环渤海湾海洋资源环境承载力定量研究

环渤海湾地区经济发展迅速但开发利用过度,生态问题突出。本文以社会环境学理论、系统论、可持续发展理论等为基础,建立了环渤海湾海洋资源环境承载力评价指标体系,利用单项评价法,以地级市为基本单位对环渤海湾地区的海洋资源环境承载力进行评价。结果表明滨州市的海洋资源环境承载力较好,其次为唐山市和天津市,沧州市的海洋资源环境承载力较弱。     

杭州湾营养盐时空分布特征及其影响研究

文章基于2015年1—12月杭州湾海域12个航次的调查资料,对杭州湾海域营养盐溶解无机氮(DIN)和活性磷酸盐(PO_4~(3-))的月度时空分布特征及其影响进行了探讨。结果表明,杭州湾表层海水DIN和PO_4~(3-)含量空间分布月际间变化明显,其变化受湾内、沿岸径流输入和长江冲淡水影响显著。杭州湾海域12个月DIN含量均超第四类海水水质标准,硝酸盐氮(NO_3~-)占DIN的94%及以上。N/P值处于较高水平,内湾(IB)和外湾(OB)的N/P值季节性变化幅度比中湾(CB)大,海湾生态系统对磷的变化敏感。营养盐-盐度对研究区域的水体混合状况有明显的指示作用,杭州湾营养盐的分布主要受物理混合作用所控制,浮游生物活动对营养盐分布的影响相对较小。     

基于地理坐标的海洋环境监测站位代码设计

为解决目前我国海洋环境监测站位编码不统一、不唯一和不稳定等问题,提高监测数据应用水平和海洋信息化能力,文章参考我国渔区编码规则,基于海洋环境监测站位的地理坐标设计站位代码,并以山东省海域为例具体说明。海洋环境监测站位代码由监测区、监测小区和监测点3个部分组成8位阿拉伯数字,将海域按经、纬度各30′划分监测区并顺序编码0000~9999(第1~4位),将每个监测区按经、纬度各3′划分监测小区并顺序编码00~99(第5~6位),将每个监测小区按经、纬度各0.3′划分监测点并顺序编码00~99(第7~8位)。该代码设计规则仅与监测站位的地理坐标相关,具有统一性、唯一性和稳定性,且容量较大,可满足我国海洋环境趋势性监测和绝大部分海洋环境业务化监测的需要。     

椭圆度-凹坑双缺陷海底管道局部屈曲特性研究

海底管道在制造、埋设以及使用过程中极易产生椭圆度-凹坑双缺陷,双缺陷影响管道局部屈曲,对含椭圆度-凹坑双缺陷海底管道的局部屈曲特性研究十分必要。现行规范中采用等效椭圆度对含椭圆度-凹坑海底管道进行评估,该方法无法准确评估不同缺陷形式的屈曲特性。采用形状系数对含椭圆度-凹坑双缺陷的海底管道进行评估,运用有限元软件ABAQUS进行数值模拟,并进行试验验证。在此基础上对含有不同凹坑深度、不同椭圆度的海底管道进行局部屈曲的数值模拟,计算不同形状椭圆度、含有不同凹坑深度海底管道的形状系数,对其进行敏感性分析。计算结果表明:形状系数对海底管道椭圆度、凹坑深度、径厚比敏感性较强;对凹坑宽度敏感性较弱。     

GPT2模型用于SDCORS反演可降水汽精度评估

利用山东区域及邻近探空站,分析GPT2模型估算气象参数（气温和气压）的精度,并将GPT2模型应用于SDCORS反演可降水汽中,分析评估其精度。研究表明,GPT2模型估算气温和气压的偏差均值分别为-1.61 ℃和0.53 Pa,标准差均值分别为2.84 ℃和4.42 Pa,均方根误差均值分别为3.27 ℃和4.49 Pa;GPT2模型估算的气象参数解算的SDCORS/PWV的偏差均值为1.22 mm,标准差均值为3.05 mm,均方根误差均值为3.46 mm,较GPT模型精度高,可靠性强。对于未配备气象传感器的CORS站,基于GPT2模型估算气温和气压,有助于利用区域CORS反演可降水汽,有效实现对大气可降水量的监测与预报。     

