Screening model for volatile pollutants in dual porosity soils

This paper develops mass fraction models for transport and fate of agricultural pollutants in structured two-region soils. Mass fraction index models, based on a semi-infinite domain solution, are derived that describe leaching at depth, vapor losses through soil surface, absorption, and degradation in the dynamic- and stagnant-water soil regions. The models predict that leaching is the result of the combined effect of the upward vapor-phase transport relative to downward advection, residence time relative to half-life, dispersion, and lateral diffusive mass transfer. Simulations show that leached fraction of volatile compounds does not always decrease monotonically with increased residence time relative to the pollutant half-life, as a result of complex interactions among the different physical and biochemical processes. The results show that leaching, volatilization, and degradation losses can be affected significantly by lateral diffusive mass transfer into immobile-water regions and advection relative to dispersion (i.e. Peclet number) in the mobile-water regions. It is shown that solute diffusion into the immobile phase and subsequent biochemical decay reduces leaching and vapor losses through soil surface. Potential use of the modified leaching index for the screening of selected pesticides is illustrated for different soil textures and infiltration rates. The analysis may be useful to the management of pesticides and the design of landfills.     

Identification of Mining Blasts at Mid- to Far-regional Distances Using Low Frequency Seismic Signals

—?This paper reports results from two recent monitoring experiments in Wyoming. Broadband seismic recordings of kiloton class delay-fired cast blasts and instantaneous calibration shots in the Black Thunder coal mine were made at four azimuths at ranges from 1° to 2°. The primary focus of this experiment was to observe and to explain low-frequency signals that can be seen at all azimuths and should routinely propagate above noise to mid-regional distances where most events will be recorded by International Monitoring System (IMS) stations.¶The recordings clearly demonstrate that large millisecond delay-fired cast blasts routinely produce seismic signals that have significant spectral modulations below 10?Hz. These modulations are independent of time, the azimuth from the source and the orientation of the sensor. Low-frequency modulations below 5?Hz are seen beyond 9°. The modulations are not due to resonance as they are not produced by the calibration shots. Linear elastic modeling of the blasts that is guided by mine-blast reports fails to reproduce the fine detail of these modulations but clearly indicates that the enhanced “spectral roughness” is due to long interrow delays and source finiteness. The mismatch between the data and the synthetics is likely due to source processes, such as nonlinear interactions between shots, that are poorly understood and to other effects, such as variations of shot time and yield from planned values, that are known to be omnipresent but cannot be described accurately. A variant of the Automated Time-Frequency Discriminant (Hedlin, 1998b), which uses low-frequency spectral modulations, effectively separates these events from the calibration shots.¶The experiment also provided evidence that kiloton class cast blasts consistently yield energetic 2–10 second surface waves. The surface waves are strongly dependent on azimuth but are seen beyond 9°. Physical modeling of these events indicates that the surface waves are due mainly to the extended source duration and to a lesser extent to the slap-down of spalled material. The directionality is largely a path effect. A discriminant that is based on the partitioning of energy between surface and body waves routinely separates these events from the calibration shots.¶The Powder River Basin has essentially no natural seismic activity. How these mining events compare to earthquake observations remains to be determined.     

Optimal placement of dampers and actuators based on stochastic approach

A general method is developed for optimal application of dampers and actuators by installing them at optimal location on seismic-resistant structures. The study includes development of a statistical criterion, formulation of a general optimization problem and establishment of a solution procedure. Numerical analysis of the seismic response in time-history of controlled structures is used to verify the proposed method for optimal device application and to demonstrate the effectiveness of seismic response control with optimal device location. This study shows that the proposed method for the optimal device application is simple and general, and that the optimally applied dampers and actuators are very efficient for seismic response reduction.     

钢筋砼摩擦耗能支撑框架结构的单元刚度和力学模型分析

为研究钢筋砼摩擦耗能支撑框架结构的动力反应性能 ,对其中的摩擦耗能器单元和框架杆单元的单元刚度和力学模型做了分析。钢筋砼摩擦耗能支撑单元由支撑杆单元和钢板—橡胶摩擦耗能器单元组成 ,支撑单元可取空间杆单元 ,摩擦耗能器单元为平面应力矩形单元。摩擦耗能器单元的剪切恢复力曲线为理想的弹塑性曲线 ,根据耗能器单元的力学模型 ,可确定其在每一时刻的刚度 ;框架结构空间杆单元的恢复力模型采用双线型模型 ,根据杆单元的力学模型 ,可确定其在每一时刻的刚度。并利用所编制的程序对十层单榀两跨空间普通框架和摩擦耗能支撑框架在地震作用下进行了弹塑性反应时程分析 ,结果表明耗能支撑框架的顶层最大位移明显小于普通框架     

Early Yanshanian post-orogenic granitoids in the Nanling region Petrological constraints and geodynamic settings

