Effects of hydrothermal alteration on Pb in the active PACMANUS hydrothermal field, ODP Leg 193, Manus Basin, Papua New Guinea: A LA-ICP-MS study

The conventional model of leaching volcanic rocks as a source of metals in a seafloor hydrothermal systems has been tested by examining the behavior of Pb and other trace elements during hydrothermal alteration. ODP Leg 193 drill sites 1188 (Snowcap) and 1189 (Roman Ruins) on Pual Ridge in the eastern Manus Basin offshore eastern Papua New Guinea provide a unique three-dimensional window into an active back-arc hydrothermal system. We investigate by means of a LA-ICP-MS microbeam technique the capacity of Pb to be leached from a host volcanic rock exposed to various types and intensities of alteration. Our results are in general agreement with previous studies that utilized bulk analytical techniques but provide a more detailed explanation of the processes.Fresh representative dacitic lavas from the Pual Ridge have an average whole rock Pb content of 5.2 ppm, an average interstitial glass Pb content of 5.6 ppm and an average plagioclase Pb content of 1.0 ppm. Altered matrix samples have highly variable Pb values ranging from 0 to 52.4 ppm. High Pb values in altered samples are associated with a low temperature chlorite and clay mineral assemblage, in some cases overprinted by a high temperature (up to 350 °C) silica-rich “bleaching” alteration. Only the most highly altered matrix samples have REE patterns that differ from the fresh Pual Ridge dacite. This may represent either different lava histories or alteration characteristics that have affected normally immobile REEs. Altered samples with the highest Pb values have similar REE patterns to those of the local unaltered lavas. They are compositionally similar to typical Pual Ridge dacites indicating a genetic relationship between the main regional volcanic suite and the subseafloor hydrothermally altered, Pb-enriched material.Relative loss/gain for Pb between the analyzed altered samples and a calculated precursor show a maximum relative gain of 901%. Samples with relative Pb gain from both drill sites are associated with lower temperature alteration mineral assemblages characterized by pervasive chloritization. The related lower temperature (220-250 °C) neutral to slightly acidic fluids have been ascribed by others to return circulation of hydrothermal fluids that did not interact with seawater. Because altered samples have a higher Pb content than the fresh precursor, leaching of fresh volcanic rocks cannot be the source of Pb in the hydrothermal systems.     

Evaluation of ground vibrations and the effect of air blast in open-pit phosphate mines

Blasting constitutes a beneficial industrial technology, used in quarries and mining production processes, which ensures the achievement of the expected results in a short period of time with relatively low cost. Nevertheless, a significant part of the used blasting energy is wasted in the form of ground vibration and air blast. Hence, blasting-induced ground vibrations are one of the fundamental problems in the mining industry which may cause severe damage to structures and plants nearby. Therefore, a vibration control study plays an important part in the minimization of the environmental effects of blasting in mines. This study represents an investigation reporting ground motion (measured in terms of peak particle velocity (mm/s)) and air blast overpressure measurements around the open-pit phosphate mine near Metlaoui area (southwestern Tunisia). It aimed to calculate the site’s constants: K (ground transmission coefficient) and n (site attenuation curve slope). The obtained site parameters allowed determining the propagation equation of the blast-induced seismic waves in the study area. The scope of this study was to predict the peak particle velocity when the amount of explosive charge and/or the distance were altered with minimum spoil to the environment. Also, a frequency overview of the study area revealed the dominance of low frequencies (>?40 Hz). Such values can cause damage to the nearby structures when a specific peak particle velocity value is reached by blasting. Moreover, this study demonstrated that all overpressure magnitudes were less than 134 dB, which is the safe limit of air blast level.     

Role of sea surface temperature,Arctic sea ice and Siberian snow in forcing the atmospheric circulation in winter of 2012–2013

Climate Dynamics - During the 2012–2013 winter, the negative phase of the North Atlantic Oscillation (NAO) predominated, resulting in a cold winter over Europe and northern Asia punctuated by...     

