上海“8.5”特大暴雨的成因和特点

利用WSR－88D多普勒雷达资料，通过分析2001年8月5日到8月6日产生于上海地区的特大暴雨过程的雷达回波特征，研究探讨这次过程的降水成因和降水特点。发现副热带高压边缘偏南气流的风速辐合、螺旋雨带中强回波短带的合并加强、风的垂直切变产生的辐合以及热带系统的高效率降水作用是这次暴雨过程的降水成因和降水特点。并提出了预报这类暴雨系统需要注意的要点：强降水回波的发生和发展加强往往和风场中的局地强辐合区相联系，利用多普勒雷达连续演变的风场资料，可及时了解辐合区的形成和演变过程，提前作出强降水可能性的预测。     

黄河下游游荡段河道平面形态与河热变化趋势预测

黄河下游可道平面形态与河势演变,从２０世纪６０年代起,地貌界就用地图法和航片资料作过不同程度的研究。随着资料的不断积累,该项研究得到逐步的深化。“八五”期间,水利界又对主流线作了深入分析,结果表明：各家所得结论不同,需要作进一步的分析讨论。我们认为：从长远的角度来看,小浪底水库清水下泄期间,黄河下游游荡性可段不对称的河谷形态不会改变;在继承性新构造运动造成的地壳向南掀沉、科氏力和人类活动的综合影响     

Correlation Fractal and Multifractal Characteristics of Seismic Activity in the Taiwan Area, China

Based on the analysis of newly collected data of plate tectonics, distribution of active faults and crustal deformation, the Taiwan area is divided into two seismic regions and six seismic belts. Then, correlation fractal dimensions of all the regions and belts are calculated, and the fractal characteristics of hypocenteral distribution can be quantitatively analyzed. Finally, multifractal dimensions Dq and f(α) are calculated by using the earthquake catalog of the past 11 years in the Taiwan area. This study indicates that (1) there exists a favorable corresponding relationship between spatial images of seismic activity described with correlation fractal dimension analysis and tectonic settings; (2) the temporal structure of earthquakes is not single but multifractal fractal, and the pattern of Dq variation with time is a good indicator for predicting strong earthquake events.     

陕西地洞河高分辨率石笋记录的DO18季风增强事件

千年尺度事件的结构特征和区域响应是理解和认识冰期气候变化及动力机制的关键。本文基于陕西汉中宁强县地洞河一支长417 mm石笋DDH1的11个U-Th年代和417个氧同位素（δ¹⁸O）数据,重建了末次冰期（64.8~33.2 ka B.P.）亚洲季风演化历史。石笋δ¹⁸O记录在64.7±0.2 ka B.P.和59.3±0.1 ka B.P.快速负偏,分别指示了DO18事件的开始和H6事件的结束。在DO18事件结束过程,石笋δ¹⁸O记录在64.0~60.4 ka B.P.持续正偏,振幅达2.9 ‰,反应季风逐渐减弱,但未出现明显转型阶段。其总体形态与大西洋Cariaco盆地岩芯反射率、南极冰芯的记录较为一致,但是不同于格陵兰冰芯的记录。因地洞河所处青藏高原、秦岭叠加影响的区域,纬度和地形的双重影响使得其石笋δ¹⁸O记录较其他地区偏负,振荡幅度更大。因地形阻挡了高纬信号,使得低纬甚至南半球的信号突现出来,ITCZ的移动、南半球温度和水汽潜热的释放作用在这一区域尤为显著。

     

末次冰盛期东亚夏季风变化的重庆石笋记录

基于重庆小山岩洞XSY1石笋的5个²³⁰Th年龄和582个氧同位素数据,重建了23134~19345 a B.P.期间分辨率约6.5 a的东亚夏季风变化历史。此石笋δ¹⁸O记录的长期趋势逐渐负偏,在其上叠加了一系列千年-百年尺度季风振荡,呈现为4谷3峰的结构形态。重庆XSY1和南京MSD石笋δ¹⁸O记录在数百年尺度的反相关系表明冰盛期时东亚大陆东部水汽并非来自印度洋。与北高纬记录对比显示东亚季风的增强与减弱基本对应格陵兰温度的升高与降低时期,暗示在冰量最大时期东亚季风与北高纬气候仍密切联系。此外,XSY1的δ¹⁸O与冰芯¹⁰Be通量亦存在明显的对应关系,表明太阳活动对东亚季风的调控作用受冰量边界条件影响较小。功率谱分析结果显示出1011 a、722 a、460 a、337 a和163 a的周期,与太阳活动周期相近,进一步确认太阳活动对东亚季风的驱动作用。石笋XSY1与澳大利亚石笋MC-S2 δ¹⁸O记录在千年尺度呈反相位变化,表明冰盛期时东亚季风与全球其他气候系统的动力联系。

