流体在岩浆型铬铁矿和铂族元素成矿过程中的作用及意义

镁铁- 超镁铁岩是揭示地幔物质组成和壳幔相互作用的重要窗口，也是Ni- Cu- PGE- Cr等金属矿产资源的重要载体。不同的镁铁- 超镁铁岩体赋矿特征明显不同：蛇绿岩以产出铬铁矿床为特征，阿拉斯加型岩体主要赋含铂族元素(PGE)矿床，大型层状岩体则可同时产出铬铁矿床、PGE矿床和Cu- Ni硫化物矿床。这种成矿差异显然与赋矿岩体形成的构造背景、母岩浆经历的岩浆演化过程有关，但缺少关键控制因素的研究。前人对上述不同种类矿床的研究工作主要集中于地幔源区的部分熔融、上升过程中或岩浆房内的围岩混染和结晶分异等岩浆过程，而极少关注流体作用。近年来，实验岩石学和岩石地球化学的研究均表明幔源岩浆演化过程中的流体活动可能对成矿元素的富集迁移起到至关重要的作用，同时这些成矿元素的赋存状态和分配系数也在不断更新。厘清Cr和PGE在熔体演化——尤其是流体出溶过程中的地球化学行为，刻画并揭示其迁移富集、分离和再富集的成矿过程及控制因素，已成为当前岩浆矿床研究的热点。本文围绕富水流体与铬铁矿和PGE成矿关系的科学问题，总结了不同镁铁- 超镁铁岩体的成矿差异以及铬铁矿和PGE矿床成矿过程中的流体活动记录，提出流体性质和组分对铬铁矿和PGE迁移富集的控制作用，强调有必要开展蛇绿岩、大型层状镁铁- 超镁铁岩体和阿拉斯加型岩体的对比研究。     

基于土地适宜性评价与元胞自动机模型的城市开发边界划定方法

城市开发边界的划定可以在一定程度上引导城市空间的良性扩张。为了研究边界划定的方法,以我国某港口城市作为研究区域,在空间增长模拟的方向进行探索。研究中借助土地适宜性评价和元胞自动机边界工具,构建既符合生态资源环境要求又符合城市发展需要的边界划定,同时,为了实现城市用地健康和动态管控举措,提出了建立健全土地用地管理机制的要求。     

毫秒时间尺度太阳微波辐射新特征

自1990年6月北京天文台太阳射电偏振仪投入实测以来,观测到一百多个“Spike”和短时标精细结构微波幅射,其中包括一些新的微波幅射特征。本文给出了主要的四点特征:(1)窄带辐射;(2)快速偏振逆转;(3)快速频率漂移;(4)不同时标的准周期振荡。     

察尔汗盐湖低品位卤水自然蒸发试验研究

察尔汗盐湖是一个以卤水钾镁盐矿为主的大型综合性盐类矿床,盐湖东部潜卤水水化学类型为氯化物型,从KCl等组份含量来看,属低钾高钠低镁的卤水。对该类型卤水进行自然蒸发试验,确定盐类结晶析出顺序和光卤石矿物的最佳分离点,取得光卤石矿的产率和光卤石中KCl含量等基础数据,以对该卤水工业利用性能作出评价。     

河南省城区经济发展研究

文章首先介绍了城区经济的概念、特征和类型，在分析河南省城区经济发展状况的基础上，论述了该省城区经济的地位和作用，提出了河南省城区经济发展构想以及对策措施。     

An experimental study of anorthosite dissolution in lunar picritic magmas: Implications for crustal assimilation processes

Experiments characterizing the kinetics of anorthosite dissolution in lunar picritic magmas (very low-Ti, low-Ti, and high-Ti picritic glasses) were conducted at 0.6 GPa and 1250-1400 °C using the dissolution couple method. Reaction between the anorthosite and lunar picritic magmas at 1250-1300 °C produced a spinel + melt layer. Reaction between the anorthosite and an olivine-saturated low-Ti magma at 1250-1300 °C produced a crystal-free region between the spinel + melt layer and the olivine-saturated magma. The anorthosite dissolution experiments conducted at 1400 °C simply dissolved anorthosite and did not result in a crystal-bearing region. The rate of anorthosite dissolution strongly depends on temperature and composition of the reacting melt. Concentration profiles that develop during anorthosite dissolution are nonlinear and extend from the picritic glass compositions to anorthite. These profiles feature a large and continuous variation in melt density and viscosity from the anorthosite-melt interface to the initial picritic magmas. In both the low-Ti and high-Ti magmas the diffusive fluxes of TiO₂, Al₂O₃, and SiO₂ are strongly coupled to the concentration gradients of CaO and FeO. Anorthosite dissolution may play an important role in producing the chemical variability of the lunar picritic magmas, the origin of spinel in the lunar basalts and picritic glasses, and the petrogenesis of the high-Al basalts.     