GPS/BDS分类组合定位的指数加权Helmert方差分量估计法

针对北斗卫星导航系统（BDS）星座结构复杂、不同类型卫星观测值残差差异较大的不利条件,将BDS系统中IGSO、MEO、GEO 3种卫星的观测值进行分类定权,提出一种顾及历史权比的指数加权Helmert方差分量估计法来精确确定不同系统之间观测值的权阵。为了验证该方法在GPS/BDS组合定位中的有效性,采用单点定位模型分别进行静态和动态导航实验,并将其定位结果与等权模型以及不考虑指数加权的Helmert方差分量估计方法进行对比。结果表明,采用改进的加权方法,在东、北、天3个方向的定位精度均获得显著提高,在静态条件下,相对于等权模型,改进方法3个方向的定位精度提高幅度分别达到50.0%、51.0%和42.0%;在动态条件下,定位精度提高幅度分别为10.0%、8.0%和9.0%。特别在卫星数量较少、卫星几何图形强度较差时,定位结果的改善效果更为明显。     

珊溪水库地区深部构造探测研究

通过对珊溪水库地区进行深地震反射探测,获得该地区近地表至地壳中部的精细几何结构和深浅构造关系。结果表明,该地区地壳结构在纵向具有明显的分带性,在横向显示出以断层为界的块状结构特点。研究区内走向北西的双溪-焦溪垟断层向深部延伸超过20 km进入中下地壳,为该区域内主要控制性断层,主要影响周围浅部断层的发育,是该地区主要发震构造。     

Total Synthesis of Marine Cyclic Enol-Phosphotriester Salinipostin Compounds

Due to their structural diversity and variety of biological activities, marine natural products have been the subject of extensive study. These compounds, especially phospholipid polycyclic aromatic hydrocarbons, have a wide range of pharmacological applications, including embedded DNA and central nervous system, anti-tumor, anti-virus, anti-parasite, anti-bacterial, and antithrombotic effects. Unfortunately, the insufficient drug sources have limited the development of these compounds. In this study, we isolated salinpostin compounds from a fermentation solution of marine-derived Salinospora sp., which has a common bicyclic enol-phosphotriester core framework, as well as potent and selective antimalarial activities against P. falciparum with EC_(50)=50 nmolL~(-1). The chemical synthesis of these compounds in greater quantities is necessary for their use in bioactivity studies. Thus we explored a short route with high yields and mild reaction conditions, which can generate combinatorial libraries for drug discovery and lead optimization. We developed a new total synthesis method for six cyclic enol-phosphotriester salinipotin compounds and their diastereomers. For the total synthesis of cyclipostin P, we prepared cyclic enol-phosphotriester salinipostin compounds in 10 steps from a readily accessible starting material, 1,3-dihydroxyacetone, and obtained an overall yield of 1.29%. We fully characterized these compounds by proton nuclear magnetic resonance(~1H-NMR), carbon-13 NMR(~(13)C-NMR), and high-resolution mass spectrometry(HRMS) analyses, and found they coincide absolutely with the same compounds reported previously.     

Evolution Characteristics of Government-Industry-University-Research Cooperative Innovation Network for China’s Agriculture and Influencing Factors: Illustrated According to Agricultural Patent Case

Under the special background of China, the cooperative innovation between different government-industry-university-research institutes plays an increasingly important role in the agricultural field. However, the existing literature has paid little attention to it. Considering the cooperation patents, published in the agriculture field stemming from the Full-text Database of China Patents as the study object, the spatial and institutional attribute of the authors as the data source, and by combining the social network and spatial econometrics analysis, this paper analyzes the structure evolution characteristics of cooperative innovation networks of agricultural government-industry-university-research institute in the city level of China in 1985–2014, based on the triple helix theory, with the influence factors discussed. This shows that, 1) since 1985, China's agricultural innovation level has been substantially increased, but the development degree of the cooperative innovation network is low, and the patent cooperation mainly relies on authors in the same unit; 2) enterprises play a leading role in the agricultural cooperative innovation. The effect of the government and hybrid organizations driven by the government is not obvious; 3) the cooperative innovation in the province and city dominates, and a multi-pole pattern has been formed. The cooperative innovation network structure evolves from a single helix empty core and double helix multi core to a double helix hierarchical network; 4) the city's science, education funding and personnel investment are key factors determining the agricultural cooperative innovation, while the agricultural development of the city presents slight negative impacts on it. The spatial mismatch of supply and demand is present in the technical cooperative innovation of China's agriculture. Therefore, the science enhancement and education investment to big agricultural provinces should be promptly implemented.     

Evolutionary dynamics of the Wnt gene family: implications for lophotrochozoans

Journal of Oceanology and Limnology - Genes encoding Wnt ligands, which have important roles in cell communication and organ development, are restricted to multicellular animals. We systematically...