     

Zero-valent iron/persulfate(Fe0/PS) oxidation acetaminophen in water

Zero-valent iron (Fe⁰), as an alternative iron source, was evaluated to activate persulfate (PS) to degrade acetaminophen (APAP), a representative pharmaceutically active compound in water. Effects of key factors in the so-called Fe⁰/PS process, including Fe⁰ dosage, initial pH, temperatures and chelating agents, were studied. Under all the conditions tested, the APAP degradation followed a pseudo-first-order kinetics pattern. The degradation efficiency of APAP was highest when the Fe⁰ to PS molar ratio increased to 1:1, and the degradation rate constant and removal were 23.19 × 10^?3 min^?1 and 93.19 %, respectively. Comparing with Fe²⁺, Fe⁰ served as an alternative iron source that can gradually release Fe²⁺ into water, thereby consistently activating PS to produce sulfate radicals. The Fe⁰/PS system was effective in a broader pH range from 3 to 8.5. Heat could facilitate production of sulfate radicals and enhance the APAP degradation in the Fe⁰/PS system. High reaction temperature also improved the Fe²⁺/PS oxidation of APAP. Finally, sodium citrate (a chelating agent) at an appropriate concentration could improve the APAP degradation rate in the Fe²⁺/PS and Fe⁰/PS system. The optimal molar ratio of Fe⁰ to citrate depended on solution pH. Our results demonstrated that Fe⁰ was an alternative iron source to activate PS to degrade APAP in water.     

山西辛安岩溶泉形成条件及随机模型

本文详细分析了山西辛安岩溶泉的水文地质条件,并通过对泉域岩溶水的补给、径流、排泄条件的分析,将辛安泉域概化为单输入单输出线性时不变集中参数随机系统的概念模型。利用24年的水文序列资料进行基流分割,获得泉多年月平均流量过程曲线,求得泉年平均流量和年平均补给量。在此基础上,应用滑动平均模型（MA）,自回归—滑动平均模型（AR-MA）及泉流量调和分析—残差自回归等三个模型,对泉域地下水进行模拟,获得了满意的结果,不仅揭示了泉水动态特征,而且对泉流量动态进行了预报,为晋东南区域经济规划提供了有益资料。     

流动注射-光度法测定地质样品中痕量碘

利用I~-对4,4′-四甲基二氨基二苯甲烷(4,4′-TMB-DPM)与氯胺T反应的催化作用,建立了流动注射-分光光度测定地质样品中痕量碘的方法。采用不等流速合并带法,分析速度快、节省试剂、灵敏度高。与高温水解法释放I~-相结合,使样品处理简单、干扰离子少。对于含I~-10μg/L的水样,其RSD(n=19)为1.1％,检出限为0.3ng/ml。用于水系沉积物、土壤分析时,含碘1.6×10~(-6)的样品RSD(n=10)为6.1％,检出限为0.08×10~(-6)。测量速度50N/h。     

Measurement of local and volumetric deformation in geotechnical triaxial testing using 3D-digital image correlation and a subpixel edge detection algorithm

Based on the three-dimensional digital image correlation (3D-DIC) technique, the stereovision system has been applied to the improved triaxial apparatus to obtain 3D full-field deformation of the specimen during triaxial testing. Through the calibration process, the 3D-DIC technique can obtain the accurate specimen’s spatial displacement deformation. Meanwhile, a subpixel edge detection algorithm has been combined with 3D-DIC technique to calculate the radial strain and the volume strain of the specimen directly. Furthermore, a series of consolidated drained and undrained triaxial tests were carried out on Hainan (China) sand specimens and measured by the conventional and the image measurement methods. Compared to the results measured by the conventional method, the image measurement technique can obtain the more experimental data, such as the 3D displacement field of the whole specimen, the local strain distribution, and so on. The measurement results also show the conventional method would be disturbed by the end constraints in triaxial tests so that the strength of the soil would be overestimated. Meanwhile, the middle of the specimen would be selected to calculate the stress–strain relationship without the influence of the end constraints in the proposed method. Based on the image measurement results, the proposed method has the potential to be used in geotechnical tests for exploring the soil’s progressive failure behaviors, inhomogeneous deformation and mechanical characteristics.