Recycling of Coal Fly Ash and Paper Waste to Improve Low Productive Red Soil in Okinawa,Japan

Coal fly ash (CFA) and paper waste (PW) related environmental problems and its recycling techniques have been a major challenge to society. Therefore, it is of crucial importance to develop new recycling methods for CFA and PW. This work proposes a potential new way of developing synthetic aggregates (SA) using CFA, PW, starch waste and ammonium sulfate (AS) as a granular nitrogen fertilizer medium, and their utilization as a soil amendment to improve crop production in the low productive acidic red soil of Okinawa, Japan. Three types of SA with three different nitrogen (N) percentages were produced and used to amend acidic red soil in a pot experiment for the cultivation of Komatsuna, which is also called as Japanese mustard spinach (Brassica rapa var. pervidis). SA had a low bulk density (0.58–0.62 g/cm³), high water holding capacity (0.60–0.64 kg/kg), high saturated hydraulic conductivity (2.34·10^–2 cm/s), high mean weight diameter (MWD) (4.32–4.48 mm), alkaline pH (8.58–8.61), high electrical conductivity (EC) (82.18–84.35 mS/m) and high carbon (C) content (68.71–70.07 g/kg) in comparison with the acidic red soil. The trace element concentrations of the developed SA were below the maximum pollutant concentration of individual metals for land application of sewage sludge given by the US Environmental Protection Agency. Scanning electron microscopic (SEM) studies showed the higher structural surface area of SA, where round shaped CFA particles were embedded into the fibrous PW matrix. Incorporation of SA into the acidic red soil not only enhanced soil fertility but also improved the physical and chemical properties of the soil compared to soil without SA addition. SA addition to the acidic red soil significantly increased the growth and yield parameters of Komatsuna compared to soil without SA addition.     

Multi-approach characterization of shallow-water carbonates off Minamitorishima and their depositional settings/history

Sedimentological, geochemical, and chronological analyses were carried out on 18 carbonate rock samples collected at depths of 938, 1085, and 3354 m on the western slope of Minamitorishima (Marcus Island), which is located near the western margin of the Pacific Plate. Four groups of carbonate rocks were distinguished: a mollusk-rich limestone, a coral-rich dolomite, a foraminiferal-nannofossil packstone, and a phosphatized mudstone/wackestone. The mollusk-rich limestone is characterized by the dominance of bivalves (including rudists) and gastropod shells. Strontium isotope ratios (⁸⁷Sr/⁸⁶Sr) and Mesorbitolina ex gr. texana (a large benthic foraminifer) indicate that the shallow-water carbonates were deposited during the late Aptian–early Albian (ca. 123–111 Ma). The coral-rich dolomite is characterized by abundant scleractinian corals and nongeniculate coralline algae associated with encrusting acervulinid foraminifers. The biotic composition is similar to that of the Oligocene–Pleistocene carbonates reported from other seamounts in the northwestern Pacific. Geochemical data show that the coral-rich carbonates were dolomitized at 9.5–6.8 Ma (Tortonian–Messinian) and that normal seawater was the most likely parent fluid. The foraminiferal-nannofossil packstone is a semi-consolidated foraminiferal-nannofossil ooze and was deposited during the Pleistocene (0.99–0.45 Ma). The phosphatized mudstone/wackestone is marked by the absence of macrofossils and the presence of traces of planktic foraminifers. Although its depositional age is not constrained, the Sr isotope ratios indicate that the phosphatization occurred at 33.2–28.9 Ma. After the deposition of the Cretaceous shallow-water carbonates, including the mollusk-rich limestone, Minamitorishima was drowned and its top was covered with a pelagic cap, represented by the mudstone/wackestone. The late Eocene–early Oligocene volcanism (40.2–33.2 Ma) caused episodic uplift and returned the top of Minamitorishima to a shallow-water environment. After the early Oligocene phosphatization of the pelagic cap, coral reefs flourished on the top of this island. The reef limestone was dolomitized during the Tortonian–Messinian.     