Monomethylmercury sources in a tropical artificial reservoir

The distribution and speciation of mercury (Hg) in the water column, the inputs (wet deposition and tributaries) and the outputs (atmospheric evasion and outlet) of an artificial partially anoxic tropical lake (Petit-Saut reservoir, French Guiana) were investigated on a seasonal basis in order to appraise the cycling and transformations of this metal. The total mercury (HgT) concentrations in the oxygenated epilimnetic waters averaged 5 ± 3 pmol L⁻¹ in the unfiltered samples (HgT_UNF) and 4 ± 2 pmol L⁻¹ in the dissolved (HgT_D) phase (<0.45 μm). On average, the monomethylmercury (MMHg) constituted 8%, 40% and 18% of the HgT in the dissolved phase, the particulate suspended matter and in the unfiltered samples, respectively. Covariant elevated concentrations of particulate MMHg and chlorophyll a in the epilimnion suggest that phytoplankton is an active component for the MMHg transfer in the lake. In the anoxic hypolimnion the HgT_UNF averages 13 ± 6 pmol L⁻¹ and the HgT_D 8 ± 4 pmol L⁻¹. The averages of MMHg_P and MMHg_D in hypolimnetic waters were two and three times the corresponding values of the epilimnion, 170 ± 90 pmol g⁻¹ and 0.9 ± 0.5 pmol L⁻¹, respectively. In the long dry and wet seasons, at the flooded forest and upstream dam sampling stations, the vertical profiles of MMHg_D concentrations accounted for two distinct maxima: one just below the oxycline and the other near the benthic interface. Direct wet atmospheric deposition accounted for 14 moles yr⁻¹ HgT_UNF, with 0.7 moles yr⁻¹ as MMHg_UNF, while circa 76 moles yr⁻¹ of HgT_UNF, with 4.7 moles yr⁻¹ as MMHg_UNF, coming from tributaries. Circa 78 moles (∼17% as MMHg) are annually exported through the dam, while 23 moles yr⁻¹ of Hg⁰ evolve in the atmosphere. A mass balance calculation suggests that the endogenic production of MMHg_UNF attained 8.1 moles yr⁻¹, corresponding to a methylation rate of 0.06% d⁻¹. As a result, the Petit-Saut reservoir is a large man-made reactor that has extensively altered mercury speciation in favor of methylated species.     

Dissipative structures in a nonlinear dynamo

This article considers magnetic field generation by a fluid flow in a system referred to as the Archontis dynamo: a steady nonlinear MHD state is driven by a prescribed body force. The field and flow become almost equal and dissipation is concentrated in cigar-like structures centred on straight-line separatrices. Numerical scaling laws for energy and dissipation are given that extend previous calculations to smaller diffusivities. The symmetries of the dynamo are set out, together with their implications for the structure of field and flow along the separatrices. The scaling of the cigar-like dissipative regions, as the square root of the diffusivities, is explained by approximations near the separatrices. Rigorous results on the existence and smoothness of solutions to the steady, forced MHD equations are given.     

European temperatures in CMIP5: origins of present-day biases and future uncertainties

European temperatures and their projected changes under the 8.5 W/m² Representative Concentration Pathway scenario are evaluated in an ensemble of 33 global climate models participating in the fifth phase of the Coupled Model Intercomparison Project (CMIP5). Respective contributions of large-scale dynamics and local processes to both biases and changes in temperatures, and to the inter-model spread, are then investigated from a recently proposed methodology based on weather regimes. On average, CMIP5 models exhibit a cold bias in winter, especially in Northern Europe. They overestimate summer temperatures in Central Europe, in association with a greater diurnal range than observed. The projected temperature increase is stronger in summer than in winter, with the highest summer warming occurring over Mediterranean regions. Links between biases and sensitivities are evidenced in winter, suggesting a potential influence of snow cover biases on the projected surface warming. A brief analysis of daily temperature extremes suggests that the intra-seasonal variability is projected to decrease (slightly increase) in winter (summer). Then, in order to understand model discrepancies in both present-day and future climates, we disentangle effects of large-scale atmospheric dynamics and regional physical processes. In particular, in winter, CMIP5 models simulate a stronger North-Atlantic jet stream than observed and, in contrast with CMIP3 results, the majority of them suggests an increased frequency of the negative phase of the North-Atlantic Oscillation under future warming. While large-scale circulation only has a minor contribution to ensemble-mean biases or changes, which are primarily dominated by non-dynamical processes, it substantially affects the inter-model spread. Finally, other sources of uncertainties, including the North-Atlantic warming and local radiative feedbacks related to snow cover and clouds, are briefly discussed.     

