High-pressure phase relations in the system TiO2–ZrO2 to 12?GPa: stability of αPbO2-type srilankite solid solutions of (Ti1?x , Zr x )O2 (0?≤?x?≤?0.6)

Phase relations in the system TiO₂–ZrO₂ were examined in the pressure range of 3.5–12?GPa at 1,800?°C, using multianvil apparatus. At 1,800?°C, TiO₂ rutile transforms to αPbO₂ structure at 10?GPa, and the αPbO₂-type solid solution is stable in compositional range between TiO₂ and about (Ti_0.6, Zr_0.4)O₂ at 3.5–12?GPa. Combination of the present results with the published data at 0–3?GPa demonstrates that continuous solid solution with the αPbO₂-type structure is stable between TiO₂ and (Ti_1?x , Zr _x )O₂ (x?≈?0.6) at 0–12?GPa. This indicates that both the αPbO₂-type TiO₂ and srilankite Ti₂ZrO₆ with the same structure belong to the continuous solid solution system though the two phases have been regarded as different minerals. With increasing ZrO₂ content, lattice parameters of a- and c-axes of the αPbO₂-type solid solution increase, but b-axis is almost constant or slightly decreases. At higher pressure, the αPbO₂-type solid solution dissociates into two phases, αPbO₂-type phase and tetragonal zirconia. Srilankite with more TiO₂-rich composition than Ti₂ZrO₆ might be found in natural rocks derived from the deep upper mantle.     

A case study of Kelvin-Helmholtz vortices on both flanks of the Earth's magnetotail

Kelvin-Helmholtz instability (KHI) is a fundamental fluid dynamical process that develops in a velocity shear layer. It is excited on the tail-flanks of the Earth's magnetosphere where the flowing magnetosheath plasma and the stagnant magnetospheric plasma sit adjacent to each other. This instability is thought to induce vortical structures and play an important role in plasma transport there. While KHI vortices have been detected, the earlier observations were performed only on one flank at a time and questions related to dawn-dusk asymmetry were not addressed. Here, we report a case where KHI vortices grow more or less simultaneously and symmetrically on both flanks, despite all the factors that may have broken the symmetry. Yet, energy distributions of ions in and around the vortices show a remarkable dawn-dusk asymmetry. Our results thus suggest that although the initiation and development of the KHI depend primarily on the macroscopic properties of the flow, the observed enhancement of ion energy transport around the dawn side vortices may be linked to microphysical processes including wave-particle interactions. Possible coupling between macro- and micro-scales, if it is at work, suggests a role for KHI not only within the Earth's magnetosphere (e.g., magnetopause and geomagnetic tail) but also in other regions where shear flows of magnetized plasma play important roles.     

The Upper Jurassic–Lower Cretaceous of eastern Heilongjiang, northeast China: stratigraphy and regional basin history

In eastern Heilongjiang, the Upper Jurassic is marine and restricted to the Suibin and Dong’an areas, where it is characterized faunally by Callovian–Volgian (Tithonian) bivalves and florally by dinoflagellates. The Lower Cretaceous is widely distributed in eastern Heilongjiang, and characterized faunally by Berriasian–Valanginian bivalves, Barremian–Albian ammonites and Aucellina, and florally by dinoflagellates. To the west, the marine facies grade into non-marine beds. Thus, in the east, for example in the Dong’an and Dajiashan areas, near the northwestern Palaeo-Pacific, the Lower Cretaceous is marine; westward, in the Yunshan, Longzhaogou, Peide, and Zhushan areas, marine and non-marine deposits alternate, whereas further west still, e.g. in the Jixi Basin, non-marine facies are intercalated with marine beds. This regional distribution is indicative of a large, shallow embayment opening eastwards to the Palaeo-Pacific; during the Early Cretaceous successive transgressive-regressive events influenced the climate and biota of eastern Heilongjiang and northeastern China. Many of the Lower Cretaceous sections contain abundant coals, demonstrating that in this region the Early Cretaceous was an important coal-forming period. Some non-marine bivalve species are common to the Lower Cretaceous Jixi Group of eastern Heilongjiang, the Jehol Group of western Liaoning and the Transbaikalian Group of Siberia, suggesting that these groups are of comparable Early Cretaceous age.     

Expected changes in future agro-climatological conditions in Northeast Thailand and their differences between general circulation models

We have studied future changes in the atmospheric and hydrological environments in Northeast Thailand from the viewpoint of risk assessment of future cultural environments in crop fields. To obtain robust and reliable estimation for future climate, ten general circulation models under three warming scenarios, B1, A1B, and A2, were used in this study. The obtained change trends show that daily maximum air temperature and precipitation will increase by 2.6°C and 4.0%, respectively, whereas soil moisture will decrease by c.a. 1% point in volumetric water content at the end of this century under the A1B scenario. Seasonal contrasts in precipitation will intensify: precipitation increases in the rainy season and precipitation decreases in the dry season. Soil moisture will slightly decrease almost throughout the year. Despite a homogeneous increase in the air temperature over Northeast Thailand, a future decrease in soil water content will show a geographically inhomogeneous distribution: Soil will experience a relative larger decrease in wetness at a shallow depth on the Khorat plateau than in the surrounding mountainous area, reflecting vegetation cover and soil texture. The predicted increase in air temperature is relatively consistent between general circulation models. In contrast, relatively large intermodel differences in precipitation, especially in long-term trends, produce unwanted bias errors in the estimation of other hydrological elements, such as soil moisture and evaporation, and cause uncertainties in projection of the agro-climatological environment. Offline hydrological simulation with a wide precipitation range is one strategy to compensate for such uncertainties and to obtain reliable risk assessment of future cultural conditions in rainfed paddy fields in Northeast Thailand.     

An overview of decadal climate predictability in a multi-model ensemble by climate model MIROC

Decadal climate predictability is examined in hindcast experiments by a multi-model ensemble using three versions of the coupled atmosphere-ocean model MIROC. In these hindcast experiments, initial conditions are obtained from an anomaly assimilation procedure using the observed oceanic temperature and salinity with prescribed natural and anthropogenic forcings on the basis of the historical data and future emission scenarios in the Intergovernmental Panel of Climate Change. Results of the multi-model ensemble in our hindcast experiments show that predictability of surface air temperature (SAT) anomalies on decadal timescales mostly originates from externally forced variability. Although the predictable component of internally generated variability has considerably smaller SAT variance than that of externally forced variability, ocean subsurface temperature variability has predictive skills over almost a decade, particularly in the North Pacific and the North Atlantic where dominant signals associated with Pacific decadal oscillation (PDO) and the Atlantic multidecadal oscillation (AMO) are observed. Initialization enhances the predictive skills of AMO and PDO indices and slightly improves those of global mean temperature anomalies. Improvement of these predictive skills in the multi-model ensemble is higher than that in a single-model ensemble.