慢地震与深部不连续颤动和慢滑事件同时发生

我们对日本西南部南海俯冲板块界面过渡带发生的超低频地震进行报道。由矩震级为3.1～3.5的超低频地震引起的地震波显示其卓越长周期约为20s。超低频地震活动伴随深源低频颤动和慢滑事件同时发生,并随之移动。慢地震一直被认为会增加向上倾斜的大型逆冲地震断裂带上的应力,而这3种现象的同时发生提高了人们对慢地震的探测和特性鉴定水平。     

Nitrate pollution from agriculture in different hydrogeological zones of the regional groundwater flow system in the North China Plain

A survey of the quality of groundwater across a broad area of the North China Plain, undertaken in 1998 to 2000, indicates that nitrate pollution is a serious problem affecting the drinking water for a vast population. The use of nitrogen (N)-fertilizer in agriculture has greatly increased over the past 20 years to meet the food needs of the rapidly expanding population. During the study, 295 water samples were collected from wells and springs to determine the water chemistry and the extent of nitrate pollution. High concentrations of nitrate, especially in a recharge area along the western side, but also in the vicinity of Beijing and locally in other parts of the plain, pose a serious problem for the drinking water supply. In places, the nitrate concentration exceeds the maximum for safe drinking water of 45 mg/L. The intense use of N-fertilizer and the widespread use of untreated groundwater for crop irrigation contribute greatly to the problem, but no doubt the disposal of industrial and municipal waste into streams and infiltrating the aquifer also contribute to the problem; however, the lack of data prevents evaluation of those sources. In the recharge area, nitrate is found at depths of as much as 50 m. Near Beijing, relatively high concentrations of nitrate occur at depths of as much as 80 m. In the discharge area, in the vicinity of the Yellow River, high concentrations of nitrate occur at depths of <8 m.

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Electronic Supplementary Material Supplementary Material is available in the online version of this article at

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Resumen Contaminacíon de nitratos a causa de prácticas agrícolas en diferentes zonas hidrogeológicas del sistema de flujo regional de aguas subterráneas en la planice del norte de China. Un estudio de la calidad del agua subterránea en una zona amplia de la planice del norte de China se llevó a cabo entre 1998 y el año 2000. Este estudio indica que la contaminación de nitratos es un problema grave que afecta el agua potable de una vasta población. El uso de fertilizantes a base de nitratos en la agricultura ha aumentado considerablemente durante los últimos 20 años para satisfacer las necesidades alimentices de la creciente población. Durante el estudio, se tomaron 295 muestras de pozos de agua y manantiales para determinar la química de las aguas y el grado de contaminación por nitratos. Altas concentraciones de nitratos, especialmente en una zona de recarga a lo largo del lado oeste, asì como en la cercanía a Pekín y en zonas locales en otras partes de la planicie, presentan un problema serio al sumunistro de agua potable. En ciertos lugares, la concentracióon de nitratos excede el nivel máximo de seguridad para el agua potable 45 mg NO₃/L. El intenso uso de fertilizantes de nitratos y el abundante uso de agua subterránea sin tratamiento para la irrigación de cultivos contribuyen sustancialmente al problema. Sin embargo, sin lugar a dudas, la descarga de deshechos industriales y municipales en arroyos y en el acuífero también contribuyen al problema. La falta de datos impide la evalución de dichas fuentes. En la zona de recarga se encuentran nitratos hasta los 50 m de profundidad. Cerca a Pekín, concentraciones relativamente altas de nitrato ocurren hasta los 80 m de profunidad. En las zonas de descarga afectadas por el Río Amarillo las concentraciones altas de nitrato se encuentran solamente a menos de 8m de profundidad.