Application of expert rules in indirect approaches for landslide susceptibility assessment

Landslide susceptibility (LS) assessment by indirect approaches presents some limitations due to (1) the tendency to simplify the environmental factors (i.e., variables) and (2) the assumptions that landslides occur under the same combination of variables for a study site. Recently, some authors have discussed the interest to introduce expert knowledge in the indirect approaches in order to improve the quality of indirect LS maps. However, if the results are reliable, the procedures used seem fastidious and a very good knowledge of the study site is essential. The objectives of this paper are to discuss a methodology to introduce the expert knowledge in the indirect mapping process. After the definition of the expert rules associated to three landslide types, several indirect LS maps are produced by two indirect exploratory approaches, based on fuzzy set theory and on a modification of a bivariate method called expert weight of evidence. Then, the indirect LS maps are confronted to a landslide inventory and a LS map produced by a direct approach. The analyses indicate that the methodology used to introduce the expert rules in the mapping process increases the predictive power of indirect LS map. Finally, some indications about advantages and drawbacks of each approach are given to help the geoscientist to introduce his expert knowledge in the landslide susceptibility mapping process.     

A new magnetostratigraphic framework for the Lower Miocene (Burdigalian/Ottnangian, Karpatian) in the North Alpine Foreland Basin

Oligocene–Miocene chronostratigraphic correlations within the Paratethys domain are still highly controversial. This study focuses on the late Early Miocene of the Swiss and S-German Molasse Basin (Late Burdigalian, Ottnangian–Karpatian). Previous studies have published different chronologies for this time interval that is represented by the biostratigraphically well constrained Upper Marine Molasse (OMM, lower and middle Ottnangian), Upper Brackish Molasse (OBM, Grimmelfingen and Kirchberg Formations, middle and upper Ottnangian to lower Karpatian, MN 4a–MN 4b) and Upper Freshwater Molasse (OSM, Karpatian–Badenian, MN 5). Here, we suggest a new chronostratigraphic framework, based on integrated magneto-litho-biostratigraphic studies on four sections and three boreholes. Our data indicate that the OBM comprises chrons 5D.1r and 5Dn (Grimmelfingen Fm), chron 5Cr (lower Kirchberg Fm) and the oldest part of chron 5Cn.3n (upper Kirchberg Fm). The OSM begins during chron 5Cn.3n, continues through 5Cn, and includes a long reversed segment that can be correlated to chron 5Br. The OMM-OSM transition was completed at 16.0 Ma in the Swiss Molasse Basin, while the OBM-OSM changeover ended at 16.6 Ma in the S-German Molasse Basin. As the lower Kirchberg Fm represents a facies of the Ottnangian, our data suggest that the Ottnangian–Karpatian boundary in the Molasse Basin is approximately at 16.8 Ma, close to the 5Cr–5Cn.3n magnetic reversal, and thus 0.4 Myr younger than the inferred age of 17.2 Ma used in recent Paratethys time scales. Notably, this would not be problematic for the Paratethys stratigraphy, because chron 5Cr is mainly represented by a sedimentation gap in the Central Paratethys. We also realise, however, that additional data is still required to definitely solve the age debate concerning this intriguing time interval in the North Alpine Foreland Basin. We dedicate this work to our dear friend and colleague Jean-Pierre Berger (8 July 1956–18 January 2012).