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131.
132.
贵州西北部基性侵入岩锆石U-Pb年代学、岩石地球化学特征 及其与铅锌成矿关系初探 总被引:1,自引:0,他引:1
贵州西北部发育多处基性侵入岩,总体规模较小(约0.25 Km2),多沿深大断裂侵位,出露于铅锌矿点外围,本文对猫猫厂、凉山两处矿点附近的儿马冲和白岩庆两地小型基性侵入岩进行了重点研究。侵入岩主要岩性为细粒辉长岩,造岩矿物主要为拉长石、普通辉石。SiO2范围为49.60-51.09 wt%,MgO从3.88-4.27 wt %,TiO2为3.69-3.85 wt %。LA-ICP-MS锆石U-Pb定年结果为268.3±7.4 Ma,显示岩浆侵位于二叠纪。基性侵入岩的微量元素蛛网图呈OIB型特征,富集大离子亲石元素(LILE)、轻稀土元素(LREE),亏损重稀土元素(HFEE),相对亏损高场强元素(Nb,Ta),有Sr、Y亏损,Pb富集。(87Sr/86Sr)i范围0.706749~0.707069,(143Nd/144Nd)i范围0.512313~0.512363,εNd(t)范围0.2~1.2;源区熔融深度处于石榴石橄榄岩相深度,可能经历了1-3 %的部分熔融,处于亏损石榴石二辉橄榄岩相向原始石榴石二辉橄榄岩相的过渡区。成岩过程中发生了单斜辉石、斜长石等矿物分离结晶,受到了有限的地壳混染作用,未经历明显的AFC过程。地壳物质在地幔源区中的加入可能是造成地幔富集的主要原因。侵入岩与成矿作用之间的关系,主要通过两方面所表现。一方面是二者间构造活动上的耦合性。另一方面是基性岩在成矿过程中可能发挥了重要的化学屏障层作用。 相似文献
133.
Light hydrocarbons (LHs) are one of the main petroleum fractions in crude oils, and carry much information regarding the genetic origin and alteration of crude oils. But secondary alterations—especially biodegradation—have a significant effect on the composition of LHs in crude oils. Because most of the LHs affected in oils underwent only slight biodegradation (rank 1 on the biodegradation scale), the variation of LHs can be used to describe more the refined features of biodegradation. Here, 23 crude oils from the Dawanqi Oilfield in the Tarim Basin, NW China, eleven of which have been biodegraded to different extents, were analyzed in order to investigate the effect of slight to minor biodegradation on C6–C7 LHs. The study results showed that biodegradation resulted in the prior depletion of straight-chained alkanes, followed by branched alkanes. In slight and minor biodegraded oils, such biodegradation scale could not sufficiently affect C6–C7 cycloalkanes. For branched C6–C7 alkanes, generally, monomethylalkanes are biodegraded earlier than dimethylalkanes and trimethylalkanes, which indicates that branched alkanes are more resistant to biodegradation, with the increase of substituted methyl groups on parent rings. The degree of alkylation is one of the primary controlling factors on the biodegradation of C6–C7 LHs. There is a particular case: although 2,2,3-trimethylbutane has a relative higher alkylation degree, 2,2-dimethylpentane is more resistant to biodegradation than 2,2,3-trimethylbutane. 2,2-Dimethylpentane is the most resistant to biodegradation in branched C6–C7 alkanes. Furthermore, the 2-methylpentane/3-methylpentane and 2-methylhexane/3-methylhexane ratios decreased steadily with increasing biodegradation, which implies that isomers of bilateral methyl groups are more prone to bacterial attack relative to mid-chain isomers. The position of the alkyls on the carbon skeleton is also one of the critical factors controlling the rate of biodegradation. With increasing biodegradation, Mango’s LH parameters K1 values decrease and K2 values increase, the values of n-heptane and isoheptane decrease, and the indices of methylcyclohexane and cyclohexane increase. LH parameters should be applied cautiously for the biodegraded oils. Because biodegraded samples belong to slight or minor biodegraded oils, the values of n-heptane and isoheptane from Dawanqi Oilfield can better reflect and determine the “Biodegraded” zone. When the heptane value is 0–21 and the isoheptane value is 0–2.6, the crude oil in Dawanqi Oilfield is defined as the “Biodegraded” zone. 相似文献
134.
为缓解内蒙古河段"二级悬河"形势,以黄河上游沙漠宽谷河段为研究对象,以龙羊峡水库、刘家峡水库为调控主体,开展黄河上游水沙调控研究。建立了输沙量、发电量最大的单目标模型以及多目标模型;分别采用自迭代模拟算法、逐次逼近动态规划算法(DPSA)和改进的非支配排序遗传优化算法(NSGA-Ⅱ)求解模型;设置了初始、常规、优化和联合优化4种方案。通过实例计算,联合优化调度方案的区间总冲刷量达到了0.38亿t,梯级发电量148.22亿kW·h。该方案以较小的电量损失换来了输沙量的大幅度增加,水沙调控效果显著,推荐为最优方案。研究成果量化了水沙调控效果和各目标间的转化规律,为开展黄河上游水沙调控提供了决策依据,具有重要的应用价值和实际指导意义。 相似文献
135.