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Resumé Une campagne dévaluation de la qualité de leau souterraine entreprise entre 1998 et 2000 à travers une vaste étendue de la plaine du nord en Chine indique que la pollution par les nitrates est un problème sérieux qui affecte la qualité de leau souterraine pour une abondante population. Lutilisation de fertilisants azotés pour lagriculture a augmenté considérablement durant les 20 dernières années afin de rencontrer les besoins alimentaires dune population à forte croissance. Lors de cette étude, 295 échantillons deau ont été prélevés dans des puits et sources naturelles afin de déterminer la composition chimique de leau souterraine ainsi que létendue de la pollution par les nitrates. Des concentrations élevées de nitrates, en particulier dans une zone de recharge le long de la limite ouest de la plaine, mais aussi dans la région de Beijing et sporadiquement dans la plaine, posent de sérieux problèmes à la consommation de leau souterraine. A certains endroits, la concentration en nitrates excède la valeur maximale acceptée pour la consommation qui est de 45 mg NO₃/L. Lutilisation intensive de fertilisants azotés ainsi que lutilisation répandue deau souterraine non traitée pour lirrigation contribuent pour beaucoup au problème, mais il ne fait pas de doute que le rejet des déchets municipaux et industriels dans les rivières et aquifères y est aussi pour quelque chose. Par contre, le manque de donnés ne permet pas dévaluer la contribution de chacune de ces sources. Dans la zone de recharge, les nitrates se retrouvent à des profondeurs allant jusquà 50 m. Près de Beijing, des concentrations relativement élevées de nitrate ont été mesurées à des profondeurs allant jusquà 80 m. Enfin, dans la zone démergence affectée par la rivière Jaune, les fortes concentrations se retrouvent à une profondeur maximale de 8 m.

     

Nitrate pollution of groundwater in the Yellow River delta,China

Nitrate pollution of groundwater in the Yellow River delta, China is an important issue related not only to nitrate dispersion and health concerns but also to mass transport and interactions of groundwater, sea, and river waters in the coastal area. The spatial distribution of nitrate, nitrate sources, and nitrogen transformation processes were investigated by field surveys and geochemical methods. Nitrate occurred mainly in shallow layers and had a spatial distribution coinciding with geomorphology and land/water use. Irrigation water from the Yellow River and anthropogenic waste are two main nitrogen sources of nitrate in the delta, and both denitrification and mixing processes could take place according to characteristics identified by ionic and isotopic data.     

Biogenic opal production changes during the Mid-Pleistocene Transition in the Bering Sea (IODP Expedition 323 Site U1343)

Biogenic opal content and mass accumulation rate (MAR) at IODP Expedition 323 Site U1343 were found to fluctuate consistently, generally being high under warm conditions and low under cold conditions during the last 2.4 Ma. Continuous wavelet transform analysis of the normalized biogenic opal content indicates that export production in the Bering Sea varied predominantly at 41-ka periodicity before 1.25 Ma, and shifted to 100-ka periodicity at the onset of the Mid-Pleistocene Transition (MPT; 1.25–0.7 Ma). The 100-ka cycles dominated until the Holocene. Export production in the Bering Sea decreased markedly in the Bering Sea two times during the MPT: the first occurred at the beginning of the MPT (1.25 Ma) and the second in the middle of the MPT (0.9 Ma). These decreases coincided with both increases in the relative abundance of sea-ice diatoms and decreases in the warm-water diatom species Neodenticula seminae, indicating that reductions in export production in the Bering Sea during the MPT were associated with climate cooling. Decreases in export production in the Bering Sea during the MPT were most likely associated with the increased influence of polar/Arctic domains on the high-latitude North Pacific.     

Geochemical and Sr–Nd isotopic constraints on the genesis of the Soheyle-PaKuh granitoid rocks (central Urumieh-Dokhtar magmatic belt,Iran)