Effect of some additives on synthesis of zeolite from coal fly ash

Hydrothermal conversion of fly ash into zeolites was conducted and the effects of the addition of sodium halide and waste solutions produced after zeolitization of fly ash, as well as the adjustment of the Si/Al ratio prior to synthesis process on the formation and cation exchange capacity (CEC) of zeolite product were evaluated. Both the addition of NaCl and NaF ameliorated the crystallinity and CEC of synthesized zeolite, but NaF had a better improvement effect. Na⁺ was considered to enhance the crystallization of zeolite, while F⁻ favored the dissolution of fly ash. The type of zeolite formed depended on the Si/Al ratio of the starting material prior to the nucleation and crystallization of zeolite. The adjustment of the Si/Al ratio of fly ash by addition of Na₂SiO₄ and Al(OH)₃ changed the type and CEC of zeolite. Waste solutions contained large amount of Si and little Al due to the formation of a zeolite named NaP1 in zeolite terminology with the Joint Committee of Powder Diffraction Standard (JCPDS) code of 39-0219. The alkalinity decreased largely. As a result, the CEC value of zeolite products synthesized with waste solution as alkali source decreased. The supplementation of new alkali to adjust the alkalinity of waste solution could enhance the CEC of synthesized product. It was concluded that: (1) addition of sodium halide and adjustment of the Si/Al ratio prior to synthesis can improve the quality of zeolite; (2) waste solutions produced following the zeolitization of fly ash can be reused as an alkali source in the activation of fly ash; zero-emission of waste solution in the synthesis of zeolite from fly ash is possible.     

用于砾石夹层钻进的新型PDC钻头的研制与使用

无压浸渍工艺生产的PDC石油钻头钻遇砾石夹层不适应。根据砾石夹层砾石坚硬、软硬互层、非均质、研磨性强的特点，研究了新型PDC钻头，在钻头结构上主要采取外抛内锥带辅助切削齿的结构形式，在复合片上主要采用非平面结合方式，即采用双向多条直槽非平面结合。按此方案设计与生产了3只钻头，分别在3口井试用，直接钻穿砾石夹层馆陶组地层井段，钻井效率提高26%，突破了砾石夹层钻进不能使用PDC钻头的禁区。     

Research progress on international rivers in Asia

With the regional population growth, socioeconomic development, more and more attention has been paid to issues on the shared water allocation and the transboundary eco-security conservation during the development of water resources in the international rivers. In this paper, the existing major problems on transboundary waters in different sub-regions of Asia, such as water shortage, transboundary waters pollution, fragile eco-environment are discussed. Then, the key scientific issues to be concerned in the next study progress on the basis of the analyses of the new research directions and focus fields are raised: (1) unpredicted changes of the hydrologic and water system, and their impacts on the allocation of the sharing waters by global changes; (2) models of the international cooperation on the international rivers on the studies of international and national water laws or regulations, policies, the relative experiences and the case studies; (3) quantificational assessment on environmental flow, available water, and the comprehensive functions and values of the international watercourse system; (4) studies on transboundary aquatic bio-diversity maintenance, transboundary pollution supervision and treatment under the rules and principles accepted by the riparian states; (5) issues on transboundary compensation at the rules of “payments for using”, “payments for harm” and “compensation for benefit”; (6) using advanced 3S techniques to promote the integrated watershed development and management; and so on.     

吉林伊通盆地莫里青断陷古近系双阳组储集层成岩作用研究

古近系双阳组是在吉林省伊通盆地莫里青断陷中，油气赋存的主要层位,储层主要为湖底扇和扇三角洲的砂体。依据双阳组储层的大量薄片、扫描电镜、粘土矿物分析的资料研究了该储集层的成岩作用。研究结果表明双阳组储集层：成岩作用经历了压实、压溶、胶结、交代和溶解6方面的作用。双储集层中的自生粘土矿物蒙皂石向伊利石转化具有明显的特征：主要演化过程经历了蒙皂石渐变带，第一迅速转化带和第二迅速转化带，相应的成岩作用阶段可划分为早成岩阶段B期、晚成岩阶段A1期和晚成岩阶段A2期。依据在垂向上的成岩变化,建立了莫里青断陷双阳组储集层的成岩作用演化序列。在垂向上成岩作用的类型和强度均存在明显的差异，造成了储层物性的垂向分带。