Experimental investigation on thermochemical sulfate reduction by H2S initiation

Hydrogen sulfide (H₂S) is known to catalyze thermochemical sulfate reduction (TSR) by hydrocarbons (HC), but the reaction mechanism remains unclear. To understand the mechanism of this catalytic reaction, a series of isothermal gold-tube hydrous pyrolysis experiments were conducted at 330 °C for 24 h under a constant confining pressure of 24.1 MPa. The reactants used were saturated HC (sulfur-free) and CaSO₄ in the presence of variable H₂S partial pressures at three different pH conditions. The experimental results showed that the in-situ pH of the aqueous solution (herein, in-situ pH refers to the calculated pH of aqueous solution under the experimental conditions) can significantly affect the rate of the TSR reaction. A substantial increase in the TSR reaction rate was recorded with a decrease in the in-situ pH value of the aqueous solution involved. A positive correlation between the rate of TSR and the initial partial pressure of H₂S occurred under acidic conditions (at pH ∼3-3.5). However, sulfate reduction at pH ∼5.0 was undetectable even at high initial H₂S concentrations. To investigate whether the reaction of H₂S_(aq) and occurs at pH ∼3, an additional series of isothermal hydrous pyrolysis experiments was conducted with CaSO₄ and variable H₂S partial pressures in the absence of HC at the same experimental temperature and pressure conditions. CaSO₄ reduction was not measurable in the absence of paraffin even with high H₂S pressure and acidic conditions. These experimental observations indicate that the formation of organosulfur intermediates from H₂S reacting with hydrocarbons may play a significant role in sulfate reduction under our experimental conditions rather than the formation of elemental sulfur from H₂S reacting with sulfate as has been suggested previously (Toland W. G. (1960) Oxidation of organic compounds with aqueous sulphate. J. Am. Chem. Soc.82, 1911-1916).Quantification of labile organosulfur compounds (LSC), such as thiols and sulfides, was performed on the products of the reaction of H₂S and HC from a series of gold-tube non-isothermal hydrous pyrolysis experiments conducted at about pH 3 from 300 to 370 °C and a 0.1-°C/h heating rate. Incorporation of sulfur into HC resulted in an appreciable amount of thiol and sulfide formation. The rate of LSC formation positively correlated with the initial H₂S pressure. Thus, we propose that the LSC produced from H₂S reaction with HC are most likely the reactive intermediates for H₂S initiation of sulfate reduction. We further propose a three-step reaction scheme of sulfate reduction by HC under reservoir conditions, and discuss the geological implications of our experimental findings with regard to the effect of formation water and oil chemistry, in particular LSC content.     

The age of the Nantuo Formation and Nantuo glaciation in South China

A U–Pb sensitive high‐resolution ion microprobe (SHRIMP) age of 654.5 ± 3.8 Ma from an ash bed immediately below the Nantuo Formation in South China provides the lowest age constraint for the Nantuo glaciation, which has been correlated with the global ‘Marinoan’ glaciation. A U–Pb SHRIMP age of 636.3 ± 4.9 Ma from a fallout tuff within the basal layer of the Nantuo Formation, along with the existing age of 635.2 ± 0.6 Ma from its overlying Doushantuo cap carbonate, suggests that the traditionally defined Nantuo Formation may have been deposited in a short time period at the end of the Nantuo glaciation. In combination with available ages globally, the data support a relatively short duration and rapid termination of ‘Marinoan’ glaciations.     

ND5-12井裂缝性漏失堵漏技术

ND5-12井是麻黄山工区施工的一口开发井,井漏十分频繁,严重制约了该地区的钻井速度,井漏问题是该地区施工必须逾越的难关。概述了该井井漏情况;分析了井漏原因及堵漏难点;制定了堵漏方案;详细介绍了堵漏泥浆的配方、性能以及堵漏技术措施。     

