Source and yearly distribution of PAHs in the snow from the Hailuogou glacier of Mountain Gongga,China

Snow samples were collected over a 3-year period from 2012 to 2014 at the Hailuogou glacier of Mountain Gongga (Mt. Gongga) and analyzed for 16 priority polycyclic aromatic hydrocarbons (PAHs) using Gas Chromatography–Mass Spectrometry (GC–MS). The results show that total average levels of the 16 PAHs ranged from 452 to 290 ng·L^?1 with a possible declining trend from 2012 to 2014. Distances between the sampling sites and the emission sources were estimated at typically less than 500 km. The results suggest that the major source of PAHs was from coal combustion, while contributions from automobile exhaust played an important role in more recent years. This finding was in agreement with the characteristics of presence of local industry, residence, and recent development of tourism of the surrounding areas.     

Zircon U‐Pb Age of the Shangxu Gold Deposit from Bangong‐Nujiang Co,Northern Tibet,and Restriction on the Early Cretaceous Orogenic Gold Mineralisation

正Objective The Tibetan Plateau is the largest continent-to-continent collision belt in the world.Two orogenic gold mineralisation belts have been recognized in this collision belt,which are as follows:the Indus-Yarlung Zangbo suture zone orogenic gold belt(IYOG),represented by the Mayoumu and Bangbu gold deposits,and the Ailaoshan     

中国南部及邻区能源资源成矿区带数据集

能源矿产是国家安全和经济发展的战略资源,加强我国及周边地区油气和煤等能源资源的研究和开发利用意义重大。依据板块构造和大陆动力学以及油气与煤成藏地质学理论,以深部构造控制盆—山发育、盆—山耦合和热动力系统控制成矿的研究工作思路,应用70个油气田、471个煤田的基础地质资料,从沉积盆地发育的区域地质特征、成矿地质条件和成矿单元诸多方面,在地理信息系统（GIS）平台上提示了该区板块构造格局与能源资源的时空分布规律。中国南部及邻区能源资源可划分为3个成矿域,每个成矿域又可进一步划分为成矿省、含矿区（盆地）、矿田聚集区带、矿田（油气田）五个级别的成矿区域。数据集由构造带（断裂带和造山带）类型和时代、盆地类型和时代、能源矿产资源类型和丰度、成矿区带等元数据组成。该数据集是在区域大地构造研究的基础上,结合沉积盆地能源矿产（石油、天然气、煤）资源评价资料,综合分析成矿区带特征,利用地理信息系统（GIS）建立的一套完整的数据库,不仅是对中国南部及邻区区域地质认识和沉积盆地能源资源勘查工作成果的集成,而且为国家科学地引导地质找矿工作部署提供理论基础。     

大兴安岭呼中钼多金属矿床成矿流体特征及成矿机制

大兴安岭呼中镇钼多金属矿床产于早白垩世碎裂花岗岩中,矿体形态似层状、脉状或透镜状。成矿阶段分为辉钼矿阶段、铜铅锌阶段、方解石阶段等3个阶段。本矿床中的包裹体主要有气液H_2O包裹体、气相H_2O包裹体、含子矿物H_2O包裹体,CO_2包裹体、CO_2-H_2O包裹体等五大类。辉钼矿阶段均一温度为209.2℃413.4℃,盐度ω(NaCleq)为0.53%16.53%,平均值7.3%,属中低盐度,成矿压力在53.3 68.5 MPa,相应的成矿深度为2 052 2 807 m;铜铅锌阶段为191.5℃351.0℃,盐度ω(NaCleq)为0.88%34.24%,平均值3.96%,属低盐度;方解石阶段207.2℃233.5℃,盐度ω(NaCleq)为3.55%4.18%,平均值3.77%,为低盐度。从辉钼矿阶段到铜铅锌阶段再到方解石阶段,温度及盐度逐渐降低。辉钼矿成矿压力在53.3 72.9 MPa,成矿深度为2 052 2 807 m。成矿过程中发生了CO_2-H_2O不混溶作用,这是导致辉钼矿沉淀的主要机制。矿床类型属中低温浅成热液型矿床。     

从成岩-蚀变特征探讨塔深1井白云岩储层成因

塔深1井钻遇的寒武系地层属于中寒武统阿瓦塔格组和上寒武统丘里塔格下亚群。阿瓦塔格组以灰色-深灰色粉晶-细晶藻白云岩为主,丘里塔格下亚群以灰色-浅灰色晶粒结构白云岩与残余亮晶结构白云岩为主。藻白云岩在阴极发光下以明亮的中等强度砖红色-桔黄色为主要特点,具有相对偏重的δ18O值(-6.3‰~-4.5‰,平均为-5.3‰,VPDB)、相对较高的稀土总量以及与正常海相碳酸盐岩相似的稀土配分样式。晶粒白云岩与残余亮晶结构白云岩在阴极发光下以偏暗的中等强度蓝紫色-砖红色为主要特点,具有相对偏轻的δ18O值(-9.2‰~-5.7‰,平均为-7.5‰,VPDB)、相对偏低的稀土总量、Eu正异常与重稀土明显亏损为特点的稀土配分模式。阿瓦塔格组和丘里塔格下亚群白云岩在上述岩石学特征和地球化学特征上的差异表明储层发育的成岩-蚀变过程存在差异。研究认为,埋藏较深的阿瓦塔格组优质储层的形成受多种因素控制,其中准同生期大气淡水作用下石膏结核的溶解及非稳定碳酸盐矿物的溶解奠定了基础,后期成岩改造及流体作用进行了强化,局部遭充填破坏。     

Occurrence and conceptual sedimentary model of Cambrian gypsum-bearing evaporites in the Sichuan Basin,SW China

