Synthesis of highly dense and fine-grained aggregates of mantle composites by vacuum sintering of nano-sized mineral powders

Synthesized mineral powders with particle size of <100 nm are vacuum sintered to obtain highly dense and fine-grained polycrystalline mantle composites: single phase aggregates of forsterite (iron-free), olivine (iron containing), enstatite and diopside; two-phase composites of forsterite + spinel and forsterite + periclase; and, three-phase composites of forsterite + enstatite + diopside. Nano-sized powders of colloidal SiO₂ and highly dispersed Mg(OH)₂ with particle size of ≤50 nm are used as chemical sources for MgO and SiO₂, which are common components for all of the aggregates. These powders are mixed with powders of CaCO₃, MgAl₂O_4, and Fe(CO₂CH₃)₂ to introduce mineral phases of diopside, spinel, and olivine to the aggregates, respectively. To synthesize highly dense composites through pressureless sintering, we find that calcined powders should be composed of particles that have: (1) fully or partially reacted to the desired minerals, (2) a size of <100 nm and (3) less propensity to coalesce. Such calcined powders are cold isostatically pressed and then vacuum sintered. The temperature and duration of the sintering process are tuned to achieve a balance between high density and fine grain size. Highly dense (i.e., porosity ≤1 vol%) polycrystalline mantle mineral composites with grain size of 0.3–1.1 μm are successfully synthesized with this method.     

Natural and anthropogenic aquatic environmental changes reconstructed by paleolimnological analyses in Lake Kitaura,central Japan

In order to assess the recent anthropogenic environmental changes in Lake Kitaura, central Japan, changes during the past few centuries were reconstructed from results of radiometric and tephrochlonological age determination, magnetic susceptibility measurements, total organic carbon analyses, total nitrogen analyses and fossil diatom analyses on a sediment core from the lake. A total of six major and sub-zones are recognized according to the diatom fossil assemblages, and we discuss aquatic environmental change in Lake Kitaura mainly based on these diatom assemblage change. Zone Ia and Zone Ib (older than AD 1707) are marine to brackish. In Zone IIa (AD␣1707–AD 1836), most of the brackish diatoms disappeared, and were replaced by freshwater species indicating a decrease in salinity. We interpret the salinity decrease in Zone I–IIa as a sea-level fall during the Little Ice Age. The salinity of the lake decreased to near freshwater conditions in Zone IIb (AD 1836–AD 1970), which could arise from alteration in River Tone or development of a sandspit in the mouth of River Tone in addition to sea-level change. In Zone IIIa (AD 1970–AD 1987), the diatom assemblage indicates a freshwater environment, and sedimentation rates increase rapidly. These changes reflect sedimentary environment change and an ecosystem transition due to the construction of the tide gate. In Zone IIIb (AD 1987–AD 2002), the diatom flux (valves cm⁻² y⁻¹) increased and species composition changed. The changes in Zone IIIb show a good agreement with limnological monitoring data gathered from the lake. These paleolimnological data suggest that the recent human-induced changes of the aquatic environment of the lake after the 1970s exceed rates during the period concerned in this study.     

Life habit of vesicomyid clam,Calyptogena soyoae,and hydrogen sulfide concentration in interstitial waters in Sagami Bay,Japan

In and around the beds of vesicomyid clam (Calytogena soyoae) located off Hatsushima Island in Sagami Bay, central Japan, hydrogen sulfide concentration in bottom water and interstitial water was measured every 10 cm from just above seafloor to 40 cm deep usingin situ separative dialysis bags. While hydrogen sulfide over 0.01 mmol/kg was not measured from the seawater just above the dense clam beds, the concentration of hydrogen sulfide increased rapidly below 10 cm deep. The results indicate that the habit of the clam is correlated with high concentration of hydrogen sulfide contained in pore waters of sediments between depths of 10 and 20 cm from the bottom surface. Concentrations of hydrogen sulfide ranging from approximately 0.05 mmol/kg to 0.6 mmol/kg might be suitable requirement for the habitat ofC. soyoae.     

Basin and crustal velocity structure models for the simulation of strong ground motions in the Kinki area,Japan

We constructed a prototype of the basin and crustal structure model for the Kinki area, southwest of Japan, for the simulation of strong ground motions of hypothetical crustal and subduction earthquakes. We collected results of the deep seismic velocity profiles obtained by the reflection experiments and seismic imaging results, which were conducted in the Kinki area. The obtained profiles give underground velocity structures of the crust, from the surface to the subducting slab. We also gather the basin velocity structure information of the Osaka, Kyoto, Nara, and Ohmi basins. To examine the applicability of the constructed velocity structure model to the ground motion simulation, we simulated waveforms of an intermediate size event occurred near the source area of the hypothetical subduction earthquakes. Simulated ground motions using the basin and crustal velocity structure model are fairly well reproducing the observations at most of stations, and the constructed basin and crustal velocity structure model is applicable for the long-period ground motion simulations.     

