沉积物中硬质粘土层的研究进展

大量的钻孔资料表明,平原地区及其海域沉积物中普遍有硬质粘土层的存在。硬质粘土层在工程地质、地理学研究等方面具有重要的价值,它不仅是高层建筑的持力层,而且是研究全球环境变化事件、古气候演变的良好载体。该文阐述了硬质粘土层的一般特征、成因以及在粒度、地球化学元素、年代学、沉积环境等方面的研究进展,并展望了硬质粘土层在年代、物质来源和沉积环境等方面的研究方向,认为黄河三角洲硬质粘土层研究较少,需要开展大范围的、系统深入的、多学科的宏观和微观综合分析,挖掘硬质粘土层蕴含的古环境意义和应用价值。     

Rock magnetic properties and palaeomagnetic results of sediments from a stone implement layer in the Bose Basin,Guangxi

Directional samples were taken to study rock magnetism and palaeomagnetic records from the Dong- sheng profile, which is 5 m thick and on the northwest edge of the Bose Basin. Mineralogy and rock magnetism of typical samples indicate that coarse granular titanomagnetite, and fine-grained hematite, superparamagnetic maghemite formed by pedogenesis are in the sediment, which has undergone many transformative processes during different stages of pedogenesis. Parallel samples were taken for thermal demagnetization (TH) (0 to 680℃) and alternating field (AF) demagnetization (0 to 80 mT) respectively. Experimental results of these two kinds of demagnetization illustrate that there are two or more magnetic components in the samples. Intensity of NRM decreases by almost 60% to 90% rapidly when the temperature ranges from 100℃ to 350℃, with a steady magnetic component. It is impossible to analyze the magnetic components at high temperature because those fluctuate widely when the temperature is higher than 400℃. Steady magnetic components from 100℃ to 350℃ indicate that the remanence was mainly carried by fine-grained hematite formed by pedogenesis, reflecting a change in the geomagnetic field while the magnetite was being oxidized into hematite by chemical weathering after deposition. The formative age of the sediments cannot be obtained by magnetic methods in this profile.     

Sensitivity assessment of strontium isotope as indicator of polluted groundwater for hydraulic fracturing flowback fluids produced in the Dameigou Shale of Qaidam Basin

Hydrogeochemical processes that would occur in polluted groundwater and aquifer system, may reduce the sensitivity of Sr isotope being the indicator of hydraulic fracturing flowback fluids(HFFF) in groundwater. In this paper, the Dameigou shale gas field in the northern Qaidam Basin was taken as the study area, where the hydrogeochemical processes affecting Sr isotope was analysed. Then, the model for Sr isotope in HFFF-polluted groundwater was constructed to assess the sensitivity of Sr isotope as HFFF indicator. The results show that the dissolution can release little Sr to polluted groundwater and cannot affect the εSr(the deviation of the 87 Sr/86 Sr ratio) of polluted groundwater. In the meantime, cation exchange can considerably affect Sr composition in the polluted groundwater. The Sr with low εSr is constantly released to groundwater from the solid phase of aquifer media by cation exchange with pollution of Quaternary groundwater by the HFFF and it accounts for 4.6% and 11.0% of Sr in polluted groundwater when the HFFF flux reaches 10% and 30% of the polluted groundwater, respectively. However, the Sr from cation exchange has limited impact on Sr isotope in polluted groundwater. Addition of Sr from cation exchange would only cause a 0.2% and 1.2% decrease in εSr of the polluted groundwater when the HFFF flux reaches 10% and 30% of the polluted groundwater, respectively. These results demonstrate that hydrogeochemical processes have little effect on the sensitivity of Sr isotope being the HFFF indicator in groundwater of the study area. For the scenario of groundwater pollution by HFFF, when the HFFF accounts for 5%(in volume percentage) of the polluted groundwater, the HFFF can result in detectable shifts of εSr(ΔεSr=0.86) in natural groundwater. Therefore, after consideration of hydrogeochemical processes occurred in aquifer with input of the HFFF, Sr isotope is still a sensitive indicator of the Quaternary groundwater pollution by the HFFF produced in the Dameigou shale of Qaidam Basin.     

山东省蓬莱市蝎子顶金矿地质特征

蓬莱市蝎子顶金矿容矿构造为NW向断裂,具NW向成串分布的特点。NW向压扭性断裂与其派生的断裂裂隙系统是该区金矿床赋存空间的重要构造标志,构造破碎带中的钾化、硅化、黄铁绢英岩化等蚀变是一种直接找矿标志。通过对矿床地质特征的研究,认为该矿床属岩浆低中温热液充填交代蚀变岩型金矿床。     

英峰岭剖面红土的粘土矿物和化学特征与成土环境关系

地球化学与粘土矿物学研究表明,广东雷州半岛英峰岭多期红土是拉弱武岩红土化初级阶段的产物,由剖面底层至顶层,红土成熟度依次递增。各层红土中主要粘土矿物含量和粘土的Ｆｅ２Ｏ３含量,以及工土和粘土的氧化,淋溶,富铁铝等化学特征系数与红土埋深之间呈波动起伏的关系。     