螺旋钻进技术在杉木树煤矿强突出煤层中的应用

通过目前瓦斯抽放孔成孔工艺的比较,介绍了杉木树矿强突出煤层采用螺旋钻进工艺试验的工艺过程及其优势,并介绍了在该煤矿的具体试验情况。     

扎赉诺尔坳陷带砂体特征及找铀矿方向分析

扎赉诺尔坳陷带内诸凹陷具有不同的沉积特征和砂体特点,查干诺尔和克鲁伦凹陷砂体形成于粗粒冲积扇和扇三角洲沉积体系,砂体厚度变化大,相变快,有机质含量低,顶底板均不发育;呼伦湖凹陷以小型三角洲平原相砂体为主,具有较稳定的泥砂岩结构,有机质含量高,砂体厚度和横向延伸较稳定,但砂体铀含量较低;胡列也吐凹陷砂体以辫状河三角洲体系产出为主,砂体厚度大,延伸稳定,底板发育,顶板发育不完全,砂体铀含量高.扎赉诺尔坳陷带各凹陷砂体的不同特点,决定了它们具有不同的找矿潜力.通过砂体综合条件对比分析,笔者认为胡列也吐凹陷和克鲁伦凹陷砂体铀成矿条件较好,呼伦湖凹陷次之,查干诺尔凹陷较差.     

Copula函数在多变量水文分析计算中的应用及研究进展

综述了多变量水文分析计算方法及存在的问题.系统地介绍了Copula函数的基本理论与方法,分析探讨Copula函数在多变量水文计算领域的适用性及优越性.总结了Copula函数应用的关键技术,包括参数估计、拟合检验及类型选择等,并展望了Copula函数的研究应用前景.     

分光光度法测定海洋河弧菌510脂多糖

本文研究了直接测定海洋河弧菌 (vibrio fluvailis) 5 10脂多糖的分光光度法。利用 1,9-二甲基亚甲蓝 (DMB) ,在适当条件下同脂多糖发生染色反应 ,在 5 5 0 nm波长下 ,反应体系的吸光值同脂多糖含量呈线性相关。相关系数为 0 .9993,最低检出限为 10 μg/m L,相对标准偏差为 1.6 2 ,平均回收率为 (10 5± 2 .18) %。     

中国对虾血细胞酶细胞化学的初步研究

运用电镜酶细胞化学技术 ,对中国对虾 (Penaeus chinensis)的血细胞和血清中的酚氧化酶、酸性磷酸酶、碱性磷酸酶和过氧化物酶的酶活性部位进行标记。实验结果显示 :酚氧化酶主要以酶原形式存在于大颗粒细胞的颗粒体中 ,酸性磷酸酶和碱性磷酸酶以酶原形式存在于小颗粒细胞的颗粒体中。健康虾和患病虾血细胞中酶活性的表现形式不尽相同 ,在病理情况下 ,颗粒细胞能以细胞解体的方式 ,排出细胞内的颗粒 ,转化成有活性的酶 ,以此提高血淋巴中这几种酶的活性。透明细胞可以吞噬排放颗粒后的颗粒细胞 ,透明细胞中由高尔基体合成的酸性磷酸酶等溶酶体酶主要用于透明细胞的细胞内消化作用。研究认为 :3种血细胞因含有不同的免疫酶以及酶的作用方式不同而具有不同的免疫功能     

中国辽宁-浙江沿海地区川蔓草分布现状、生态特征及其主要威胁

川蔓草(Ruppia)是一种广泛分布在咸水、半咸水生境中的广义海草, 其形成的川蔓草床具有重要的生态学价值。然而, 对于其在中国境内的分布情况尚缺乏大范围的调查。基于此, 本研究于2016—2019年对中国辽宁-浙江沿海区域的川蔓草分布情况进行了初步调查, 探究了调查区域内川蔓草的生境分布类型, 及生态特征, 分析了川蔓草床的主要威胁, 并提出了对川蔓草床科学管理的建议。结果表明: 川蔓草在中国浙江省、江苏省、山东省、天津市、河北省、辽宁省均有分布; 分布面积超过2 100 ha; 该区域内分布的川蔓草物种均为中国川蔓草, 主要分布生境包括咸水养殖池塘、咸水沟渠(池塘)、盐场、瀉湖(湖泊)、潮间带(围堰)5类; 人类活动影响(人工清捞、施药、河道工程等)与极端气候事件(极端干旱事件)都会导致川蔓草床退化, 但大部分川蔓草床可以依靠沉积物中的种子库在环境适宜时进行种群恢复; 不同生境中的川蔓草种群特征差异较大, 因此, 对不同生境中的川蔓草应制定差异性管理措施。     

中太平洋西部深海沉积物中的火山碎屑与粘土矿物

对于太平洋深海沉积物的研究虽有很久的历史(如1873-1876年“挑战者”号的科学考察),但对该区开展深入系统的岩石学和矿物学研究却是六十年代以后的事.随着研究手段的发展和进步,已积累了关于该区深海沉积物的大量资料.目前我国的海洋工作者也正在努力开展这方面的科学研究工作.