施数量较多;③ 居民可达设施类型数量存在一定差异,70%以上的住宅楼中的居民可以获得全部6类公共服务设施;④ 各社区居民可达设施总体处于差异较小的均衡状态,但仍有个别社区存在内部差异较大的现象。设施的分布、地物的阻隔和社区的封闭程度对居民获取各类公共服务设施影响较大,建议构建“设施完善、便捷可达”的15 min社区生活圈。     

广西森林转型与森林扰动遥感监测研究

近20年来由于封山育林政策的实施和人工乔木林的大面积种植,广西森林面积大幅增加,正在经历深刻的森林转型,森林转型过程中农林交错带和森林内部的结构重组都给生态系统带来了不容忽视的扰动。本文基于2000—2016年MODIS-EVI影像数据、1∶100万地貌图和4期土地利用数据,采用变化矢量法和Sen+Mann-Kendall对广西进行森林转型背景下的森林转型路径和森林内部扰动特征分析。研究表明:自2000年以来广西森林的EVI变化强度以无变化和低变化类型为主,总体EVI上升趋势略大于下降趋势,EVI显著下降主要分布于十万大山、大瑶山、海洋山和越城岭等山地区域和桂西北的百色水利枢纽和龙滩水利枢纽周围,显著上升部分主要集中于桂中南的左江-邕江-郁江流域平原丘陵区、桂西南喀斯特区和桂东北山地区地势低平的河谷地带。广西森林面积增加的土地来源于耕地和草地,森林转型路径表现为"经济增长型"和"森林短缺型"两种路径并存,或者存在更为复杂的复合型路径。广西森林内部扰动的减少型和扰动型分布于桂西北喀斯特和桂东北山地起伏度较大的陡坡区域,增加型分布于桂中南的平原丘陵地区。由于山地陡坡区域和喀斯特地区的生态敏感性,应更多关注扰动型和减少型在桂西北和桂东北地区的集中分布问题。     

Base cation concentrations in forest litter and topsoil have different responses to climate and tree species along elevational gradients

The forest litter is an essential reservoir of nutrients in forests, supplying a large part of absorbable base cations(BC) to topsoil, and facilitating plant growth within litter-soil system. To characterize elevational patterns of base cation concentrations in the forest litter and topsoil, and explore the effects of climate and tree species, we measured microclimate and collected the forest litter and topsoil(0-10 cm) samples across an elevational range of more than 2000 m(1243 ～ 3316 m a.s.l.),and analyzed the concentrations of BC in laboratory. Results showed that: 1) litter Ca concentration displayed a hump-shaped pattern along the elevational gradients, but litter K and Mg showed saddle-shaped patterns. Soil Ca concentration increased with elevation, while soil K and Mg had no significant changes. 2) Ca concentration in the forest litter under aspen(Populus davidiana) was significantly higher than that in all other species, but in topsoil, Ca concentration was higher under coniferous larch and fir(Larix chinensis and Abies fargesii). Litter K and Mg concentrations was higher under coniferous larch and fir, whereas there were nosignificant differences among tree species in the concentrations of K and Mg in topsoil. 3) Climatic factors including mean annual temperature(MAT), growing season precipitation(GSP) and non-growing season precipitation(NGSP) determined BC concentrations in the forest litter and topsoil. Soil C/N and C/P also influenced BC cycling between litter and soil. Observation along elevations within different tree species implies that above-ground tree species can redistribute below-ground cations, and this process is profoundly impacted by climate. Litter and soil Ca, K and Mg with different responses to environmental variables depend on their soluble capacity and mobile ability.     

中国老龄事业发展水平时空演化及其与经济发展水平的空间匹配

基于“积极老龄化”理论框架,从健康、参与和保障三大维度构建中国老龄事业发展水平评价指标体系。以中国大陆31个省（自治区、直辖市）为研究对象,运用数理统计、重心和空间重叠性、空间错位分析和计量经济模型等方法,分析了2004—2016年中国老龄事业发展水平的时序变化、空间格局、错位特征及其影响机制。结果表明：① 2004—2016年,中国老龄事业发展水平整体快速增长,区域差异逐渐缩小,但区域失衡特征不容忽视。东部地区整体水平高于中部、西部及东北地区,并伴有“西部崛起,中部及东北地区塌陷”特征。东部地区呈现“两极化”现象。② 中国老龄事业基本处于低水平发展阶段,空间分布由西南-东北辐射递减模式转变为显著的“中部塌陷”式,形成一条由北向南的低值集聚带,纵贯中国中部,与区域经济发展存在错位关系。③ 负向错位区主要分布在黄河、长江中上游地区,正向错位区主要集中在东部沿海、长城以北等地区。空间错位强度存在显著的地域差异性,其中西部地区尤为显著。④ 老龄事业发展水平的动态变化是多因素交互作用的结果。经济发展水平、政府政策和行政导向及产业结构的时空分异对其产生正向影响。市场经济规模扩大和人口老龄化未对老龄事业发展起推动作用,与理论预期不符。家庭规模小型化的倒逼作用不显著。     

Spatial associations between NDVI and environmental factors in the Heihe River Basin

Journal of Geographical Sciences - The Heihe River Basin is located in the arid and semi-arid regions of Northwest China. Here, the terrestrial ecosystem is vulnerable, making it necessary to...