Electron microscopy study of domain structure due to phase transitions in natural perovskite

Transmission electron microscopy on natural calcium metatitanate perovskite (dysanalyte) reveals the following twin laws in the orthorhombic (space group Pbnm) phase: reflection twins on the {110} and {112} planes, and 90° rotation twins about the [001] axis (referred to as [001]_90° twin). Single crystals that were heattreated and quenched from above 1585 K exhibit a dramatic change in domain structure compared with the starting material and specimens quenched from T < 1470=" k.=" mutually=" perpendicular=" {110}=" and=">_90° twins are observed throughout the crystal, forming a cross-hatched domain texture. 1/2[001] antiphase domains, which are very rarely observed in the starting material, also become dominant in the crystal. This change in domain structure is interpreted as due to a structural phase transition in perovskite at a temperature below 1585 K. From the point symmetry elements that describe the twin laws and the translational elements that relate the antiphase domains, the most likely phase near 1585 K is tetragonal with space group P4/mbm. These results are consistent with high-temperature powder X-ray diffraction study. On the other hand, density of the {112} twins is increased significantly in the crystal quenched from 1673 K. Twin domains are either bound by mutually perpendicular {110} and (001) walls, or by {112} walls with {110} twin domains within the polygonal {112} domains. Both twin density variation and domain morphology suggest that the crystal may be cubic at this temperature. Microstructure of a single crystal deformed at 1273 K and 3.5 GPa (within the orthorhombic stability field) is morphologically quite distinct from that of the heat-treated specimens. Dislocations dominate the microstructure and often interact with twin domain boundaries.A National Science Foundation Science and Technology Center     

福建石炭纪岩相古地理分析

笔者总结了福建省石炭纪生物地层与岩石地层的研究成果,提出了生物地层与岩石地层的划分对比。在详尽的相分析基础上对该纪地层进行了相系、相、亚相及微相的划分,并按“优势相”的原则分期编制了林地期、黄龙期及船山期的岩相古地理图。笔者采用“相、层、位”控矿观点对石炭纪的矿产成因及成矿规律作了探讨。     

19802000北京市农业土地生产性的变动分析

根据1980、1990、2000年的统计资料和实地走访观察,本文分析了北京市乡镇一级的粮食作物、蔬菜作物和果品作物的分布格局及农业土地生产性近20年的变化。研究认为:1980年北京农业生产分布格局与土地生产性为比较典型的杜能模式;随着农业经营的多样化,1990年和2000年北京农业土地生产性呈现出多样的分布格局;北京粮食作物、蔬菜作物、果品作物的分布格局及农业土地生产性近20年的变化与此阶段的农业生产政策、农业以外的社会经济活动变化有较强的关联性;对北京以上问题的研究为验证杜能、辛克利亚、布莱昂特城市周边农业地域研究经典理论的演变提供了实证案例。     

Uniaxial compression and tension tests of anthracite and loading rate dependence of peak strength

The mechanical characteristics of coal under uniaxial compressive stress and uniaxial tensile stress are key factors in investigations of the stability of galleries and coal faces, and are vital considerations for the efficient design of coalmines, disaster prevention, and environmental preservation. These mechanical characteristics have long been a topic of research, but remain insufficiently understood. In this study we performed uniaxial compression tests and uniaxial tension tests on coal, with particular attention to two concerns. The first was to measure the loading rate dependence of the peak strength of coal. Coal shows high sample-to-sample scatter in strength; test methods that are successful in comparatively homogeneous rock types cannot be used for coal. We therefore used an alternative test method that was recently developed by the authors. Anthracite samples were subjected to alternating slow and fast strain rates. Measured variations in stress during this process were used to estimate the loading rate dependence of peak strength. The second objective was to obtain complete stress–strain curves for coal under uniaxial tensile stress. It is difficult to hold samples secure during a tensile test; consequently, such curves have yet to be obtained. This study presents a successful application of the authors' method to the analysis of coal samples, yielding a complete stress–strain curve under tensile stress. The two methods presented here hold promise for application not only to anthracite but also to a wide variety of coals. It is possible to derive the values of the constants used in constitutive equations from the obtained experimental results. Once these equations are determined, they can be incorporated into finite-element software to investigate various time-dependent behaviors of coal and aid in the efficient design of coalmines and the prevention of subsidence and mine disasters.     