ABSTRACT

Soheyle-Pakuh granitoid rocks, with a variety of quartz diorite, quartz monzodiorite, granodiorite, tonalite, and granite, have been emplaced into the Tertiary volcanic rocks in the Urumieh-Dokhtar magmatic arc in central Iran. Zircon U–Pb dating yields an age of 39.63 ± 0.93 Ma for the crystallization of this body. Whole-rock compositions show that SiO₂ changes from 52.31 to 65.78 wt.% and Al₂O₃ varies from 15.54 to 18.24 wt.%, as well as high concentrations of large-ion lithophile elements (LILE, e.g. Cs, Rb, Ba, and K) and quite low contents of high field strength elements (HFSE, e.g. Nb, Ti, P), as expected in I-type arc granitoids formed in an active continental margin setting. Initial ratios of ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd exhibit ranges 0.7043–0.7047 and 0.51284 to 0.51287, respectively, with positive εNd_(t) from +4.9 to +5.5 with a young TDM1 age (483–674 Ma); this tracer isotopic data suggesting that the SPG originated from juvenile basaltic crust derived from depleted mantle (~90%) with variable contributions from undepleted mantle and approximately 10% old lower crust, despite diverse processes (e.g. magma mixing and fractional crystallization) during their evolution and emplacement into a local extensional setting within the continental margin arc. The isotopic data are similar to those of other Phanerozoic granitoids of the Central Asian Orogenic Belt and corroborate melting of predominantly mantle-derived juvenile crustal protoliths and indicating extensive addition of new continental crust, during Cambrian-Neoproterozoic time, in the suprasubduction zone beneath the central Urumieh-Dokhtar magmatic arc. Generation of these types of granitoids favours a model whereby rollback and (or) break-off of a subducted slab with subsequent lithospheric extension triggered by mantle upwelling, heat advection, and underplating resulting in melting of the central UDMA mantle-derived juvenile lower continental crust in the Late Eocene.     

Global mantle heterogeneity and its influence on teleseismic regional tomography

A new global P-wave tomography model is determined using a flexible-grid parameterization. This new model better reveals the mantle structure under the polar regions than the previous tomographic models. The subducting slabs are generally imaged clearly as high-velocity (high-V) zones. The young slabs are still subducting in the upper mantle and the mantle transition zone (MTZ), whereas the old and ancient slabs are either stagnant in the MTZ or have subducted down to the lower mantle, even reaching the core-mantle boundary. Low-velocity (low-V) anomalies are generally revealed in the mantle under the hotspot regions. It seems that a variety of mantle upwelling (plumes) exist. Some strong plumes are visible in the whole mantle under the long-living hotspots, such as those in south-central Pacific, Africa, Hawaii and Iceland, whereas weak plumes are visible in only some depth range under the minor hotspots. Under the intraplate volcanoes in East Eurasia, Bering Sea and West Alaska, significant low-V anomalies are revealed in the upper mantle, which may reflect hot and wet upwelling associated with corner flows in the big mantle wedge (BMW) above the stagnant Pacific slab in the MTZ and perhaps deep slab dehydration as well. The subduction-triggered magmatism in the BMW may be a new class of mantle plumes. We also used the new global model to investigate the influence of whole-mantle heterogeneity on the determination of upper-mantle tomography under Japan with a teleseismic inversion method. The results show that the mantle heterogeneities outside the target volume of regional tomography can cause significant changes (~ 0.2-0.4 s) to the observed relative travel-time residuals of a distant earthquake. The pattern of regional tomography remains the same even after correcting for the whole-mantle heterogeneity, but there are some changes in the amplitude of velocity anomalies in the regional tomography. Hence it is necessary to correct for the mantle heterogeneities outside the target volume so as to obtain a better regional tomography.     

End bearing capacity comparison of screw pile with straight pipe pile under similar ground conditions

In the present study, the end bearing capacity of screw and straight pipe pile under similar pile tip area and ground conditions were investigated. The effect of increasing overburden pressure was also considered in this research. Pile load tests on close-ended screw and straight pipe piles were conducted in the small scale. Dry Toyoura sand was used to develop the model ground. The sand was compacted at relative density of 70, 80 and 92 %. It was observed that in case of straight pipe pile, load settlement curve plunges downward without increase in load around settlement equals to 10 % of pile tip diameter, whereas in case of screw pile, the load settlement curve plunges around settlement equals to 15 % of pile tip diameter. Moreover, the screw piles having helix-to-shaft diameter ratio 2–4.1 showed 2–12 times higher end bearing capacity than straight pipe piles with similar pile shaft diameter. It was also observed from the test results that the end bearing capacity of single-helix screw pile was in average 16.25 % less than straight pipe pile with similar pile tip area and ground conditions irrespective of the effect of increasing overburden pressure.