Early Yanshanian magmatic suites predominate absolutely in the Nanling granite belt. They consist mainly of monzogranite and K-feldspar granite. There occur associations of early Yanshanian A-type granitoids (176 Ma-178 Ma) and bimodal volcanic rocks (158 Ma-179 Ma) in southern Jiangxi and southwestern Fujian in the eastern sector of the granite belt and early Yanshanian basalts (177 Ma-178 Ma) in southern Hunan in the central sector of the belt. Both the acid end-member rhyolite in the bimodal volcanic rock association and A-type granitoids in southern Jiangxi have the geochemical characteristics of intraplate granitic rocks and the basic end-member basalt of the association is intraplate tholeiite, while the basaltic rocks in southern Hunan include not only intraplate tholeiite but also intraplate alkali basalt. Therefore the early Yanshanian magmatic suites in the Nanling region are undoubtedly typical post-orogenic rock associations. Post-orogenic suites mark the end of a post-collision or late orogenic event and the initiation of Pangaea break-up, indicating that a new orogenic Wilson cycle is about to start. Therefore it may be considered that the early Yanshanian geodynamic settings in the Nanling region should be related to post-orogenic continental break-up after the Indosinian orogeny and the break-up did not begin in the Cretaceous.     

Model-independent Travel-time Attributes for 2-D, Finite-offset Multicoverage Reflections

— In this paper, we provide a 5-parameter stacking formula to transform 2-D prestack data into a particular common-offset section. This requires the knowledge of the near-surface velocity only and it is expected that ray theory holds to describe primary reflections. The earth model can be arbitrarily inhomogeneous. The new stacking approach can be viewed as a generalization of the 3-parameter common-reflection-surface (CRS) stack, by which 2-D multicoverage data are stacked into a simulated zero-offset section. The new 5-parameter formula can handle P-P, P-S and S-S reflections.     

Sedimentary cycles of trace elements in Salawusu River Valley since 150 ka BP

The paper makes some analyses on 11 trace elements in the Milanggouwan stratigraphical section in the Salawusu River valley, which is regarded as a prototype geology-palaeoclimate record since 150 ka BP. The results show that the content and variation of trace elements has experienced remarkably regular changes in the pace with coarse and fine sedimentary cycles of palaeo-aeolian sands to its overlying fluvio-lacustrine facies or/and palaeosols. The trace elements with chemical properties of relatively active (V, Sr, Cu, Ni, As) and relatively stable (P, Pb, Rb, Mn, Nb, Zr) are a manifestation of the corresponding 27 changeable cycles between peak and valley values, appearing a multi-fiuctuational process line of relative gathering and migration since then. The low numerical value distribution of these two types of trace elements in the aeolian sand facies represents erosion and accumulation under wind force during the cold-dry climate. Whereas their enrichments in both fluvio-lacustrine facies and palaeosols are related to the valley’s special low-lying physiognomic position between the Ordos Plateau and the Loess Plateau under the warm and humid climate conditions. The above relatively migrated and gathered change of the trace elements is the result of 27 climatic cycles of cold-dry and warm-humid, which is probably caused by repeated alternations of winter monsoon and summer monsoon in the Mu Us Sandy Land influenced by the climate vicissitudes in northern hemisphere during glacial and interglacial periods since 150 ka BP.     

Dynamic processes of a simple linear dune—a study in the Taklimakan Sand Sea, China

Samples of dune sands, surveys of the morphology and field measurements of wind velocity and direction of a simple linear dune in Taklimakan Sand Sea show that the airflow and sand flux vary with the change of wind direction on the dune surface. Decrease of the airflow stress on the lee flank does not result in much decrease of the sand flux because of the low threshold shear velocities and the airflow conditions. There are no significant relations between the sand flux on the lee flank and the angle of incidence of the airflow. The low threshold shear velocities and the maintenance of the sand flux at the lee flank are the main mechanisms keeping the linear shape of the dunes. Measurements of the sand flux shows that it reaches a maximum on the crest of the dune. The grain size of the transported sands has some differences compared to that of the dune surface. The sands transported are finer than that on the dune surface, but better sorted under the influence of the medium to low wind activity. The field experiment results exhibit that it is possible for the dunes to be shaped as linear dunes during the processes of accumulation and elongation.     

层序地层学研究及隐蔽油气藏预测--以南阳凹陷古近系为例

高精度层序地层学已被证明是寻找隐蔽圈闭行之有效的理论方法．运用该理论对南阳凹陷进行了研究，对地震剖面中反射界面的追踪，在古近系中识别出了各级别的层序界面，结合周缘露头、钻井、测井等资料，分析了主要目的层序内体系域的构成及高频单元变化规律，建立了层序地层模式，在此基础上预测南部陡崖式断坡带和北部缓坡式弯折带是低位域砂体和隐蔽岩性油气藏形成的有利区带．     

油田开发中的相态特征及流体组份研究--以大张坨凝析气藏为例

大张坨凝析气藏是在我国发现的高含量凝析气藏之—．开发中据相态特征及流体组份研究结果，适时调整开发方式．1994年开始试采，1995年初实施循环注气开发．该气藏的开发经历了衰竭试采循环注气2个开采过程，开发过程中定期取地层流体样品进行相态特征和流体组份研究，并注重其成果的应用，凝折油采出率29．0％，取得了较好的开发效果．证实了相态研究在凝析气藏循环注气开发全过程应用的重要性．