岷县漳县6.6级地震前区域地壳运动变形背景与断层形变异常特征

利用甘肃岷县漳县6.6级地震区所在的青藏块体东北缘地区的区域水准、GPS、流动重力和跨断层短测线等地形变监测资料,结合地质构造、动力环境和已往的研究结果,分析了不同类型资料反映的震前区域性地壳变形背景、断层形变异常特征和可能的机理.结果认为：（1）岷县漳县6.6级地震前西秦岭、六盘山等构造区不同程度地存在着GPS水平挤压闭锁高应变积累、垂直隆升异常高梯度带和重力升、降差异剧烈变化等中长期背景;（2）震前到震时发震断裂附近及其外围相关构造区域断层形变异常在空间和时间上的起伏波动变化显著,尤其是汶川地震以来的波动变化在一定程度上反映了与本区构造比邻的龙门山断裂带剧烈右旋错动对本区的影响,与本次岷县6.6级地震过程有关;（3）本区有地形变监测资料积累以来缺乏6级以上震例,虽然存在不同程度的中长期形变背景异常,但何时进入短期-短临阶段确实很难把握,需要不断积累总结和探索提高.     

低周反复荷载下Q460钢材框架柱抗震性能分析

为了进一步完善Q460钢材在抗震设计规范中相关限值的要求,本文利用有限元软件ABAQUS,以轴压比、翼缘宽厚比、腹板高厚比和壁板宽厚比为变量,建立了共48根“工”字型框架柱和“箱”型框架柱,分析了其抗震性能。结果表明:翼缘宽厚比对框架柱的能量耗散系数影响较小;能量耗散系数随轴压比、腹板高厚比（“工”字型）和壁板宽厚比（“箱”型）增大而明显减小;框架柱的极限承载力随轴压比的减小及壁板宽厚比和翼缘宽厚比的增大而逐渐增大,当腹板高厚比接近规范限值时,承载力下降趋势明显增大。与采用Q235钢材的框架柱相比,Q460钢材框架柱的延性较小,仅为2左右;当采用Q460钢材时,“工”字型框架柱的极限位移角限值建议取为0.03,“箱”型框架柱的极限位移角限值建议取为0.032。规范中对翼缘宽厚比限值的规定偏于保守,其值最大可取至9。无论是“工”字型框架柱还是“箱”型框架柱,其腹板高厚比均不宜过大。Q460钢材框架柱的刚度退化率随轴压比的增大而增强,且翼缘宽厚比越大,腹板高厚比越小,柱的初始刚度越大,刚度退化程度越明显。     

热力强迫对台风次级环流的作用

本文利用无量纲的台风次级环流方程,用西太平洋地区11年的综合台风资料,计算了热力因子强迫的次级环流。通过计算,得到主要结论如下: 1.非绝热加热和积云热量垂直混合是主要的热力强迫因子,二者的作用具有同样量级。 2.热量的湍流涡旋通量及积云的热量水平输送作用都比较小。 3.Ekman抽吸与积云热量垂直混合是相互促进,共同发展的。有利于次级环流的增强。     

Methods and procedures to determine the outer limits of the continental shelf beyond 200 nautical miles

This paper establishes techniques and methods to determine a variety of boundaries associated with 200 nautical miles beyond the continental shelf. The methods, based on topography, slope and second-deriv- ative profile integrated analysis, are now able to identify automatically the foot of the continental slope （FOS）. By analyzing the sedimentary profile, the points of 1% sediment thickness are recognized. Through the intersection, cut, deletion and mergence calculation of the extrapolated data set of fLxed-point series, the method succeeds in generating automatically the extrapolated boundaries, including the FOS＋60 M line, the 350 M line, and the 2500 m＋100 M line. In addition, based on the automatic analysis of the topographic profile, it can be applied to determine rapidly the points of maximum water depth. Taking the northern Okinawa Trough （OT） as an example, these methods are used to calculate and examine the boundaries in- cluded in the Submission by the People＇s Republic of China Concerning the Outer Limits of the Continental Shelf beyond 200 Nautical miles in Part of the East China Sea （ECS）; the boundaries thus derived have a solid scientific and rational basis.     

应用GasBench Ⅱ-IRMS优化碳氧同位素分析方法

GasBenchⅡ-连续流稳定同位素质谱仪(IRMS)联用在线分析已成为碳酸盐碳氧同位素分析测试的常用方法,已有研究认为不同的实验条件直接影响δ¹³C和δ¹⁸O同位素测试结果的准确性。但这些报道未对该联用方法所涉及的实验条件进行综合分析。本文系统研究了GasBenchⅡ-IRMS法中各种实验条件(包括排空时间、反应温度、反应时间和色谱分离温度)对碳氧同位素测试结果的综合影响。结果表明:排空时间大于9 min可有效消除空气对测试结果的干扰,不同的反应温度和时间对碳氧同位素分析结果均有一定影响,经条件优化确定反应温度为72℃,反应时间为60 min,色谱分离温度为60℃。在优化的实验条件下,碳氧同位素分析精度分别优于0.03‰和0.05‰,达到了国际分析测试水平。同时,选择合适的同位素数据归一化方法可以进一步保证碳氧同位素测试结果的准确性和可靠性。通过分析近4000件实际样品,对比单一标准物质校准和双标准物质校准同位素归一化方法的计算结果,发现双标准物质校准偏差小于单一标准物质校准偏差,因此建议采用双标准物质校准法进行样品同位素标准化计算。本研究为GasBenchⅡ-IRMS联用技术中实验条件的选取提供了一定的参考,保证碳氧同位素测试结果的可靠性和准确性。同时提出,由于样品成分复杂且不均一,在分析实际样品时需要根据样品的性质进一步对实验条件进行考察。