Zircon U–Pb ages of granitic and mafic dikes associated with granitoids and metamorphic rocks of the Ryoke Belt in the eastern Kii Peninsula,southwest Japan

Zircon U–Pb dates for felsic and intermediate to mafic dikes intruding into the Ryoke granitoids and metamorphic rocks at selected outcrops in the Takamiyama area of the eastern Kii Peninsula, southwest Japan, were determined along with their geology and petrography to reveal the history of Cretaceous magmatism. At each outcrop, the felsic and intermediate to mafic dikes exhibit specific structures that are indicative of magma intermingling and have coeval intrusion ages of ca. 81–77 Ma. Our zircon U–Pb data complement previously published data, suggesting that the mafic magmatism continued intermittently from 83 to 76 Ma in the Takamiyama area and that magmatism migrated eastward within the Ryoke Belt. A comparison of intrusion ages between a dike and a host Ryoke granitoid at one outcrop indicates that the host rock experienced ductile deformation at ~88 to ~83 Ma. Judging from the small number of zircons and the concordant date distributions, we didn't recognize the evidence suggesting the partial melting of the host rocks, as Nakajima et al. (Journal of the Geological Society of Japan, 2021, 127, 69–78) reported.     

Three-dimensional image of the anisotropic bodies beneath central Honshu, Japan

Shear-wave splitting from local deep earthquakes is investigated to clarify the volume and the location of two anisotropic bodies in the mantle wedge beneath central Honshu, Japan. We observe a spatial variation in splitting parameters depending on the combination of sources and receivers, nearly N–S fast in the northern region, nearly E–W fast in the southern region and small time delays in the eastern region. Using forward modelling, two models with 30 and 10 per cent anisotropy are tested by means of a global search for the locations of anisotropic bodies with various volumes. The optimum model is obtained for 30 per cent anisotropy, which means a 5 per cent velocity difference between fast and slow polarized waves. The northern anisotropic body has a volume of 1.00° (longitude) × 0.5° (latitude) × 75 km (depth), with the orientation of the symmetry axis being N20°E. The southern anisotropic body has a volume of 1.25° × 1.25° × 100 km with the symmetry axis along N95°E. Our results show that the anisotropic bodies are located in low-velocity and low- Q regions of the mantle. This, together with petrological data and the location of volcanoes in the arc, suggests that the possible cause of the anisotropy is the preferred alignment of cracks filled with melt.     

Response of plant growth to surface water balance during a summer dry period in the Kazakhstan steppe

In drylands, water deficit is the primary factor limiting plant growth. In the present study, surface energy balance and plant growth (above‐ground and below‐ground biomass) were measured continuously during the 2002 growing season in semiarid grassland in the northern part of Kazakhstan, Central Asia. Although there was above normal total rainfall during the 2002 growing season (May–November; 244 mm over 183 days), there was a dry period during July and August. Evaporative water was effectively supplied by precipitation and surface soil moisture during the wet season (May and June), during which time above‐ground biomass increased. During the early stages of the dry period, mature plants were likely to tap deeper sources of soil moisture, representing stored snowmelt water. As the soil moisture content decreased during the summer dry period due to the high levels of evapotranspiration and lack of precipitation, the evaporative fraction and above‐ground biomass rapidly decreased, whereas the below‐ground biomass increased. These results suggest that in summer, soil moisture acts to store water, and that soil moisture is essential for plant growth as a direct source of water during the dry period in natural grasslands in the Kazakhstan steppe. Copyright © 2007 John Wiley & Sons, Ltd.     

Curation protocol of Phobos sample returned by Martian Moons eXploration

Japan Aerospace Exploration Agency's Martian Moons eXploration (MMX) mission will launch a spacecraft in 2024 to return samples from Phobos in 2029. Curatorial work for the returned Phobos samples is critical for the sample allocation without degrading the sample integrity and subsequent sample analysis that will provide new constraints on the origin of Phobos and the evolution of the circum-Mars environment. The Sample Analysis Working Team of the MMX is designing the sample curation protocol. The curation protocol consists of three phases: (1) quick analysis (extraction and mass spectrometry for gases), (2) pre-basic characterization (bulk-scale observation), and (3) basic characterization (grain-by-grain observation and allocation of the sample aliquots). Nondestructive analyses within the clean chamber (e.g., visible and near-infrared spectral imaging) and outside the chamber (e.g., gas mass spectrometry) are incorporated into the curation flow in coordination with the MMX mission instrument teams for ground-truthing the remote-sensing data sets. The MMX curation/sample analysis flow enables the seamless integration between the sample and remote-sensing data sets to maximize the scientific value of the collected Phobos samples.     

Siderophile element characteristics of acapulcoite–lodranites and winonaites: Implications for the early differentiation processes of their parent bodies

We have studied magnetic fractions of five acapulcoites, three lodranites, and two winonaites to investigate chemical compositions of their precursor materials and metallic partial melting processes occurring on their parent bodies. One winonaite metal is similar in composition to low Au, low Ni IAB iron subgroup, indicating genetic relationship between them. Magnetic fractions of chondrule‐bearing acapulcoite and winonaite have intermediate chemical compositions of metals between H chondrites and EL chondrites. This fact indicates that the precursor materials of acapulcoite–lodranites and winonaites were similar to H and/or EL chondrites in chemical compositions. Magnetic fractions in acapulcoite–lodranites have a large variety of chemical compositions. Most of them show enrichments of W, Re, Ir, Pt, Mo, and Rh, and one of them shows clear depletion in Re and Ir relative to those of chondrule‐bearing acapulcoite. Chemical compositional variations among acapulcoite–lodranite metals cannot be explained by a single Fe‐Ni‐S partial melting event, but a two‐step partial melting model can explain it.