During the Cambrian, gypsum-bearing evaporites formed in the Sichuan Basin, SW China. These rocks are important for oil and gas sealing, but details of their distribution and origin are not well established. This study examines the regional distribution and origin of the gypsum-bearing evaporites using a comprehensive analysis of drilling data from 34 wells, 5 measured cross-sections in the basin and surrounding area, and 96 maps of area-survey data. Results show that in the stratigraphic succession, the gypsum-bearing evaporites occur mainly in the Lower Cambrian Longwangmiao Formation, the Middle Cambrian Douposi Formation, and the Middle-Upper Cambrian Xixiangchi Group. Geographically, the rocks are found mainly in the southeastern part of the basin, and the distribution of deposits shows an overall SW-NE trend. The sedimentary environments for evaporite formation were evaporative lagoon and inter-platform basin in a platform setting. Gypsum was generated by the underwater concentration of sea water in a strongly evaporative environment. Both an evaporative restricted platform and a mixeddeposition restricted platform model appear to be applicable to the development of gypsum in the Sichuan Basin. The gypsum-bearing evaporites with the best sealing capacity are located mostly in the southeastern part of the basin. These constraints can be applied directly to regional exploration, and have implications for the regional paleogeography and paleoclimate.     

吉林永吉县头道沟地区镁铁—超镁铁质岩U-Pb年代学研究及地质意义

吉林省永吉县头道沟地区出露许多与头道沟岩组相伴产出的镁铁—超镁铁质岩,鉴于其处于长春-延吉构造带附近而受到业内关注,但由于缺少高精度年代学资料,制约了对区域大地构造的深入研究。本文采用锆石U-Pb(LA-ICP-MS)方法,对镁铁—超镁铁质岩进行了年代学研究。变质辉绿岩年龄为270±5 Ma,变质橄榄岩中捕获锆石最小年龄为297 Ma,考虑岩石组合及二者紧密相伴产出,认为二者均形成于中二叠世。镁铁—超镁铁质岩中捕获的锆石记录了华北克拉通及其北缘多次重要的构造热事件。其中,变辉绿岩中获得446±6 Ma的年龄与变质橄榄岩中获得的不一致线下交点434±240 Ma年龄共同对应了华北克拉通北缘早古生代的重要构造岩浆热事件;大量的1.8~2.4Ga年龄对应古元古代辽吉造山带热事件;1377 Ma、1542 Ma与蓟县系建造时代对应;869~997 Ma与青白口系建造时代对应;在变质辉绿岩中还存在众多3.0~3.2Ga锆石年龄。分析上述年龄结构及龙岗陆块北缘古生代地质体分布特征,推测研究区深部可能存在古老的变质基底,同时也表明研究区出露的镁铁—超镁铁质岩形成于陆内构造环境,而非蛇绿岩的组成成分,这对深化区域大地构造研究具有重要意义。     

Os水吸收液ICP-MS测量信号强度衰减原因研究

蒸馏法能从样品中有效分离出OsO_4,吸收液直接用于ICP-MS测定,是辉钼矿Re-Os定年的关键技术环节。但实验发现,长时间放置的吸收液中Os信号强度显著降低。根据OsO_4化学性质推测原因在于一是挥发使吸收液Os含量减少,二是还原使+8价Os变成低价态,气态比例降低,若雾化效率不变,进入质谱仪的Os减少,两者都会导致信号降低,但具体影响情况不明,需深入研究。本文利用辉钼矿标准物质制备不同放置时间、酸度和温度的吸收液,对比上述条件对ICP-MS信号强度的影响。实验时将残余吸收液与稀释剂、氧化剂封入Carius管加热蒸馏,测定Os含量。结果表明:吸收液放置时间越长,酸度越低,温度越高,信号降幅越大,幅度达到3.2%~68.6%。室温下放置相同时间,低酸度吸收液的Os保存率高于高酸度吸收液,但Os信号强度低于后者,证明了挥发和还原共同导致信号衰减,且还原是主导原因。本文提出,冷冻(-18℃)可抑制OsO_4挥发,提高酸度(约3.5 mol/L)可减弱OsO_4还原,两者结合抑制信号衰减,提高了蒸馏法的灵活性和适用性。     

巴音戈壁盆地南部塔木素铀矿床水岩作用特征及其与铀成矿关系研究

在较封闭的环境中,塔木素铀矿床高矿化度(平均矿化度为35.4 g/L)NaCl型地下水中的Na+替换了斜长石中的Ca2+,使斜长石由更长石(An≈13)转变为钠长石(An≈1),被替换出的Ca_2+(以CaO计,约占斜长石总质量的4.5%)与地下水中的HCO_3~-、CO_3~(2-)及Mg~(2+)等结合形成了白云石等碳酸盐胶结物。在此过程中发生了脱碳作用,促使地下水中以[UO_2(CO_3)_3]~(4-)、[UO_2(CO_3)_3]~(2-)等碳酸铀酰络合离子及Mg CO_3·Na_2UO_2(CO_3)_2复盐发生分离而形成了铀的沉淀,并受扩散作用影响,水中的铀趋向于向水岩作用相对强烈地段迁移,从而促使铀在特定的层位集中、富集。同时,斜长石因水岩作用(溶解、溶蚀等),在解理面及表面形成了次生的缝隙及孔洞等,为铀沉淀提供了空间。成岩后,含SO_4~(2-)等的酸性地表水沿层间下渗,溶解了砂岩中碳酸盐胶结物而形成了溶洞,为后期再次迁移的铀提供了沉淀空间,并形成了铀的进一步叠加、富集。     

Water system characteristics of Karst river basins in South China and their driving mechanisms of hydrological drought

Natural Hazards - It is common knowledge that drought is considered one of the most damaging natural disasters in terms of economic costs, societal problems, and ecological impacts. In this study,...