Microbially Induced Sedimentary Structures (MISS) are primary sedimentary structures that arise syndepositionally from microbial community activity. Especially valuable are MISS for the analysis of early Archean (and extraterrestrial) deposits. However, most reports of MISS have focused on the Precambrian and Phanerozoic mass extinction marine sediments, and only a few and terrestrial MISS have been studied. The MISS presented in this paper, which mainly consists of mat growth feature, mat destruction feature and mat decay feature, are well preserved in terrestrial clastic rocks around the P-T boundary in Xiyang area, western Henan. Large U ridges, oriented sand quartz, mica grains and thin clayey laminae arranged parallel to bedding plane are the main features visible under the microscope. Several lines of evidence indicate that the Xingyang MISS are of biogenic origin. Abundant MISS in Xingyang may indicate the degradation of terrestrial ecosystems and proliferation of microbial mats immediately after the severe Permian-Triassic mass extinction. Study aiming at MISS helps to analyze their space distribution in the globe and to probe into links between microbial proliferation and environmental stresses following the end-Permian mass extinction in terrestrial ecosystems. 相似文献
136.
昆阳群的形成时代、沉积环境、源岩性质等一直存在较大争议,为了查明滇中地区昆阳群的物源及其形成的构造环境,文章在分析昆阳群沉积组合和沉积相的基础上,对昆阳群3件变质砂岩样品中的碎屑锆石进行LA-ICPMS锆石U-Pb年龄测定,对昆阳群20件极低级变质碎屑岩进行地球化学分析。从昆阳群黄草岭组、黑山头组和美党组中分别获得了最年轻的谐和年龄为984.0 Ma、945.0 Ma和954.0 Ma;碎屑锆石年龄峰谱显示,在1.0 Ga、1.35Ga、1.73 Ga和2.44 Ga出现了统计峰值,其年龄主要集中在1.73 Ga和1.35 Ga。表明昆阳群源区主要经历了1.0 Ga、1.35 Ga、1.73 Ga和2.44 Ga的构造热事件,资料显示扬子地块西南缘出露的大红山群形成时代为1.7 Ga,格林威尔期的构造热事件时期为1.0~1.3 Ga。此外,地球化学分析结果表明昆阳群源岩主要是形成于大陆岛弧—活动大陆边缘的石英质旋回沉积、长英质岩石和少量镁铁质岩石。在中元古代晚期—新元古代早期(0.95~1.0 Ga),Rodinia超大陆形成阶段,在扬子地块西南缘的弧后前陆盆地中形成昆阳群的沉积组合,物源主要来自扬子地块西南缘的大红山群和格林威尔期岛弧的岩石。 相似文献
137.
针对普通凝胶抗温能力较差难以适用于高温地层堵漏作业的问题,通过设计合成抗高温凝胶主剂GN-1并运用二次交联技术,研发了新型抗高温凝胶堵漏材料。优选配方为:淡水+1.5%GN-1+0.15%地面交联剂+1%井下交联剂+0.2%抗氧化剂。通过热滚老化与高温流变测试相结合的手段对凝胶抗温能力进行评价。结果表明,该凝胶材料具有良好的热稳定性,在180 ℃下老化24 h后,7.34 s-1下剪切粘度>10000 mPa?s。大幅加重后180 ℃老化24 h仍能保持较好的粘弹性。此外还考察了不同温度和pH值下的成胶性能以及与聚磺钻井液体系的配伍性,为抗高温凝胶堵漏材料在现场的应用奠定基础。 相似文献
138.
139.
Recent studies have suggested that large rivers play important roles in mobilizing and transporting black carbon (BC) from land to the ocean. However, the influence of the Changjiang and Huanghe, the two largest rivers in China, on the fate of BC has not been determined. In this paper, we present measurements of BC in both the dissolved and particulate phases in the Changjiang and Huanghe Rivers and in the coastal waters of the East China Sea (ECS). Our results show that dissolved black carbon (DBC) accounted for 3.0 ± 0.4 % and 4.8 ± 3.6 % of the total DOC pool in the Changjiang and Huanghe Rivers and 3.4 ± 0.6 % of the DOC pool in the coast of the ECS. In addition, particulate black carbon (PBC) accounted for 13 ± 0.9 % and 22 ± 11 % of the POC pool in the Changjiang and Huanghe Rivers, respectively. We calculate that the Changjiang and Huanghe transported 4.7 × 1010 gC and 1.7 × 109 gC of DBC, and 2.0 × 1011 gC and 1.2 × 1010 gC of PBC to the ECS and Bohai Sea in 2015. The large amounts of BC transported by the two rivers represent a major sink of anthropogenically derived organic carbon and could have a significant impact on the ecosystem and carbon cycling in China’s marginal seas. 相似文献
140.
Scapharca broughtonii is a commercially important and over-exploited species. In order to investigate its genetic diversity and population structure, 43 novel polymorphic microsatellites were isolated and characterized. The number of alleles per locus ranged from 3 to 22 with an average of 6.93, and the observed and expected heterozygosities varied between 0.233 and 1.000, and 0.250 and 0.953, with an average of 0.614 and 0.707, respectively. Three highly informative multiplex PCRs were developed from nine of those microsatellites for S. broughtonii. We evaluated and validated these multiplex PCRs in 8 full-sib families. The average polymorphism information content (PIC) was 0.539. The frequency of null alleles was estimated as 3.13% of all the alleles segregation based on a within-family analysis of Mendelian segregation patterns. Parentage analysis of real offspring demonstrated that 100% of all offspring were unambiguously allocated to a pair of parents based on 3 multiplex sets. Those 43 microsatellite loci with high variability will be helpful for the analysis of population genetics and conservation of wild stock of S. broughtonii. The 3 sets of multiplex PCRs could be an important tool of pedigree reconstruction, population genetic analysis and brood stock management. 相似文献