Exploiting the dual functions of polymer depressants in fine particle flotation

Fine hydrophilic particles are known to be entrained with water in flotation of many ores. Flocculation of the hydrophilic particles by polymer depressants could potentially reduce the mechanical entrainment of these particles. This paper reports testwork completed on fine particles of several solids, iron oxide, hydroxyapatite and sphalerite, as well as on a relatively coarse quartz sample (− 75 + 38 μm). Dodecylamine was used as a collector for quartz, and several dispersants and polymer depressants, including sodium silicate, sodium metaphosphate, zinc sulfate, cornstarch, corn dextrin and carboxymethyl celluloses (with molecular weights of both 700,000 and 80,000) were used as flotation modifiers. The major part of the testwork involved flotation tests in a 200 mL flotation column. It was observed that flocculation of the fine hydrophilic particles significantly reduced their mechanical entrainment, while dispersion severely aggravated it. Thus, in the flotation separation of synthetic mixtures of the − 75 + 38 μm quartz and fine (reagent grade) iron oxide or hydroxyapatite, polymer depressants that caused flocculation performed better than those that did not cause flocculation.     

贵州南部“半边街式”铅锌矿床地质特征及其成因探讨

贵州省南部地区是全国重要的汞、锑资源分布区。2000年由于产于上泥盆统中铅锌矿的陆续发现,贵州省地矿局启动了以铅锌资源评价和成矿规律研究为主的地质工作,目标是总结铅锌矿产出的地质特征和成矿规律。通过三年的研究认为,该区处扬子准地台、华南褶皱带和右江造山带交汇部位,受晚古生代初期发生的陆内裂谷活动影响,产生了一个与桂中台陷相连的大型沉积凹陷区—黔南台陷沉积区,形成了巨厚碳酸盐和碎屑岩沉积,产生了与裂陷盆地边缘同沉积断层活动有关的低温成矿作用,造成了在晚泥盆纪以前的地层中汞、锑、砷、金、铅锌等矿床沿同沉积断层密集分布。本文通过矿床特征总结和矿床成因探讨,建立了准同生沉积成矿作用模式,旨在为该区寻找这类矿床提供参考和借鉴作用。     

西北地区泥石流沟形态因素的非线性分析——以兰州市为例

以兰州市区96条主要的泥石流沟为例,利用分形理论的统计自相似性对泥石流沟数的累计分布随沟谷形态要素沟道比降、汇水面积和沟道长度的变化进行了分析;并与不同流域形态要素的分维进行了比较,探讨了分维不同的原因。兰州市区泥石流沟三个形态要素均具有统计意义上的自相似性,其中以汇水面积显示出分维最小(0.46),沟道长度次之(0.71),沟道比降最大(1.09)。分维的大小描述了作为系统的沟谷及其泥石流的形成的空间结构,即分形结构,同时也反映了不同形态要素对系统所起作用的差异,分维越小,所起作用越显著。其结果对西北干旱半干旱地区石流灾害的进一步研究与防治提供了新的思路。     

Biological and Geochemical Record of Anthropogenic Impacts in Recent Sediments from Lake Pupuke, Auckland City, New Zealand

Frozen sediment cores from Lake Pupuke in Auckland City, New Zealand, contain a high resolution decadal to annual scale record of changing lake paleoenvironments and geochemistry that reflects changing landuse and hydrology in the catchment over the past c. 190 years. A reliable chronology is available from AMS ¹⁴C and ²¹⁰Pb dating of the sediments, with the timing of the older part of the record supported by the first appearance of pollen of introduced Pinus and Plantago lanceolata associated with European settlement of Auckland in the early 1840s. Diatom stratigraphy, sediment elemental and carbon isotope geochemistry reflect changes in sediment sources and lake conditions commensurate with European development of the Lake Pupuke catchment, in particular enhanced algal productivity controlled by the influx of nutrients after c. 1920 AD. Attempts to prevent nuisance algal blooms in 1933, 1934 and 1939 using CuSO₄ addition produced Cu spikes in the sediment that allowed confirmation of the accuracy of the ²¹⁰Pb chronology. Hence, the elemental and isotopic composition of the Lake Pupuke sediments reflect the timing of significant anthropogenic activities, rather than climatic variations, that have occurred within the watershed over the past c. 190 years. The comparison of records of land use change in the catchment with the multi-proxy record of changes in the sediments usually allowed unambiguous identification of the signatures of change and their causes.     

Towards models of strategic spatial choice behaviour: theory and application issues

Models of spatial choice behaviour have been around in geography urban planning for decades to assess the feasibility of planning actions or to predict external (competition) effects on existing destinations. Although these models differ in terms of complexity and key concepts, they all have in common that spatial choice behaviour is predicted as a function of the attributes of the choice alternatives and distance or travel time separation only. None of these models do take into account that the attributes of choice alternatives and travel time may be highly non-stationary and that often the utility that people derive from visiting a particular location also depends on the choice behaviour of other individuals. Under these circumstances, individuals may exhibit strategic choice behaviour. That is, they will choose particular choice options taking into account their expected behaviour of others such as to maximize their own utility. The purpose of the proposed paper is to discuss possible models of strategic choice behaviour for these urban planning problems. Theory will be outlined and some critical issues in the application of such models to problems of spatial choice will be discussed.